Tranexamic acid derived gold nanoparticles modified glassy carbon electrode as sensitive sensor for determination of nalbuphine
•Facile synthesis of AuNps using tranexamic acid as reducing and capping agent.•Characterization of synthesized AuNps.•Fabrication of new sensor by utilizing nafion stabilized Tr-AuNps on GCE.•Application of novel voltammetric sensor for sensitive detection of nalbuphine. We display a simple chemica...
Saved in:
| Published in | Sensors and actuators. B, Chemical Vol. 211; pp. 359 - 369 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.05.2015
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | •Facile synthesis of AuNps using tranexamic acid as reducing and capping agent.•Characterization of synthesized AuNps.•Fabrication of new sensor by utilizing nafion stabilized Tr-AuNps on GCE.•Application of novel voltammetric sensor for sensitive detection of nalbuphine.
We display a simple chemical procedure for fabrication of spherical gold nanoparticles (AuNps) using tranexamic acid (Tr) as reducing as well as capping agent. As-formed Tr-AuNps were characterized by Ultra Violet Visible (UV–Vis) spectroscopy where the surface plasmon absorption band was controlled at 522nm under already optimized conditions. Atomic force microscopy (AFM) unveiled information in relation to size and shape of Tr-AuNps. Fourier transform infra red (FTIR) spectroscopy divulged the interaction between capping agent and AuNps while X-ray diffractometry (XRD) disclosed the nature of crystalline patterns of AuNps. As-prepared Tr-AuNps were sandwiched between the surface of glassy carbon electrode (GCE) and nafion and used as sensor for highly selective and sensitive voltammetric determination of nalbuphine (NA) using square wave voltammetry (SWV) as analytical mode. Parameters such as volume of nafion, working electrodes, type and ionic strength of supporting electrolyte, pH, stirring rate, initial potential, accumulation potential and accumulation time were optimized. The mechanism regarding the oxidation of NA was also proposed. The sensor responded linearly in the range of 0.05–1.25μgmL−1 NA with excellent limit of detection (LOD) of 13.2ngmL−1 and R2 value of 0.997. In addition, the sensor performed linearly to NA even within the matrices of serum as well as urine samples. The fabricated sensor demonstrated higher selectivity for sensitive determination of NA in the presence of various interfering species commonly found in human serum and urine. The developed sensor was successfully applied and validated for the determination of NA in human serum and urine samples with excellent recoveries. |
|---|---|
| AbstractList | We display a simple chemical procedure for fabrication of spherical gold nanoparticles (AuNps) using tranexamic acid (Tr) as reducing as well as capping agent. As-formed Tr-AuNps were characterized by Ultra Violet Visible (UV-Vis) spectroscopy where the surface plasmon absorption band was controlled at 522nm under already optimized conditions. Atomic force microscopy (AFM) unveiled information in relation to size and shape of Tr-AuNps. Fourier transform infra red (FTIR) spectroscopy divulged the interaction between capping agent and AuNps while X-ray diffractometry (XRD) disclosed the nature of crystalline patterns of AuNps. As-prepared Tr-AuNps were sandwiched between the surface of glassy carbon electrode (GCE) and nafion and used as sensor for highly selective and sensitive voltammetric determination of nalbuphine (NA) using square wave voltammetry (SWV) as analytical mode. Parameters such as volume of nafion, working electrodes, type and ionic strength of supporting electrolyte, pH, stirring rate, initial potential, accumulation potential and accumulation time were optimized. The mechanism regarding the oxidation of NA was also proposed. The sensor responded linearly in the range of 0.05-1.25 mu gmL-1 NA with excellent limit of detection (LOD) of 13.2ngmL-1 and R 2 value of 0.997. In addition, the sensor performed linearly to NA even within the matrices of serum as well as urine samples. The fabricated sensor demonstrated higher selectivity for sensitive determination of NA in the presence of various interfering species commonly found in human serum and urine. The developed sensor was successfully applied and validated for the determination of NA in human serum and urine samples with excellent recoveries. •Facile synthesis of AuNps using tranexamic acid as reducing and capping agent.•Characterization of synthesized AuNps.•Fabrication of new sensor by utilizing nafion stabilized Tr-AuNps on GCE.