Influences of Process Parameters and Addition Elements on the Fabrication of TiC-Ti3SiC2 Composites by Spark Sintering
In TiC-Ti3SiC2 composites, the introduction of the TiC hard phase could improve the hardness of the Ti3SiC2 phase and prepare high hardness, high toughness and self-lubricating materials. In this study, elementary Ti, Si and graphite powders in the molar ratio of 3:1+x:2 were used as starting powder...
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| Published in | MATERIALS TRANSACTIONS Vol. 66; no. 5; pp. 608 - 615 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Sendai
The Japan Institute of Metals and Materials
01.05.2025
公益社団法人 日本金属学会 Japan Science and Technology Agency |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1345-9678 1347-5320 |
| DOI | 10.2320/matertrans.MT-MC2024008 |
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| Abstract | In TiC-Ti3SiC2 composites, the introduction of the TiC hard phase could improve the hardness of the Ti3SiC2 phase and prepare high hardness, high toughness and self-lubricating materials. In this study, elementary Ti, Si and graphite powders in the molar ratio of 3:1+x:2 were used as starting powders, a small amount of Al powder was added as a sintering aid, and spark sintering technology was used to sinter in the temperature range of 1373 to 1673 K at 50 MPa in vacuum. The reacted phases were identified by X-ray diffraction, and microstructure characteristics were observed. The formation mechanism of TiC-Ti3SiC2 composites was investigated based on the sintering behavior of the elemental powders during spark sintering. Pure TiC-Ti3SiC2 composites could be prepared from Ti, Si, graphite powders and Al at a molar ratio of 3:1.1:2:0.3 at 1573 K with a holding time of 0.9 ks. In conclusion, dual phase consist of TiC and Ti3SiC2 composite could be synthesized through in-situ reaction by adjusting process parameters such as sintering temperature, holding time and the content of Si and Al in element blending method. |
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| AbstractList | In TiC-Ti3SiC2 composites, the introduction of the TiC hard phase could improve the hardness of the Ti3SiC2 phase and prepare high hardness, high toughness and self-lubricating materials. In this study, elementary Ti, Si and graphite powders in the molar ratio of 3:1+x:2 were used as starting powders, a small amount of Al powder was added as a sintering aid, and spark sintering technology was used to sinter in the temperature range of 1373 to 1673 K at 50 MPa in vacuum. The reacted phases were identified by X-ray diffraction, and microstructure characteristics were observed. The formation mechanism of TiC-Ti3SiC2 composites was investigated based on the sintering behavior of the elemental powders during spark sintering. Pure TiC-Ti3SiC2 composites could be prepared from Ti, Si, graphite powders and Al at a molar ratio of 3:1.1:2:0.3 at 1573 K with a holding time of 0.9 ks. In conclusion, dual phase consist of TiC and Ti3SiC2 composite could be synthesized through in-situ reaction by adjusting process parameters such as sintering temperature, holding time and the content of Si and Al in element blending method. In TiC-Ti3SiC2 composites, the introduction of the TiC hard phase could improve the hardness of the Ti3SiC2 phase and prepare high hardness, high toughness and self-lubricating materials. In this study, elementary Ti, Si and graphite powders in the molar ratio of 3:1+x:2 were used as starting powders, a small amount of Al powder was added as a sintering aid, and spark sintering technology was used to sinter in the temperature range of 1373 to 1673 K at 50 MPa in vacuum. The reacted phases were identified by X-ray diffraction, and microstructure characteristics were observed. The formation mechanism of TiC-Ti3SiC2 composites was investigated based on the sintering behavior of the elemental powders during spark sintering. Pure TiC-Ti3SiC2 composites could be prepared from Ti, Si, graphite powders and Al at a molar ratio of 3:1.1:2:0.3 at 1573 K with a holding time of 0.9 ks. In conclusion, dual phase consist of TiC and Ti3SiC2 composite could be synthesized through in-situ reaction by adjusting process parameters such as sintering temperature, holding time and the content of Si and Al in element blending method.Fig. 13 Phase content rate of prepared compacts (3Ti/1.1Si/2C/0.3Al) in the sintering conditions at 1573 K for 0.3–0.9 ks. 400–3200 HV is obtained from literature [2, 32–35]. |
| ArticleNumber | MT-MC2024008 |
| Author | Xu, Zhefeng Matsugi, Kazuhiro Choi, Yongbum Qu, Jing Yu, Jinku |
| Author_xml | – sequence: 1 fullname: Qu, Jing organization: Department of Mechanical Materials Engineering, Hiroshima University – sequence: 1 fullname: Xu, Zhefeng organization: State Key Laboratory of Metastable Materials Science and Technology, Yanshan University – sequence: 1 fullname: Matsugi, Kazuhiro organization: Department of Mechanical Materials Engineering, Hiroshima University – sequence: 1 fullname: Yu, Jinku organization: State Key Laboratory of Metastable Materials Science and Technology, Yanshan University – sequence: 1 fullname: Choi, Yongbum organization: Department of Mechanical Materials Engineering, Hiroshima University |
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| SubjectTerms | Aluminum Chemical synthesis Compacts Composite materials Graphite Hardness in-situ reaction Process parameters Self lubricating materials Self lubrication Silicon Sintering Sintering (powder metallurgy) Sintering aids spark sintering sustainable development goals’ materials TiC-Ti3SiC2 composites Titanium carbide Titanium silicon carbide |
| Title | Influences of Process Parameters and Addition Elements on the Fabrication of TiC-Ti3SiC2 Composites by Spark Sintering |
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