Reduction of carbon monoxide by a tetrakis(aryloxide)diniobium complex having four bridging hydrides

The use of a sterically demanding aryloxide ligand allows us to isolate a tetrakis(aryloxide)diniobium complex bridged by four hydride ligands. This hydride aryloxide undergoes reduction of CO via hydrogenation and deoxygenation, resulting in formation of a methylidene species. Further carbonylation...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 42; no. 21; pp. 7510 - 7513
Main Authors Kurogi, Takashi, Ishida, Yutaka, Hatanaka, Tsubasa, Kawaguchi, Hiroyuki
Format Journal Article
LanguageEnglish
Published England 01.01.2013
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Summary:The use of a sterically demanding aryloxide ligand allows us to isolate a tetrakis(aryloxide)diniobium complex bridged by four hydride ligands. This hydride aryloxide undergoes reduction of CO via hydrogenation and deoxygenation, resulting in formation of a methylidene species. Further carbonylation gives a vinylidene complex.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt32798h