Oxidation of Thiols. IV. The Effect of Substituents on Ionization and Hexacyanoferrate (III) Oxidation of Monothiodiacylmethane
Ionization constants, pKa, for a set of six monothiodiacylmethanes have been determined in 50 vol% ethanol-water mixture at 25°±0.1. Excellent linear correlations are obtained when pKa values are plotted against the substituent constant, σx, and the polar substituent constant, σ*xC6H4, for substitut...
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Published in | Chemical & pharmaceutical bulletin Vol. 27; no. 3; pp. 620 - 624 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Tokyo
The Pharmaceutical Society of Japan
1979
Japan Science and Technology Agency |
Subjects | |
Online Access | Get full text |
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