Desorption isotherms of flaxseeds (Linum usitatissimum L.) and thermodynamic parameters of the process
ABSTRACT Sorption isotherms of flaxseeds were determined by static gravimetric method at temperatures 40, 60, and 80 ºC, over a relative moisture range of 10-95%. Six mathematical models were applied to analyze the experimental data. The modified GAB model showed the best fitting to the experimental...
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Published in | Ciência agronômica Vol. 51; no. 2 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English Portuguese |
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Universidade Federal do Ceará
01.01.2020
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Abstract | ABSTRACT Sorption isotherms of flaxseeds were determined by static gravimetric method at temperatures 40, 60, and 80 ºC, over a relative moisture range of 10-95%. Six mathematical models were applied to analyze the experimental data. The modified GAB model showed the best fitting to the experimental data. The isosteric heat and differential entropy were determined by applying the Clausius-Clapeyron and Gibbs-Helmholtz equations, respectively. The isosteric heat and the entropy of desorption isotherm presented similar behavior, with a sharp change of 10% in the equilibrium moisture content. The enthalpy-entropy compensation theory was applied to the isotherms, indicating that they are enthalpy-controlled. |
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AbstractList | ABSTRACT Sorption isotherms of flaxseeds were determined by static gravimetric method at temperatures 40, 60, and 80 ºC, over a relative moisture range of 10-95%. Six mathematical models were applied to analyze the experimental data. The modified GAB model showed the best fitting to the experimental data. The isosteric heat and differential entropy were determined by applying the Clausius-Clapeyron and Gibbs-Helmholtz equations, respectively. The isosteric heat and the entropy of desorption isotherm presented similar behavior, with a sharp change of 10% in the equilibrium moisture content. The enthalpy-entropy compensation theory was applied to the isotherms, indicating that they are enthalpy-controlled. |
Author | Valente, Maria da Conceição da Costa Santana, Elza Brandão Costa, Cristiane Maria Leal Nascimento, Rafael Alves do Faria, Lênio José Guerreiro de |
AuthorAffiliation | Universidade Federal do Pará |
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Author_xml | – sequence: 1 givenname: Maria da Conceição da Costa surname: Valente fullname: Valente, Maria da Conceição da Costa – sequence: 2 givenname: Rafael Alves do surname: Nascimento fullname: Nascimento, Rafael Alves do – sequence: 3 givenname: Elza Brandão surname: Santana fullname: Santana, Elza Brandão – sequence: 4 givenname: Lênio José Guerreiro de surname: Faria fullname: Faria, Lênio José Guerreiro de – sequence: 5 givenname: Cristiane Maria Leal surname: Costa fullname: Costa, Cristiane Maria Leal |
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Keywords | Secagem Conteúdo de umidade de equilíbrio Equilibrium moisture content Drying Isosteric heat Calor isostérico |