•Application of novel voltammetric sensor for sensitive detection of nalbuphine. We display a simple chemical procedure for fabrication of spherical gold nanoparticles (AuNps) using tranexamic acid (Tr) as reducing as well as capping agent. As-formed Tr-AuNps were characterized by Ultra Violet Visible (UV–Vis) spectroscopy where the surface plasmon absorption band was controlled at 522nm under already optimized conditions. Atomic force microscopy (AFM) unveiled information in relation to size and shape of Tr-AuNps. Fourier transform infra red (FTIR) spectroscopy divulged the interaction between capping agent and AuNps while X-ray diffractometry (XRD) disclosed the nature of crystalline patterns of AuNps. As-prepared Tr-AuNps were sandwiched between the surface of glassy carbon electrode (GCE) and nafion and used as sensor for highly selective and sensitive voltammetric determination of nalbuphine (NA) using square wave voltammetry (SWV) as analytical mode. Parameters such as volume of nafion, working electrodes, type and ionic strength of supporting electrolyte, pH, stirring rate, initial potential, accumulation potential and accumulation time were optimized. The mechanism regarding the oxidation of NA was also proposed. The sensor responded linearly in the range of 0.05–1.25μgmL−1 NA with excellent limit of detection (LOD) of 13.2ngmL−1 and R2 value of 0.997. In addition, the sensor performed linearly to NA even within the matrices of serum as well as urine samples. The fabricated sensor demonstrated higher selectivity for sensitive determination of NA in the presence of various interfering species commonly found in human serum and urine. The developed sensor was successfully applied and validated for the determination of NA in human serum and urine samples with excellent recoveries. |
| Author | Sirajuddin Agheem, Muhammad H. Sherazi, Syed Tufail H. Talpur, Farah N. Siddiqui, Samia Nafady, Ayman Shah, Muhammad R. Soomro, Razium A. Shaikh, Tayyaba |
| Author_xml | – sequence: 1 givenname: Tayyaba surname: Shaikh fullname: Shaikh, Tayyaba organization: National Center of Excellence in Analytical Chemistry, University of Sindh, A-333, Phase 1, SUECHS, Jamshoro 76080, Pakistan – sequence: 2 givenname: Ayman surname: Nafady fullname: Nafady, Ayman organization: Department of Chemistry, College of Science, King Saud University, Riyadh, Saudi Arabia – sequence: 3 givenname: Farah N. surname: Talpur fullname: Talpur, Farah N. organization: National Center of Excellence in Analytical Chemistry, University of Sindh, A-333, Phase 1, SUECHS, Jamshoro 76080, Pakistan – sequence: 4 surname: Sirajuddin fullname: Sirajuddin email: drsiraj03@yahoo.com, drsiraj03@hotmail.com organization: National Center of Excellence in Analytical Chemistry, University of Sindh, A-333, Phase 1, SUECHS, Jamshoro 76080, Pakistan – sequence: 5 givenname: Muhammad H. surname: Agheem fullname: Agheem, Muhammad H. organization: Center for Pure and Applied Geology, University of Sindh, Jamshoro 76080, Pakistan – sequence: 6 givenname: Muhammad R. surname: Shah fullname: Shah, Muhammad R. organization: International Center for Chemical and Biological Sciences, HEJ Research Institute of Chemistry, University of Karachi, Karachi 75270, Pakistan – sequence: 7 givenname: Syed Tufail H. surname: Sherazi fullname: Sherazi, Syed Tufail H. organization: National Center of Excellence in Analytical Chemistry, University of Sindh, A-333, Phase 1, SUECHS, Jamshoro 76080, Pakistan – sequence: 8 givenname: Razium A. surname: Soomro fullname: Soomro, Razium A. organization: National Center of Excellence in Analytical Chemistry, University of Sindh, A-333, Phase 1, SUECHS, Jamshoro 76080, Pakistan – sequence: 9 givenname: Samia surname: Siddiqui fullname: Siddiqui, Samia organization: National Center of Excellence in Analytical Chemistry, University of Sindh, A-333, Phase 1, SUECHS, Jamshoro 76080, Pakistan |
| BookMark | eNp9kE1rFTEUhoNU8Lb6A9xl6WbGk_nITHAlRatQKEj3IR9n9FwyyTWZW-zKv25ur6suuggJ5H1eeJ9LdhFTRMbeC2gFCPlx35Zo2w7E2IJoQclXbCfmqW96mKYLtgPVjc0AML5hl6XsAWDoJezY3_tsIv4xKzluHHnuMdMDev4zBc-jielg8kYuYOFr8rTQ6S-YUh65M9mmyDGg23LyyE3hBWOhrTY8vVLmSz0eN8wrRbNRzael9gZ7PPyiiG_Z68WEgu_-31fsx9cv99ffmtu7m-_Xn28b1yu5NX6UUo3OKid8Nw2iEx4tuGlG6xapZI-ztaMU8wALqEmC6FRFrBpgWPor9uFcesjp9xHLplcqDkOo09OxaDHNFR1ra42Kc9TlVErGRR8yrSY_agH6ZFrvdTWtT6Y1CF1NV2Z6xjjanrZu2VB4kfx0JrFOfyDMujjC6NBTrlK1T_QC_Q9GtJ1l |
| CitedBy_id | crossref_primary_10_1016_j_snb_2017_02_111 crossref_primary_10_1016_j_snb_2016_02_094 crossref_primary_10_1016_j_snb_2016_04_065 crossref_primary_10_1177_0003702817724180 crossref_primary_10_1016_j_cej_2023_144976 crossref_primary_10_1016_j_snb_2017_12_162 crossref_primary_10_1149_1945_7111_abb3db crossref_primary_10_1007_s10854_021_06244_3 crossref_primary_10_1016_j_saa_2021_119645 crossref_primary_10_1016_j_jelechem_2017_11_020 crossref_primary_10_1149_2_0911702jes crossref_primary_10_1177_0883911520913900 crossref_primary_10_1016_j_jelechem_2019_03_002 crossref_primary_10_3390_catal8010029 crossref_primary_10_1007_s11664_017_5573_y crossref_primary_10_1149_1945_7111_ad97e8 crossref_primary_10_3390_s21041220 crossref_primary_10_1016_j_talanta_2018_03_011 crossref_primary_10_3390_ph17030282 crossref_primary_10_1016_j_microc_2020_105439 crossref_primary_10_1016_j_ijbiomac_2023_125384 crossref_primary_10_1016_j_jhazmat_2017_08_014 crossref_primary_10_1007_s10008_019_04298_2 crossref_primary_10_1088_1361_6528_ad0f58 crossref_primary_10_2139_ssrn_4089520 crossref_primary_10_1149_1945_7111_ad8a91 