Properties of Bloodmeal/Linear Low-density Polyethylene Blends Compatibilized with Maleic Anhydride Grafted Polyethylene
ABSTRACT Novatein thermoplastics from bloodmeal (NTP) were blended with linear low‐density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE‐g‐MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and co...
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| Published in | Journal of applied polymer science Vol. 130; no. 3; pp. 1890 - 1897 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Hoboken, NJ
Blackwell Publishing Ltd
05.11.2013
Wiley Wiley Subscription Services, Inc |
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| Online Access | Get full text |
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| Abstract | ABSTRACT
Novatein thermoplastics from bloodmeal (NTP) were blended with linear low‐density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE‐g‐MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and compared with blends without compatibilizer. The amount of polyethylene added was varied between 20 and 70% in NTP with addition of 10% compatibilizer. An improvement in compatibility between NTP and LLDPE was observed across the entire composition range and the difference were more pronounced at higher NTP contents where the tensile strength of blends was maintained and never dropped below that of pure NTP. Theoretical models were compared to the results to describe mechanical properties. A finely dispersed small particles of NTP in compatibilized blends were observed using SEM. Improved compatibility has restricted chain movement resulting in slightly elevated Tg revealed by DMA. On the other hand, water absorption of the hydrophilic NTP has been decreased when blending with hydrophobic LLDPE. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1890–1897, 2013 |
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| AbstractList | ABSTRACT
Novatein thermoplastics from bloodmeal (NTP) were blended with linear low‐density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE‐
g
‐MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and compared with blends without compatibilizer. The amount of polyethylene added was varied between 20 and 70% in NTP with addition of 10% compatibilizer. An improvement in compatibility between NTP and LLDPE was observed across the entire composition range and the difference were more pronounced at higher NTP contents where the tensile strength of blends was maintained and never dropped below that of pure NTP. Theoretical models were compared to the results to describe mechanical properties. A finely dispersed small particles of NTP in compatibilized blends were observed using SEM. Improved compatibility has restricted chain movement resulting in slightly elevated
T
g
revealed by DMA. On the other hand, water absorption of the hydrophilic NTP has been decreased when blending with hydrophobic LLDPE. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1890–1897, 2013 ABSTRACT Novatein thermoplastics from bloodmeal (NTP) were blended with linear low‐density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE‐g‐MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and compared with blends without compatibilizer. The amount of polyethylene added was varied between 20 and 70% in NTP with addition of 10% compatibilizer. An improvement in compatibility between NTP and LLDPE was observed across the entire composition range and the difference were more pronounced at higher NTP contents where the tensile strength of blends was maintained and never dropped below that of pure NTP. Theoretical models were compared to the results to describe mechanical properties. A finely dispersed small particles of NTP in compatibilized blends were observed using SEM. Improved compatibility has restricted chain movement resulting in slightly elevated Tg revealed by DMA. On the other hand, water absorption of the hydrophilic NTP has been decreased when blending with hydrophobic LLDPE. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1890–1897, 2013 Novatein thermoplastics from bloodmeal (NTP) were blended with linear low-density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE-g-MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and compared with blends without compatibilizer. The amount of polyethylene added was varied between 20 and 70% in NTP with addition of 10% compatibilizer. An improvement in compatibility between NTP and LLDPE was observed across the entire composition range and the difference were more pronounced at higher NTP contents where the tensile strength of blends was maintained and never dropped below that of pure NTP. Theoretical models were compared to the results to describe mechanical properties. A finely dispersed small particles of NTP in compatibilized blends were observed using SEM. Improved compatibility has restricted chain movement resulting in slightly elevated Tg revealed by DMA. On the other hand, water absorption of the hydrophilic NTP has been decreased when blending with hydrophobic LLDPE. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1890-1897, 2013 [PUBLICATION ABSTRACT] Novatein thermoplastics from bloodmeal (NTP) were blended with linear low-density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE-g-MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and compared with blends without compatibilizer. The amount of polyethylene added was varied between 20 and 70% in NTP with addition of 10% compatibilizer. An improvement in compatibility between NTP and LLDPE was observed across the entire composition range and the difference were more pronounced at higher NTP contents where the tensile strength of blends was maintained and never dropped below that of pure NTP. Theoretical models were compared to the results to describe mechanical properties. A finely dispersed small particles of NTP in compatibilized blends were observed using SEM. Improved compatibility has restricted chain movement resulting in slightly elevated T sub(g)revealed by DMA. On the other hand, water absorption of the hydrophilic NTP has been decreased when blending with hydrophobic LLDPE. [copy 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1890-1897, 2013 |
| Author | Verbeek, C. J. R. Marsilla, K. I. Ku |
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| Keywords | Polymer blends Meat product Mechanical properties compatibilization Organic anhydride Experimental study biopolymers and renewable polymers Compatibilizer Functional polymer Heterogeneous mixture Tensile strength Thermal properties Industrial waste Morphology Blood meal Animal protein Extrusion Olefin polymer Water absorption Linear low density ethylene polymer blends |
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Novatein thermoplastics from bloodmeal (NTP) were blended with linear low‐density polyethylene (LLDPE) using maleic anhydride grafted polyethylene... Novatein thermoplastics from bloodmeal (NTP) were blended with linear low-density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE-g-MAH)... |
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| SubjectTerms | Applied sciences Biological and medical sciences biopolymers and renewable polymers Blends Compatibility compatibilization Exact sciences and technology extrusion Extrusion moulding Food industries Fundamental and applied biological sciences. Psychology Grafting Machinery and processing Maleic anhydride Materials science Moulding Natural polymers Physicochemistry of polymers Plastics Polyethylenes Polymer blends Polymer industry, paints, wood Polymers Proteins Reproduction Technology of polymers Use and upgrading of agricultural and food by-products. Biotechnology Water absorption |
| Title | Properties of Bloodmeal/Linear Low-density Polyethylene Blends Compatibilized with Maleic Anhydride Grafted Polyethylene |
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