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References | CHISTÉ, R. C. 2015; 45 MENKOV, N. D. 2000; 45 ALPIZAR-REYES, E. 2017; 101 BOTHEJU, W. S.; AMARATHUNGE, K. S. P.; ZIYAD MOHAMED, M. T. 2008; 26 GREENSPAN, L. 1977; 18 MADAMBA, P. S.; DRISCOLL, R. H.; BUCKLE, K. A. 1996; 28 SPIESS, W. E. L.; WOLF, W. F.; JOWITT, R. 1983 ALVES, T. P.; FÓZ, H. D; NICOLETI, J. F. 2015; 18 OLIVEIRA, D. E. C. de 2017; 21 ANDRADE, P. R. D.; LEMUS, M. R.; PEREZ, C. C. E. 2011; 18 MAZZA, G.; JAYAS, D. S.; WHITE, N. D. G. 1990; 33 MOREIRA, R. 2008; 88 SIQUEIRA, V. C.; RESENDE, O.; CHAVES, T. H. 2013; 44 CORRÊA, P. C. 2015; 37 CHOO, W. S.; BIRCH, J.; DUFOUR, J. P. 2007; 20 LABUZA, T. P. 1983; 28 BELGHITH, A.; AZZOUZ, S.; ELCAFSI, A. 2016; 52 CLADERA-OLIVERA, F. 2008; 43 RIZVI, S. S. H.; RAO, M. A.; RIZVI, S. S. H.; DATTA, A. K. 2005 HORWITZ, W. 2005 KAJLA, P.; SHARMA, A.; SOOD, D. R. 2015; 52 CABEZA, L. F.; SOLÉ, A.; BARRENECHE, C. 2017; 110 FREITAS, M. L. F. 2016; 51 SINGH, A. K.; KUMARI, N. 2014; 5 GONELI, A. L. 2016; 20 MIANOWSKI, A.; URBAŃCZYK, W. 2017; 23 SORMOLI, M. E.; LANGRISH, T. A. G. 2015; 62 |
References_xml | – volume: 26 start-page: 1294 issue: 10 year: 2008 end-page: 1299 article-title: Modeling moisture desorption isotherms and thermodynamic properties of fermented tea dhool (Camellia sinensis var. assamica) publication-title: Drying Technology contributor: fullname: BOTHEJU, W. S.; AMARATHUNGE, K. S. P.; ZIYAD MOHAMED, M. T. – volume: 5 issue: 4 year: 2014 article-title: Moisture sorption isotherm characteristics of ground flaxseed publication-title: Journal of Food Processing & Technology contributor: fullname: SINGH, A. K.; KUMARI, N. – volume: 43 start-page: 900 issue: 5 year: 2008 end-page: 907 article-title: Thermodynamic properties of moisture desorption of raw pinhão (Araucaria angustifólia seeds) publication-title: International Journal of Food Science and Technology contributor: fullname: CLADERA-OLIVERA, F. – volume: 62 start-page: 875 year: 2015 end-page: 882 article-title: Moisture sorption isotherms and net isosteric heat of sorption for spray-dried pure orange juice powder publication-title: LWT- Food Science and Technology contributor: fullname: SORMOLI, M. E.; LANGRISH, T. A. G. – volume: 37 start-page: 218 issue: 3 year: 2015 end-page: 225 article-title: Moisture desorption isotherms of cucumber seeds: modeling and thermodynamic properties publication-title: Journal of Seed Science contributor: fullname: CORRÊA, P. C. – volume: 44 start-page: 278 issue: 2 year: 2013 end-page: 285 article-title: Mathematical modelling of the drying of jatropha fruit: an empirical comparison publication-title: Revista Ciência Agronômica contributor: fullname: SIQUEIRA, V. C.; RESENDE, O.; CHAVES, T. H. – volume: 18 start-page: 89 issue: 1 year: 1977 end-page: 96 article-title: Humidity fixed points of binary saturated aqueous solutions publication-title: Journal of Research of the National Bureau of Standards - A. Physics and Chemistry contributor: fullname: GREENSPAN, L. – volume: 33 start-page: 1313 issue: 4 year: 1990 end-page: 1318 article-title: Moisture sorption isotherms of flax seed publication-title: Transactions of the ASAE contributor: fullname: MAZZA, G.; JAYAS, D. S.; WHITE, N. D. G. – volume: 21 start-page: 285 issue: 4 year: 2017 end-page: 289 article-title: Hygroscopicity of ‘sucupira-branca’(Pterodon emarginatus Vogel) fruits publication-title: Revista Brasileira de Engenharia Agrícola e Ambiental contributor: fullname: OLIVEIRA, D. E. C. de – volume: 101 start-page: 166 year: 2017 end-page: 176 article-title: Thermodynamic sorption properties and glass transition temperature of tamarind seed mucilage (Tamarindus indica L.) publication-title: Food and Bioproducts Processing contributor: fullname: ALPIZAR-REYES, E. – volume: 45 start-page: 189 issue: 4 year: 2000 end-page: 194 article-title: Moisture sorption isotherms of chickpea seeds at several temperatures publication-title: Journal of Food Engineering contributor: fullname: MENKOV, N. D. – volume: 23 start-page: 831 issue: 6 year: 2017 end-page: 846 article-title: Enthalpy-entropy compensation for isosteric state adsorption at near ambient temperatures publication-title: Adsorption