crossref_primary_10_1002_elan_201600221 crossref_primary_10_1039_C9BM01635J crossref_primary_10_2116_analsci_20P126 crossref_primary_10_1016_j_ab_2024_115595 crossref_primary_10_1016_j_mtcomm_2022_105198 crossref_primary_10_1111_jocd_15426 crossref_primary_10_1007_s00396_023_05086_1 crossref_primary_10_1016_j_ijpharm_2022_122411 crossref_primary_10_1016_j_jelechem_2024_118130 crossref_primary_10_1016_j_jmrt_2021_09_057 crossref_primary_10_1155_2016_8621234 crossref_primary_10_1007_s13738_022_02558_z crossref_primary_10_3390_molecules26226985 crossref_primary_10_1016_j_snb_2016_04_024 crossref_primary_10_1007_s10904_021_02186_9 crossref_primary_10_1007_s10904_023_02562_7 crossref_primary_10_1007_s40242_020_0339_0 crossref_primary_10_1016_j_aca_2022_340239 |
| Cites_doi | 10.1016/j.aca.2007.05.053 10.1016/j.talanta.2014.07.023 10.1007/BF03254280 10.1080/00032710701380475 10.1016/j.snb.2012.07.093 10.1016/j.aca.2013.01.052 10.1016/j.bios.2009.10.037 10.1021/la0358567 10.1016/j.electacta.2009.12.052 10.1016/j.snb.2011.04.082 10.1016/j.snb.2014.11.021 10.1016/S0378-4347(96)00374-X 10.1016/S0002-9378(02)70185-3 10.1016/0378-4347(88)80109-9 10.1016/j.bios.2012.04.027 10.1034/j.1399-6576.2001.045007795.x 10.1016/j.aca.2004.10.007 10.1021/nn204830b 10.1213/00000539-200009000-00019 10.1213/00000539-198711000-00015 10.1002/elan.200503415 10.1016/j.jhazmat.2011.04.047 10.1016/j.bpc.2006.07.008 10.1365/s10337-003-0146-z 10.4103/1658-354X.87265 10.1016/j.aca.2011.08.040 10.1111/j.1601-0825.2008.01507.x 10.1080/105504999305965 10.1021/la026906v 10.1016/0165-9936(88)85088-X 10.1016/S1452-3981(23)16939-2 10.3390/s10400102 10.1016/j.jchromb.2005.06.008 10.1034/j.1399-6576.2000.440808.x 10.1093/jat/31.1.62 10.1007/BF02704195 |
| ContentType | Journal Article |
| Copyright | 2015 Elsevier B.V. |
| Copyright_xml | – notice: 2015 Elsevier B.V. |
| DBID | AAYXX CITATION 7SP 7SR 7TB 7U5 8BQ 8FD FR3 JG9 L7M |
| DOI | 10.1016/j.snb.2015.01.096 |
| DatabaseName | CrossRef Electronics & Communications Abstracts Engineered Materials Abstracts Mechanical & Transportation Engineering Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Engineering Research Database Materials Research Database Advanced Technologies Database with Aerospace |
| DatabaseTitle | CrossRef Materials Research Database Engineered Materials Abstracts Technology Research Database Mechanical & Transportation Engineering Abstracts Electronics & Communications Abstracts Solid State and Superconductivity Abstracts Engineering Research Database Advanced Technologies Database with Aerospace METADEX |
| DatabaseTitleList | Materials Research Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1873-3077 |
| EndPage | 369 |
| ExternalDocumentID | 10_1016_j_snb_2015_01_096 S0925400515001239 |
| GroupedDBID | --K --M -~X .~1 0R~ 123 1B1 1RT 1~. 1~5 4.4 457 4G. 53G 5VS 7-5 71M 8P~ 9JN AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABFNM ABMAC ABXDB ABYKQ ACDAQ ACGFS ACNNM ACRLP ADBBV ADECG ADEZE ADMUD ADTZH AEBSH AECPX AEKER AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHJVU AIEXJ AIKHN AITUG AJBFU AJOXV AJQLL AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BJAXD BKOJK BLXMC CS3 EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HMU HVGLF HZ~ IHE J1W JJJVA KOM M36 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 PC. Q38 R2- RIG RNS ROL RPZ SCB SCC SCH SDF SDG SDP SES SEW SPC SPCBC SSK SST SSZ T5K TN5 WUQ XFK YK3 ~G- AATTM AAXKI AAYWO AAYXX ABWVN ACRPL ADNMO AEIPS AFJKZ AFXIZ AGCQF AGQPQ AGRNS AIIUN ANKPU APXCP BNPGV CITATION SSH 7SP 7SR 7TB 7U5 8BQ 8FD EFKBS FR3 JG9 L7M |
| ID | FETCH-LOGICAL-c396t-d56695cb9c1d274121deb0c78ebcf6963e8bb561840f09760129566b9404f3 |
| IEDL.DBID | .~1 |
| ISSN | 0925-4005 |
| IngestDate | Mon Jul 21 11:36:42 EDT 2025 Tue Jul 01 03:00:20 EDT 2025 Thu Apr 24 23:07:23 EDT 2025 Fri Feb 23 02:29:24 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Tranexamic acid Voltammetric sensor Serum and urine samples Gold nanoparticles Nalbuphine |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c396t-d56695cb9c1d274121deb0c78ebcf6963e8bb561840f09760129566b9404f3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| PQID | 1786185121 |
| PQPubID | 23500 |
| PageCount | 11 |
| ParticipantIDs | proquest_miscellaneous_1786185121 crossref_primary_10_1016_j_snb_2015_01_096 crossref_citationtrail_10_1016_j_snb_2015_01_096 elsevier_sciencedirect_doi_10_1016_j_snb_2015_01_096 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2015-05-01 |
| PublicationDateYYYYMMDD | 2015-05-01 |
| PublicationDate_xml | – month: 05 year: 2015 text: 2015-05-01 day: 01 |
| PublicationDecade | 2010 |
| PublicationTitle | Sensors and actuators. B, Chemical |
| PublicationYear | 2015 |
| Publisher | Elsevier B.V |
| Publisher_xml | – name: Elsevier B.V |
