Modulated synthesis and isoreticular expansion of Th-MOFs with record high pore volume and surface area for iodine adsorption

• Published in: Chemical communications (Cambridge, England) Vol. 56; no. 49; pp. 6715 - 6718
• Main Authors: Li, Zi-Jian, Ju, Yu, Yu, Bowen, Wu, Xiaoling, Lu, Huangjie, Li, Yongxin, Zhou, Jing, Guo, Xiaofeng, Zhang, Zhi-Hui, Lin, Jian, Wang, Jian-Qiang, Wang, Shuao
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 18.06.2020
• Subjects: Adsorption; chemical reactions; Crystallography; Iodine; Porosity; Surface area; Surface chemistry; Synthesis; Thorium

Modulated synthesis and isoreticular expansion of Th-MOFs enable the stepwise construction of hierarchical complexes in which porosity and functionality can be fine-tuned, affording new Th-MOFs with a record high void space (74.0%), the largest surface area (3396.5 m 2 g −1 ) among thorium materials...