contributor: fullname: MIANOWSKI, A.; URBAŃCZYK, W. – volume: 18 start-page: 325 issue: 3 year: 2011 end-page: 334 article-title: Models of sorption isotherms for food: uses and limitations publication-title: Vitae contributor: fullname: ANDRADE, P. R. D.; LEMUS, M. R.; PEREZ, C. C. E. – volume: 52 start-page: 407 year: 2016 end-page: 419 article-title: Desorption isotherms and mathematical modeling of thin layer drying kinetics of tomato publication-title: Heat Mass Transfer contributor: fullname: BELGHITH, A.; AZZOUZ, S.; ELCAFSI, A. – volume: 28 start-page: 109 issue: 2 year: 1996 end-page: 119 article-title: Enthalpy-entropy compensation models for sorption and browning of garlic publication-title: Journal of Food Engineering contributor: fullname: MADAMBA, P. S.; DRISCOLL, R. H.; BUCKLE, K. A. – volume: 45 start-page: 1515 issue: 8 year: 2015 end-page: 1521 article-title: Hygroscopic behaviour of cassava flour from dry and water groups publication-title: Ciência Rural contributor: fullname: CHISTÉ, R. C. – volume: 51 start-page: 250 issue: 1 year: 2016 end-page: 259 article-title: Sorption isotherms and thermodynamic properties of grated Parmesan cheese publication-title: International Journal of Food Science & Technology contributor: fullname: FREITAS, M. L. F. – start-page: 65 year: 1983 end-page: 91 publication-title: Physical properties of foods contributor: fullname: SPIESS, W. E. L.; WOLF, W. F.; JOWITT, R. – volume: 88 start-page: 514 issue: 4 year: 2008 end-page: 521 article-title: Thermodynamic analysis of experimental sorption isotherms of loquat and quince fruits publication-title: Journal of Food Engineering contributor: fullname: MOREIRA, R. – year: 2005 publication-title: Official Methods of Analysis of the AOAC International contributor: fullname: HORWITZ, W. – volume: 52 start-page: 1857 issue: 4 year: 2015 end-page: 1871 article-title: Flaxseed: a potential functional food source publication-title: Journal of Food Science and Technology contributor: fullname: KAJLA, P.; SHARMA, A.; SOOD, D. R. – volume: 28 start-page: 258 issue: 4 year: 1983 end-page: 258 article-title: Standard procedure for isotherm determination publication-title: Cereal Foods World (USA) contributor: fullname: LABUZA, T. P. – volume: 18 start-page: 137 issue: 2 year: 2015 end-page: 145 article-title: Isotermas de dessorção de pimentão verde e energia envolvida no processo publication-title: Brazilian Journal of Food Technology contributor: fullname: ALVES, T. P.; FÓZ, H. D; NICOLETI, J. F. – volume: 110 start-page: 3 year: 2017 end-page: 39 article-title: Review on sorption materials and technologies for heat pumps and thermal energy storage publication-title: Renewable Energy contributor: fullname: CABEZA, L. F.; SOLÉ, A.; BARRENECHE, C. – volume: 20 start-page: 757 issue: 8 year: 2016 end-page: 762 article-title: Moisture sorption isotherms of castor beans. Part 2: Thermodynamic properties publication-title: Revista Brasileira de Engenharia Agrícola e Ambiental contributor: fullname: GONELI, A. L. – start-page: 239 year: 2005 end-page: 326 publication-title: Engineering Properties of Foods contributor: fullname: RIZVI, S. S. H.; RAO, M. A.; RIZVI, S. S. H.; DATTA, A. K. – volume: 20 start-page: 202 issue: 3 year: 2007 end-page: 211 article-title: Physicochemical and quality characteristics of cold-press flaxseed oils publication-title: Journal of Food composition and Analysis contributor: fullname: CHOO, W. S.; BIRCH, J.; DUFOUR, J. P. |
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Title | Desorption isotherms of flaxseeds (Linum usitatissimum L.) and thermodynamic parameters of the process |
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