| References | Zhang, Gu, Ding, Zhang, Li (bib0345) 2013; 770 Lu, Song, Zhu, Wu, Song (bib0330) 2012; 7 Selvakannan, Mandal, Phadtare, Pasricha, Sastry (bib0310) 2003; 19 Rozenberg, Shoham (bib0315) 2007; 125 Culebras, Gaggero, Zatloukal, Kern, Marti (bib0200) 2000; 91 Sanghavi, Srivastava (bib0270) 2011; 706 Groenendaal, Blom-Roosemalen, Danhof, de Lange (bib0365) 2005; 822 Sirajuddin, Nafady, Afridi, Sara, Shah, Niaz (bib0295) 2011; 8 de Cazanove, Kinowski, Audran, Rochette, Bressolle (bib0190) 1997; 690 Kim, In, Paeng, Chung (bib0240) 2004; 59 Tagar, Sirajuddin, Memon, Agheem, Junejo, Hassan (bib0305) 2011; 157 Carralero Sanz, Mena, González-Cortés, Yáñez-Sedeño, Pingarrón (bib0265) 2005; 528 Suojanen, Sorsa, Salo (bib0370) 2009; 15 Walder, Schafer, Henzi, Tramer (bib0210) 2001; 45 Tom, Suryanarayanan, Reddy, Baskaran, Pradeep (bib0300) 2004; 20 Dube, Beaudoin, Lalande, McGilveray (bib0245) 1988; 427 Klinzig, Vinner, Brassart, Houdain, Humbert, Lhermitte (bib0220) 2007; 31 Jang, Condrate (bib0320) 1972; 57 Ghorbani-Bidkorbeh, Shahrokhian, Mohammadi, Dinarvand (bib0350) 2010; 55 Li, Song, Shan, Gao, Xu, Niu (bib0355) 2010; 25 Hassan, Nafady, Sirajuddin, Solangi, Kalhoro, Abro, Sherazi (bib0280) 2015; 208 Soomro, Nafady, Sirajuddin, Memon, Sherazi, Kalwar (bib0360) 2014; 130 de Jong, Maes, van Rossum (bib0225) 1988; 7 Alzeftawy, Amin, Fathy, Amr (bib0235) 2011; 5 Xiao, Zhao, Li, Yan, Yu, Zeng (bib0275) 2007; 596 Fournier, Van Gessel, Macksay, Gamulin (bib0205) 2000; 44 Luo, Morrin, Killard, Smyth (bib0260) 2006; 18 Hammock, Sokolov, Stoltenberg, Naab, Bao (bib0335) 2012; 6 Bricker, Lavender (bib0195) 2002; 186 Tagar, Sirajuddin, Memon, Kalhoro, O’Brien, Malik, Abro, Hassan, Kalwar, Junejo (bib0255) 2012; 173 Sharma, Gupta, Srivastava (bib0290) 2012; 37 Wines, Gruber, Pope, Lukas (bib0230) 1999; 8 Mandal, Selvakannan, Phadtare, Pasricha, Sastry (bib0285) 2002; 114 Hassan, Sirajuddin, Solangi, Agheem, Junejo, Kalwar (bib0325) 2011; 190 Ugo, Cavalieri, Rudello, Moretto, Argese (bib0340) 2001; 1 Zsigmond, Winnie, Raza, Wang, Barabas (bib0215) 1987; 66 El-Tohamy, El-Maamly, Shalaby, Aboul-Enein (bib0250) 2007; 40 Selvakannan (10.1016/j.snb.2015.01.096_bib0310) 2003; 19 Sirajuddin (10.1016/j.snb.2015.01.096_bib0295) 2011; 8 Alzeftawy (10.1016/j.snb.2015.01.096_bib0235) 2011; 5 Sharma (10.1016/j.snb.2015.01.096_bib0290) 2012; 37 Luo (10.1016/j.snb.2015.01.096_bib0260) 2006; 18 Hassan (10.1016/j.snb.2015.01.096_bib0325) 2011; 190 Tagar (10.1016/j.snb.2015.01.096_bib0255) 2012; 173 Carralero Sanz (10.1016/j.snb.2015.01.096_bib0265) 2005; 528 Ugo (10.1016/j.snb.2015.01.096_bib0340) 2001; 1 Wines (10.1016/j.snb.2015.01.096_bib0230) 1999; 8 Sanghavi (10.1016/j.snb.2015.01.096_bib0270) 2011; 706 Ghorbani-Bidkorbeh (10.1016/j.snb.2015.01.096_bib0350) 2010; 55 Bricker (10.1016/j.snb.2015.01.096_bib0195) 2002; 186 Culebras (10.1016/j.snb.2015.01.096_bib0200) 2000; 91 Klinzig (10.1016/j.snb.2015.01.096_bib0220) 2007; 31 El-Tohamy (10.1016/j.snb.2015.01.096_bib0250) 2007; 40 Hassan (10.1016/j.snb.2015.01.096_bib0280) 2015; 208 Rozenberg (10.1016/j.snb.2015.01.096_bib0315) 2007; 125 Fournier (10.1016/j.snb.2015.01.096_bib0205) 2000; 44 Walder (10.1016/j.snb.2015.01.096_bib0210) 2001; 45 Soomro (10.1016/j.snb.2015.01.096_bib0360) 2014; 130 Suojanen (10.1016/j.snb.2015.01.096_bib0370) 2009; 15 Hammock (10.1016/j.snb.2015.01.096_bib0335) 2012; 6 Tagar (10.1016/j.snb.2015.01.096_bib0305) 2011; 157 Tom (10.1016/j.snb.2015.01.096_bib0300) 2004; 20 de Cazanove (10.1016/j.snb.2015.01.096_bib0190) 1997; 690 de Jong (10.1016/j.snb.2015.01.096_bib0225) 1988; 7 Jang (10.1016/j.snb.2015.01.096_bib0320) 1972; 57 Zsigmond (10.1016/j.snb.2015.01.096_bib0215) 1987; 66 Dube (10.1016/j.snb.2015.01.096_bib0245) 1988; 427 Li (10.1016/j.snb.2015.01.096_bib0355) 2010; 25 Zhang (10.1016/j.snb.2015.01.096_bib0345) 2013; 770 Xiao (10.1016/j.snb.2015.01.096_bib0275) 2007; 596 Mandal (10.1016/j.snb.2015.01.096_bib0285) 2002; 114 Groenendaal (10.1016/j.snb.2015.01.096_bib0365) 2005; 822 Lu (10.1016/j.snb.2015.01.096_bib0330) 2012; 7 Kim (10.1016/j.snb.2015.01.096_bib0240) 2004; 59 |
| References_xml | – volume: 5 start-page: 371 year: 2011 end-page: 375 ident: bib0235 article-title: Maternal and neonatal effects of nalbuphine given immediately before induction of general anesthesia for elective cesarean section publication-title: Saudi J. Anaesth. – volume: 59 start-page: 219 year: 2004 end-page: 226 ident: bib0240 article-title: Simultaneous determination of nalbuphine and opiates in human hair by gas chromatography–mass spectrometry publication-title: Chromatographia – volume: 66 start-page: 1155 year: 1987 end-page: 1164 ident: bib0215 article-title: Nalbuphine as an analgesic component in balanced anesthesia for cardiac surgery publication-title: Anesth. Analg. – volume: 770 start-page: 53 year: 2013 end-page: 61 ident: bib0345 article-title: A novel sensor based on electropolymerization of β-cyclodextrin and publication-title: Anal. Chim. Acta – volume: 37 start-page: 30 year: 2012 end-page: 37 ident: bib0290 article-title: Modulating electron transfer properties of gold nanoparticles for efficient biosensing publication-title: Biosens. Bioelectron. – volume: 91 start-page: 601 year: 2000 end-page: 605 ident: bib0200 article-title: Advantages of intrathecal nalbuphine, compared with intrathecal