A flexible pH sensor based on the iridium oxide sensing film

We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol–gel fabrication process of iridium oxide (IrO x ) sensing film. A pair of miniature IrO x /AgCl electrodes on a flexible substrate generated electrical potentials in solutions by electrochemical mechanisms re...

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Published inSensors and actuators. A. Physical. Vol. 169; no. 1; pp. 1 - 11
Main Authors Huang, Wen-Ding, Cao, Hung, Deb, Sanchali, Chiao, Mu, Chiao, J.C.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 10.09.2011
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Abstract We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol–gel fabrication process of iridium oxide (IrO x ) sensing film. A pair of miniature IrO x /AgCl electrodes on a flexible substrate generated electrical potentials in solutions by electrochemical mechanisms responding to their pH levels. Our flexible IrO x pH sensors exhibited promising sensing performance with a near-Nernstian response in sensitivity repeatedly and reversibly between −51.1 mV/pH and −51.7 mV/pH in the pH range between 1.5 and 12 at 25 °C. The fabrication processes including sol–gel deposition, thermal oxidation, and AgCl electro-plating on polymeric substrates were reported. The performance and characterization of the flexible pH sensors in sensitivity, response time, stability, reversibility, repeatability and selectivity were also discussed. Our IrO x pH electrodes on a deformable substrate demonstrated their sensing capability while they were conformed to a curved surface inside a limited space with distinct responding potentials at various pH levels similar to the traditional glass-rod pH electrodes.
AbstractList We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol-gel fabrication process of iridium oxide (IrO sub(x) sensing film. A pair of miniature IrO) sub(x)/AgCl electrodes on a flexible substrate generated electrical potentials in solutions by electrochemical mechanisms responding to their pH levels. Our flexible IrO sub(x pH sensors exhibited promising sensing performance with a near-Nernstian response in sensitivity repeatedly and reversibly between -51.1 mV/pH and -51.7 mV/pH in the pH range between 1.5 and 12 at 25 [deg]C. The fabrication processes including sol-gel deposition, thermal oxidation, and AgCl electro-plating on polymeric substrates were reported. The performance and characterization of the flexible pH sensors in sensitivity, response time, stability, reversibility, repeatability and selectivity were also discussed. Our IrO) sub(x) pH electrodes on a deformable substrate demonstrated their sensing capability while they were conformed to a curved surface inside a limited space with distinct responding potentials at various pH levels similar to the traditional glass-rod pH electrodes.
We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol–gel fabrication process of iridium oxide (IrOₓ) sensing film. A pair of miniature IrOₓ/AgCl electrodes on a flexible substrate generated electrical potentials in solutions by electrochemical mechanisms responding to their pH levels. Our flexible IrOₓ pH sensors exhibited promising sensing performance with a near-Nernstian response in sensitivity repeatedly and reversibly between −51.1mV/pH and −51.7mV/pH in the pH range between 1.5 and 12 at 25°C. The fabrication processes including sol–gel deposition, thermal oxidation, and AgCl electro-plating on polymeric substrates were reported. The performance and characterization of the flexible pH sensors in sensitivity, response time, stability, reversibility, repeatability and selectivity were also discussed. Our IrOₓ pH electrodes on a deformable substrate demonstrated their sensing capability while they were conformed to a curved surface inside a limited space with distinct responding potentials at various pH levels similar to the traditional glass-rod pH electrodes.
We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol–gel fabrication process of iridium oxide (IrO x ) sensing film. A pair of miniature IrO x /AgCl electrodes on a flexible substrate generated electrical potentials in solutions by electrochemical mechanisms responding to their pH levels. Our flexible IrO x pH sensors exhibited promising sensing performance with a near-Nernstian response in sensitivity repeatedly and reversibly between −51.1 mV/pH and −51.7 mV/pH in the pH range between 1.5 and 12 at 25 °C. The fabrication processes including sol–gel deposition, thermal oxidation, and AgCl electro-plating on polymeric substrates were reported. The performance and characterization of the flexible pH sensors in sensitivity, response time, stability, reversibility, repeatability and selectivity were also discussed. Our IrO x pH electrodes on a deformable substrate demonstrated their sensing capability while they were conformed to a curved surface inside a limited space with distinct responding potentials at various pH levels similar to the traditional glass-rod pH electrodes.
Author Cao, Hung
Deb, Sanchali
Huang, Wen-Ding
Chiao, Mu
Chiao, J.C.
Author_xml – sequence: 1
  givenname: Wen-Ding
  surname: Huang
  fullname: Huang, Wen-Ding
  email: hendiauhuang@yahoo.com
  organization: Department of Electrical Engineering, University of Texas at Arlington, Arlington, TX 76019-0016, USA
– sequence: 2
  givenname: Hung
  surname: Cao
  fullname: Cao, Hung
  organization: Department of Electrical Engineering, University of Texas at Arlington, Arlington, TX 76019-0016, USA
– sequence: 3
  givenname: Sanchali
  surname: Deb
  fullname: Deb, Sanchali
  organization: Department of Electrical Engineering, University of Texas at Arlington, Arlington, TX 76019-0016, USA
– sequence: 4
  givenname: Mu
  surname: Chiao
  fullname: Chiao, Mu
  organization: Department of Mechanical Engineering, University of British Columbia, Vancouver, BC V6T1Z4, Canada
– sequence: 5
  givenname: J.C.
  surname: Chiao
  fullname: Chiao, J.C.
  organization: Department of Electrical Engineering, University of Texas at Arlington, Arlington, TX 76019-0016, USA
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Issue 1
Keywords Miniature pH sensor array
Iridium oxide
Deformable sensors
Sol–gel process
Polyimide flexible substrate
Language English
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Snippet We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol–gel fabrication process of iridium oxide (IrO x ) sensing film. A...
We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol-gel fabrication process of iridium oxide (IrO sub(x) sensing film....
We have developed a novel flexible pH sensor based on a polymeric substrate by low-cost sol–gel fabrication process of iridium oxide (IrOₓ) sensing film. A...
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SubjectTerms Deformable sensors
Detection
Electric potential
electrochemistry
Electrodes
Iridium
Iridium oxide
Miniature pH sensor array
oxidation
Oxides
Polyimide flexible substrate
Sensors
silver chloride
Sol gel process
Title A flexible pH sensor based on the iridium oxide sensing film
URI https://dx.doi.org/10.1016/j.sna.2011.05.016
https://www.proquest.com/docview/1671309125
https://www.proquest.com/docview/1746368711
https://www.proquest.com/docview/896191203
Volume 169
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