Microscopic Evidence for the Topological Transition in Model Vitrimers

In addition to the glass transition, vitrimers undergo a topological transition from viscoelastic liquid to viscoelastic solid behavior when the network rearrangements facilitated by dynamic bond exchange reactions freeze. The microscopic observation of this transition is elusive. Model polyisoprene...

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Bibliographic Details
Published inACS macro letters Vol. 12; no. 11; pp. 1595 - 1601
Main Authors Arbe, Arantxa, Alegría, Angel, Colmenero, Juan, Bhaumik, Saibal, Ntetsikas, Konstantinos, Hadjichristidis, Nikos
Format Journal Article
LanguageEnglish
Published 21.11.2023
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