morphine, after cesarean delivery: an evaluation of postoperative analgesia and adverse effects publication-title: Anesth. Analg. – volume: 44 start-page: 940 year: 2000 end-page: 945 ident: bib0205 article-title: Onset and offset of intrathecal morphine versus nalbuphine for postoperative pain relief after total hip replacement publication-title: Acta Anaesth. Scand. – volume: 208 start-page: 320 year: 2015 end-page: 326 ident: bib0280 article-title: Ultra-trace level electrochemical sensor for methylene blue dye based on nafion stabilized ibuprofen derived gold nanoparticles publication-title: Sens. Actuators B: Chem. – volume: 20 start-page: 1909 year: 2004 end-page: 1914 ident: bib0300 article-title: Ciprofloxacin-protected gold nanoparticles publication-title: Langmuir – volume: 114 start-page: 513 year: 2002 end-page: 520 ident: bib0285 article-title: Synthesis of a stable gold hydrosol by the reduction of chloroaurate ions by the amino acid, aspartic acid publication-title: J. Chem. Sci. – volume: 8 start-page: S34 year: 2011 end-page: S43 ident: bib0295 article-title: Direct synthesis and stabilization of Bi-sized cysteine-derived gold nanoparticles: reduction catalyst for methylene blue publication-title: J. Iran. Chem. Soc. – volume: 706 start-page: 246 year: 2011 end-page: 254 ident: bib0270 article-title: Simultaneous voltammetric determination of acetaminophen and tramadol using Dowex50wx2 and gold nanoparticles modified glassy carbon paste electrode publication-title: Anal. Chim. Acta – volume: 18 start-page: 319 year: 2006 end-page: 326 ident: bib0260 article-title: Application of nanoparticles in electrochemical sensors and biosensors publication-title: Electroanalysis – volume: 186 start-page: S94 year: 2002 end-page: S109 ident: bib0195 article-title: Parenteral opioids for labor pain relief: a systematic review publication-title: Am. J. Obstet. Gynecol. – volume: 528 start-page: 1 year: 2005 end-page: 8 ident: bib0265 article-title: Development of a tyrosinase biosensor based on gold nanoparticles-modified glassy carbon electrodes: application to the measurement of a bioelectrochemical polyphenols index in wines publication-title: Anal. Chim. Acta – volume: 1 start-page: 102 year: 2001 end-page: 113 ident: bib0340 article-title: Nafion coated electrodes as voltammetric sensors for iron analysis in sediments and pore waters: an example from the lagoon of Venice publication-title: Sensors – volume: 6 start-page: 3100 year: 2012 end-page: 3108 ident: bib0335 article-title: Organic transistors with ordered nanoparticle arrays as a tailorable platform for selective, in situ detection publication-title: ACS Nano – volume: 40 start-page: 1569 year: 2007 end-page: 1578 ident: bib0250 article-title: Development of nalbuphine-selective membrane electrode and its applications in pharmaceutical analysis publication-title: Anal. Lett. – volume: 596 start-page: 79 year: 2007 end-page: 85 ident: bib0275 article-title: Sensitive voltammetric determination of chloramphenicol by using single-wall carbon nanotube–gold nanoparticle–ionic liquid composite film modified glassy carbon electrodes publication-title: Anal. Chim. Acta – volume: 822 start-page: 230 year: 2005 end-page: 237 ident: bib0365 article-title: High-performance liquid chromatography of nalbuphine, butorphanol and morphine in blood and brain microdialysate samples: application to pharmacokinetic/pharmacodynamic studies in rats publication-title: J. Chromatgr. B – volume: 19 start-page: 3545 year: 2003 end-page: 3549 ident: bib0310 article-title: Capping of gold nanoparticles by the amino acid lysine renders them water-dispersible publication-title: Langmuir – volume: 173 start-page: 745 year: 2012 end-page: 751 ident: bib0255 article-title: Highly sensitive, selective and stable multi-metal ions sensor based on ibuprofen capped mercury nanoparticles publication-title: Sens. Actuators B: Chem. – volume: 190 start-page: 1030 year: 2011 end-page: 1036 ident: bib0325 article-title: Ultra-fast catalytic reduction of dyes by ionic liquid recoverable and reusable mefenamic acid derived gold nanoparticles publication-title: J. Hazard. Mater. – volume: 7 start-page: 11236 year: 2012 end-page: 11245 ident: bib0330 article-title: Synthesis of gold nanoparticles using cefopernazone as a stabilizing reagent and its application publication-title: Int. J. Electrochem. Sci. – volume: 130 start-page: 415 year: 2014 end-page: 422 ident: bib0360 article-title: L-cysteine protected copper nanoparticles as colorimetric sensor for mercuric ions publication-title: Talanta – volume: 125 start-page: 166 year: 2007 end-page: 171 ident: bib0315 article-title: FTIR spectra of solid poly-l-lysine in the stretching NH mode range publication-title: Biophys. Chem. – volume: 57 start-page: 494 year: 1972 end-page: 498 ident: bib0320 article-title: The infrared spectra of valine adsorbed on Cu-montmorillonite publication-title: Am. Mineral. – volume: 25 start-page: 1408 year: 2010 end-page: 1413 ident: bib0355 article-title: Electrochemical