Electrochemical Mechanism of the Preparation of High-Purity Indium by Electrodeposition

• Published in: Frontiers in chemistry Vol. 10; p. 871420
• Main Authors: Hou, Zhongmin, Wang, Xiaomin, Li, Jidong, Li, Zhen, Wang, Yiyong, Xing, Hongxuan
• Format: Journal Article
• Language: English
• Published: Switzerland Frontiers Media S.A 24.05.2022
• Subjects: Chemistry; cyclic voltammetry; electrodeposition; indium; indium sulfate; nucleation mechanism; indium; nucleation mechanism; cyclic voltammetry; electrodeposition; indium sulfate
• ISSN: 2296-2646; 2296-2646
• DOI: 10.3389/fchem.2022.871420

Indium is a crucial material and is widely used in high-tech industries, and electrodeposition is an efficient method to recover rare metal resources. In this work, the electrochemical behavior of In 3+ was investigated by using different electrochemical methods in electrolytes containing sodium and indium sulfate. Cyclic voltammetry (CV), chronoamperometry (CA), and alternating current impedance (EIS) techniques were used to investigate the reduction reaction of In 3+ and the electrocrystallization mechanism of indium in the indium sulfate system. The cyclic voltammetry results showed that the electrodeposition process is irreversible. The average charge transfer coefficient a of In 3+ was calculated to be 0.116 from the relationship between the cathodic peak potential and the half-peak potential, and the H + discharge occurred at a higher negative potential of In 3+ . The nucleation mechanism of indium electrodeposition was analyzed by chronoamperometry. The mechanism of indium at potential steps of −0.3 to −0.6 V was close to diffusion-controlled instantaneous nucleation with a diffusion coefficient of 7.31 × 10 −9 cm 2  s −1 . The EIS results demonstrated that the reduction process of In 3+ is subject to a diffusion-controlled step when pH = 2.5 and the applied potential was −0.5 V. SEM and XRD techniques indicated that the cathodic products deposited on the titanium electrode have excellent cleanliness and purity.