Additivity of pore structural parameters of granular activated carbons derived from different coals and their blends

A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were m...

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Published inInternational journal of mining science and technology Vol. 26; no. 4; pp. 661 - 667
Main Authors Yao, Xin, Xie, Qiang, Yang, Chuan, Zhang, Bo, Wan, Chaoran, Cui, Shanshan
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.07.2016
Department of Chemical and Food Engineering,Hefei University of Technology,Xuancheng 242000,China%School of Chemical and Environmental Engineering,China University of Mining and Technology,Beijing 100083,China
School of Chemical and Environmental Engineering,China University of Mining and Technology,Beijing 100083,China
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Abstract A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were measured and cal- culated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.
AbstractList A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (S sub(BET)), total pore volume (V sub(T)) and average pore diameter (d sub(a)) were measured and calculated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error ( delta ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with delta less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the delta increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.
A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBET), total pore volume (VT) and average pore diameter (da) were measured and calculated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with δ less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.
A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were measured and cal- culated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.
Author Yao Xin Xie Qiang Yang Chuan Zhang Bo Wan Chaoran Cui Shanshan
AuthorAffiliation School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China Department of Chemical and Food Engineering, Hefei University of Technology, Xuancheng 242000, China
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Keywords Additivity
Pore structural parameters
Granular activated carbon
Coal blend
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Notes Granular activated carbon Coal blend Pore structural parameters Additivity
32-1827/TD
A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as the binder. Pore structural parameters including BET specific surface area (SBEr), total pore volume (Vr) and average pore diameter (da) were measured and cal- culated as well as process parameters such as yield of char (CY) and burn-off (B). The relationship between the pore structural parameters of the GAC from coal blend (BC-GAC) and the ones of the GACs from corresponding single coals (SC-GACs) was analyzed, in which an index, the relative error (δ), was presented to define the bias between fitted values and experimental values of these parameters of the BC-GACs. The results show that the BC-GAC keeps qualitatively the pore structural features of the SC-GACs; as concerned as the quantitative relationship, the pore structural parameters of the BC-GAC from coal blend consisting of non-caking coals can be obtained by adding proportionally the pore structural parameters of the SC-GACs with a less than 10%. Meanwhile, for the BC-GAC from coal blend containing weak caking bituminous coal, the δ increases up to 25% and the experimental pore size distribution differs greatly from the fitted one.
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Snippet A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as...
A series of granular activated carbons (GACs) were prepared by briquetting method from Chinese coals of different ranks and their blends, with coal pitch as...
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SubjectTerms Activated carbon
Additivity
Bituminous coal
Blends
Caking
Coal
Coal blend
Error analysis
Granular activated carbon
Mathematical analysis
Pore structural parameters
Porosity
可加性
孔隙结构参数
工艺参数
平均孔径
成型方法
混煤
粘结性煤
颗粒活性炭
Title Additivity of pore structural parameters of granular activated carbons derived from different coals and their blends
URI http://lib.cqvip.com/qk/85399B/201604/669551477.html
https://dx.doi.org/10.1016/j.ijmst.2016.05.019
https://www.proquest.com/docview/1835638389
https://d.wanfangdata.com.cn/periodical/zgkydxxb-e201604019
Volume 26
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