determination of morphine at ordered mesoporous carbon modified glassy carbon electrode publication-title: Biosens. Biolectron. – volume: 690 start-page: 203 year: 1997 end-page: 210 ident: bib0190 article-title: Determination of nalbuphine in human plasma by high-performance liquid chromatography with electrochemical detection. Application to a pharmacokinetic study publication-title: J. Chromatogr. B – volume: 7 start-page: 375 year: 1988 end-page: 382 ident: bib0225 article-title: Doping control of athletes publication-title: Trends Anal. Chem. – volume: 157 start-page: 430 year: 2011 end-page: 437 ident: bib0305 article-title: Selective, simple and economical lead sensor based on ibuprofen derived silver nanoparticles publication-title: Sens. Actuators B: Chem. – volume: 31 start-page: 62 year: 2007 end-page: 65 ident: bib0220 article-title: Hair analysis by LC–MS as evidence of nalbuphine abuse by a nurse publication-title: J. Anal. Toxicol. – volume: 55 start-page: 2752 year: 2010 end-page: 2759 ident: bib0350 article-title: Simultaneous voltammetric determination of tramadol and acetaminophen using carbon nanoparticles modified glassy carbon electrode publication-title: Electrochim. Acta – volume: 427 start-page: 113 year: 1988 end-page: 120 ident: bib0245 article-title: Determination of nalbuphine by high-performance liquid chromatography with electrochemical detection: application to clinical samples from postoperative patients publication-title: J. Chromatogr. – volume: 45 start-page: 795 year: 2001 end-page: 804 ident: bib0210 article-title: Efficacy and safety of patient-controlled opioid analgesia for acute postoperative pain. A quantitative systematic review publication-title: Acta Anaesth. Scand. – volume: 8 start-page: 161 year: 1999 end-page: 164 ident: bib0230 article-title: Nalbuphine hydrochloride dependence in anabolic steroid users publication-title: Am. J. Addict. – volume: 15 start-page: 170 year: 2009 end-page: 175 ident: bib0370 article-title: Tranexamic acid can inhibit tongue squamous cell carcinoma invasion in vitro publication-title: Oral Dis. – volume: 596 start-page: 79 year: 2007 ident: 10.1016/j.snb.2015.01.096_bib0275 article-title: Sensitive voltammetric determination of chloramphenicol by using single-wall carbon nanotube–gold nanoparticle–ionic liquid composite film modified glassy carbon electrodes publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2007.05.053 – volume: 130 start-page: 415 year: 2014 ident: 10.1016/j.snb.2015.01.096_bib0360 article-title: L-cysteine protected copper nanoparticles as colorimetric sensor for mercuric ions publication-title: Talanta doi: 10.1016/j.talanta.2014.07.023 – volume: 8 start-page: S34 year: 2011 ident: 10.1016/j.snb.2015.01.096_bib0295 article-title: Direct synthesis and stabilization of Bi-sized cysteine-derived gold nanoparticles: reduction catalyst for methylene blue publication-title: J. Iran. Chem. Soc. doi: 10.1007/BF03254280 – volume: 40 start-page: 1569 year: 2007 ident: 10.1016/j.snb.2015.01.096_bib0250 article-title: Development of nalbuphine-selective membrane electrode and its applications in pharmaceutical analysis publication-title: Anal. Lett. doi: 10.1080/00032710701380475 – volume: 173 start-page: 745 year: 2012 ident: 10.1016/j.snb.2015.01.096_bib0255 article-title: Highly sensitive, selective and stable multi-metal ions sensor based on ibuprofen capped mercury nanoparticles publication-title: Sens. Actuators B: Chem. doi: 10.1016/j.snb.2012.07.093 – volume: 770 start-page: 53 year: 2013 ident: 10.1016/j.snb.2015.01.096_bib0345 article-title: A novel sensor based on electropolymerization of β-cyclodextrin and l-arginine on carbon paste electrode for determination of fluoroquinolones publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2013.01.052 – volume: 25 start-page: 1408 year: 2010 ident: 10.1016/j.snb.2015.01.096_bib0355 article-title: Electrochemical determination of morphine at ordered mesoporous carbon modified glassy carbon electrode publication-title: Biosens. Biolectron. doi: 10.1016/j.bios.2009.10.037 – volume: 20 start-page: 1909 year: 2004 ident: 10.1016/j.snb.2015.01.096_bib0300 article-title: Ciprofloxacin-protected gold nanoparticles publication-title: Langmuir doi: 10.1021/la0358567 – volume: 55 start-page: 2752 year: 2010 ident: 10.1016/j.snb.2015.01.096_bib0350 article-title: Simultaneous voltammetric determination of tramadol and acetaminophen using carbon nanoparticles modified glassy carbon electrode publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2009.12.052 – volume: 157 start-page: 430 year: 2011 ident: 10.1016/j.snb.2015.01.096_bib0305 article-title: Selective, simple and economical lead sensor based on ibuprofen derived silver nanoparticles publication-title: Sens. Actuators B: Chem. doi: 10.1016/j.snb.2011.04.082 – volume: 208 start-page: 320 year: 2015 ident: 10.1016/j.snb.2015.01.096_bib0280 article-title: Ultra-trace level electrochemical sensor for methylene blue dye based on nafion stabilized ibuprofen derived gold nanoparticles