Effects of short-time heat treatment and subsequent chemical surface treatment on the mechanical properties, low-cycle fatigue behavior and corrosion resistance of a Ni–Ti (50.9at.% Ni) biomedical alloy wire used for the manufacture of stents

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Vol. 528; no. 3; pp. 1864 - 1876
• Main Authors: Vojtěch, D., Voděrová, M., Kubásek, J., Novák, P., Šedá, P., Michalcová, A., Fojt, J., Hanuš, J., Mestek, O.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 25.01.2011; Elsevier
• Subjects: Applied sciences; Corrosion; Corrosion prevention; Exact sciences and technology; Fatigue; Fracture; Mechanical characterization; Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology; Metals. Metallurgy; Other surface treatments; Oxidation; Production techniques; Shape memory alloys; Surface treatment; Fatigue; Fracture; Oxidation; Shape memory alloys; Mechanical characterization; Titanium alloy; Fatigue life; Annealing; Heat treatment; Intermetallic compound; Cold drawing; Chemical etching; Stent; Tension test; Low cycle fatigue; Tensile strength; Surface treatment; Corrosion resistance; Transmission electron microscopy; Shape memory alloy; Transition metal alloy; Chemical treatment; Biomaterial; Nickel alloy
• ISSN: 0921-5093; 1873-4936
• DOI: 10.1016/j.msea.2010.10.043

▶ Effect of short-time heat treatments on functional properties of a NiTi alloy. ▶ Negative effect of heat treatments on corrosion resistance. ▶ Positive effect of heat treatments on fatigue life. ▶ Positive influence of chemical treatment on both fatigue and corrosion resistance. Cold-drawn and straight-annealed NiTi wires (50.9% Ni) with a tensile strength of 1650MPa were subjected to heat treatments at 450, 510 and 600°C for 10min in air to simulate the shape-setting process in the manufacture of stents. Afterwards, the wires were chemically etched in acidic baths containing HF, HNO3 and H2O, followed by boiling in water. Variations in the internal structure, surface state and chemistry and transformation behavior of the wires due to these treatments were examined in detail by scanning and transmission electron microscopy, energy dispersion spectrometry, glow discharge spectrometry, X-ray photoelectron spectroscopy and differential scanning calorimetry. Mechanical properties were determined by tensile tests, and low-cycle fatigue behavior was measured by bend-type cyclic loading tests. Corrosion behavior was assessed by immersion tests and potentiodynamic measurements. A high tensile strength of the wire was shown to be attributable to a very fine-grained structure and work hardening. Heat treatment at 450–510°C/10min did not significantly affect the tensile strength of the wire. At 600°C/10min, the strength decreased by about 600MPa due to recrystallization. The transformation temperatures first slightly increased after heat treatment at 450°C and then reduced after treatments at higher temperatures due to changes in the composition of the B2 phase. The fatigue life was observed to prolong with both heat treatment and chemical etching. In contrast, the corrosion resistance worsened with heat treatment, but it improved significantly upon chemical etching. The observed behaviors are discussed in relation to the structural and chemical characteristics of the wires subjected to various treatment regimes.