Fluoride shuttle batteries: On the performance of the BiF3 electrode in organic liquid electrolytes containing a mixture of lithium bis(oxalato)borate and triphenylboroxin

• Published in: Solid state ionics Vol. 357; no. C; p. 115499
• Main Authors: Celik Kucuk, Asuman, Yamanaka, Toshiro, Abe, Takeshi
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.12.2020; Elsevier BV; Elsevier
• Subjects: Anions; Batteries; Boron; Cations; Cesium fluorides; Electrochemical analysis; Electrodes; Electrolytes; Fluoride shuttle battery; Fluorine; Ion currents; LiBOB; Lithium; Microparticles; Organic liquids; Organic-liquid electrolyte; Reaction mechanisms; Redox reactions; Room temperature; Stability; Studies; Fluoride shuttle battery; Organic-liquid electrolyte; Room temperature; LiBOB

In a typical organic liquid electrolyte-based fluoride shuttle battery (FSB), a high concentration of a boron-based anion acceptor (AA) capable of binding specific anions is required to provide a sufficient amount of dissolved fluoride salt. In this study, and a mixture of lithium bis(oxalato)borate...