publication-title: Sens. Actuators B: Chem. doi: 10.1016/j.snb.2014.11.021 – volume: 690 start-page: 203 year: 1997 ident: 10.1016/j.snb.2015.01.096_bib0190 article-title: Determination of nalbuphine in human plasma by high-performance liquid chromatography with electrochemical detection. Application to a pharmacokinetic study publication-title: J. Chromatogr. B doi: 10.1016/S0378-4347(96)00374-X – volume: 186 start-page: S94 year: 2002 ident: 10.1016/j.snb.2015.01.096_bib0195 article-title: Parenteral opioids for labor pain relief: a systematic review publication-title: Am. J. Obstet. Gynecol. doi: 10.1016/S0002-9378(02)70185-3 – volume: 57 start-page: 494 year: 1972 ident: 10.1016/j.snb.2015.01.096_bib0320 article-title: The infrared spectra of valine adsorbed on Cu-montmorillonite publication-title: Am. Mineral. – volume: 427 start-page: 113 year: 1988 ident: 10.1016/j.snb.2015.01.096_bib0245 article-title: Determination of nalbuphine by high-performance liquid chromatography with electrochemical detection: application to clinical samples from postoperative patients publication-title: J. Chromatogr. doi: 10.1016/0378-4347(88)80109-9 – volume: 37 start-page: 30 year: 2012 ident: 10.1016/j.snb.2015.01.096_bib0290 article-title: Modulating electron transfer properties of gold nanoparticles for efficient biosensing publication-title: Biosens. Bioelectron. doi: 10.1016/j.bios.2012.04.027 – volume: 45 start-page: 795 year: 2001 ident: 10.1016/j.snb.2015.01.096_bib0210 article-title: Efficacy and safety of patient-controlled opioid analgesia for acute postoperative pain. A quantitative systematic review publication-title: Acta Anaesth. Scand. doi: 10.1034/j.1399-6576.2001.045007795.x – volume: 528 start-page: 1 year: 2005 ident: 10.1016/j.snb.2015.01.096_bib0265 article-title: Development of a tyrosinase biosensor based on gold nanoparticles-modified glassy carbon electrodes: application to the measurement of a bioelectrochemical polyphenols index in wines publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2004.10.007 – volume: 6 start-page: 3100 issue: 4 year: 2012 ident: 10.1016/j.snb.2015.01.096_bib0335 article-title: Organic transistors with ordered nanoparticle arrays as a tailorable platform for selective, in situ detection publication-title: ACS Nano doi: 10.1021/nn204830b – volume: 91 start-page: 601 year: 2000 ident: 10.1016/j.snb.2015.01.096_bib0200 article-title: Advantages of intrathecal nalbuphine, compared with intrathecal morphine, after cesarean delivery: an evaluation of postoperative analgesia and adverse effects publication-title: Anesth. Analg. doi: 10.1213/00000539-200009000-00019 – volume: 66 start-page: 1155 year: 1987 ident: 10.1016/j.snb.2015.01.096_bib0215 article-title: Nalbuphine as an analgesic component in balanced anesthesia for cardiac surgery publication-title: Anesth. Analg. doi: 10.1213/00000539-198711000-00015 – volume: 18 start-page: 319 year: 2006 ident: 10.1016/j.snb.2015.01.096_bib0260 article-title: Application of nanoparticles in electrochemical sensors and biosensors publication-title: Electroanalysis doi: 10.1002/elan.200503415 – volume: 190 start-page: 1030 year: 2011 ident: 10.1016/j.snb.2015.01.096_bib0325 article-title: Ultra-fast catalytic reduction of dyes by ionic liquid recoverable and reusable mefenamic acid derived gold nanoparticles publication-title: J. Hazard. Mater. doi: 10.1016/j.jhazmat.2011.04.047 – volume: 125 start-page: 166 year: 2007 ident: 10.1016/j.snb.2015.01.096_bib0315 article-title: FTIR spectra of solid poly-l-lysine in the stretching NH mode range publication-title: Biophys. Chem. doi: 10.1016/j.bpc.2006.07.008 – volume: 59 start-page: 219 year: 2004 ident: 10.1016/j.snb.2015.01.096_bib0240 article-title: Simultaneous determination of nalbuphine and opiates in human hair by gas chromatography–mass spectrometry publication-title: Chromatographia doi: 10.1365/s10337-003-0146-z – volume: 5 start-page: 371 year: 2011 ident: 10.1016/j.snb.2015.01.096_bib0235 article-title: Maternal and neonatal effects of nalbuphine given immediately before induction of general anesthesia for elective cesarean section publication-title: Saudi J. Anaesth. doi: 10.4103/1658-354X.87265 – volume: 706 start-page: 246 year: 2011 ident: 10.1016/j.snb.2015.01.096_bib0270 article-title: Simultaneous voltammetric determination of acetaminophen and tramadol using Dowex50wx2 and gold nanoparticles modified glassy carbon paste electrode publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2011.08.040 – volume: 15 start-page: 170 year: 2009 ident: 10.1016/j.snb.2015.01.096_bib0370 article-title: Tranexamic acid can inhibit tongue squamous cell carcinoma invasion in vitro publication-title: Oral Dis. doi: 10.1111/j.1601-0825.2008.01507.x – volume: 8 start-page: 161 year: 1999 ident: 10.1016/j.snb.2015.01.096_bib0230 article-title: Nalbuphine hydrochloride dependence in anabolic steroid users publication-title: Am. J. Addict. doi: 10.1080/105504999305965 – volume: 19 start-page: 3545 year: 2003 ident: 10.1016/j.snb.2015.01.096_bib0310 article-title: Capping of gold nanoparticles by the amino acid lysine renders them water-dispersible publication-title: Langmuir doi: 10.1021/la026906v – volume: 7 start-page: 375 year: 1988 ident: 10.1016/j.snb.2015.01.096_bib0225 article-title: Doping control of athletes publication-title: Trends Anal. Chem. doi: 10.1016/0165-9936(88)85088-X – volume: 7 start-page: 11236 year: 2012 ident: 10.1016/j.snb.2015.01.096_bib0330 article-title: Synthesis of gold nanoparticles using cefopernazone as a stabilizing reagent and its application publication-title: Int. J. Electrochem. Sci. doi: 10.1016/S1452-3981(23)16939-2 – volume: 1 start-page: 102 year: 2001 ident: 10.1016/j.snb.2015.01.096_bib0340 article-title: Nafion coated electrodes as voltammetric sensors for iron analysis in sediments and pore waters: an example from the lagoon of Venice publication-title: Sensors doi: 10.3390/s10400102 – volume: 822 start-page: 230 year: 2005 ident: 10.1016/j.snb.2015.01.096_bib0365 article-title: High-performance liquid chromatography of nalbuphine, butorphanol and morphine in blood and brain microdialysate samples: application to pharmacokinetic/pharmacodynamic studies in rats publication-title: J. Chromatgr. B doi: 10.1016/j.jchromb.2005.06.008 – volume: 44 start-page: 940 year: 2000 ident: 10.1016/j.snb.2015.01.096_bib0205 article-title: Onset and offset of intrathecal morphine versus nalbuphine for postoperative pain relief after total hip replacement publication-title: Acta Anaesth. Scand. doi: 10.1034/j.1399-6576.2000.440808.x – volume: 31 start-page: 62 year: 2007 ident: 10.1016/j.snb.2015.01.096_bib0220 article-title: Hair analysis by LC–MS as evidence of nalbuphine abuse by a nurse publication-title: J. Anal. Toxicol. doi: 10.1093/jat/31.1.62 – volume: 114 start-page: 513 year: 2002 ident: 10.1016/j.snb.2015.01.096_bib0285 article-title: Synthesis of a stable gold hydrosol by the reduction of chloroaurate ions by the amino acid, aspartic acid publication-title: J. Chem. Sci. doi: 10.1007/BF02704195 |
| SSID | ssj0004360 |
| Score | 2.3547668 |
| Snippet | •Facile synthesis of AuNps using tranexamic acid as reducing and capping agent.•Characterization of synthesized AuNps.•Fabrication of new sensor by utilizing... We display a simple chemical procedure for fabrication of spherical gold nanoparticles (AuNps) using tranexamic acid (Tr) as reducing as well as capping agent.... |
| SourceID | proquest crossref elsevier |
| SourceType | Aggregation Database Enrichment Source Index Database Publisher |
| StartPage | 359 |
| SubjectTerms | Electrodes Fourier transforms Glassy carbon Gold Gold nanoparticles Nalbuphine Sensors Serum and urine samples Serums Spectroscopy Tranexamic acid Urine Voltammetric sensor |
| Title | Tranexamic acid derived gold nanoparticles modified glassy carbon electrode as sensitive sensor for determination of nalbuphine |
| URI | https://dx.doi.org/10.1016/j.snb.2015.01.096 https://www.proquest.com/docview/1786185121 |
| Volume | 211 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT9wwELbQcoFDBaVVaQtyJU6V0rU3zsNHhEBbEBygSHuz4lebaklW-0BwKX-dGccpLao49JbEDzkee-Yb-fMMIQc6Z94Y75OS8yoRppCJZkWRZFVV5S7jmgVH8fwiH1-L00k2WSNH_V0YpFVG3d_p9KCt45dhnM3hrK6HV0yCcxNylARggJf4hChwlX_59UTzEGm4KYyVE6zdn2wGjtei0cju6iJ3Ytz-f9umZ1o6mJ6TLfIqYkZ62A1rm6y55jXZ_COS4A55QJvj7jC5PK1MbamFgltn6fd2amlTNeAbRwocvWlt7WssQ-R8T001121DY0Ic62i1oAvktaMmDE_tnAK2hT4jdQaFSVsP_U71avYDhvGGXJ4cfzsaJzG3QmJSmS8TCzBOZkZLwy1GsBlx6zQzRem08TnsSldqnWE2GOaZROLMCDypXEvBhE_fkkHTNu4doakxuStlOSoycEyYlamwzHOfOZZZ8OV2CeunVJkYdRyTX0xVTy_7qUAKCqWgGFcghV3y-XeTWRdy46XKopeT-mvdKDAJLzX71MtUwX7CQxKQUrtaKF6U8NcAg_j7_-v6A9nAt44U-ZEMlvOV2wPgstT7YWXuk_XDr2fji0fO2e7V |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9QwELZKewAOiPIQhUKNBBeksHbePvSAoNWWPg5QpF6QFb9oqiVZbXaBXtq_xE9kxnFKQagHBLcojkfOzHge8ucZQp6pnDmtnYtKzqso1YWIFCuKKKuqKrcZV8wnivsH-fhD-vYoO1oi34e7MAirDLa_t-neWoc3o8DN0bSuR--ZgOTG9yjxgYEIyMpde_oV8rZuc-cNCPl5HG9vHb4eR6G1QKQTkc8jA1GMyLQSmhss4BJzYxXTRWmVdjkopS2VyrAZCnNMIG4khkQiVyJlqUuA6DWykoKtwJ4JL89-gkrSxN9LxqVFuLbhHNUjyrpGIZasrxOKXQL-7Al_8wne0W3fJrdChEpf9UxYJUu2uUNuXqpbeJeco4ez37CVPa10baiBgS_W0E_txNCmaiATD4A7-rk1tatxDOP0U6qrmWobGtrvGEurjnaIoke765_aGYVIGmgGoA6qDm0d0J2oxfQYlnGPvPv37L5Plpu2sQ8ITbTObSnKuMggDWJGJKlhjrvMssxA5rhG2MBSqUONc2y1MZEDmO1EghQkSkEyLkEKa-TFxZRpX-Djqo_TQU7yFy2V4ICumvZ0kKmE3YtHMiCldtFJXpTw1xB08Yd_R3qDXB8f7u_JvZ2D3UfkBo70cMx1sjyfLexjCJnm6onXUko-_tc98QOCCSda |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Tranexamic+acid+derived+gold+nanoparticles+modified+glassy+carbon+electrode+as+sensitive+sensor+for+determination+of+nalbuphine&rft.jtitle=Sensors+and+actuators.+B%2C+Chemical&rft.au=Shaikh%2C+Tayyaba&rft.au=Nafady%2C+Ayman&rft.au=Talpur%2C+Farah+N&rft.au=Agheem%2C+Muhammad+H&rft.date=2015-05-01&rft.issn=0925-4005&rft.volume=211&rft.spage=359&rft.epage=369&rft_id=info:doi/10.1016%2Fj.snb.2015.01.096&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0925-4005&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0925-4005&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0925-4005&client=summon |