Micro-explosion and burning characteristics of a single droplet of pyrolytic oil from castor seeds
•Castor pyrolytic oil exhibits a smaller micro-explosion than that of emulsion fuel.•The residue after combustion is only 0.18% of the weight of the pyrolytic oil.•Three different stages of micro-explosion are identified.•During the combustion process, the variation of droplet diameter follows d2-la...
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Published in | Applied thermal engineering Vol. 114; pp. 1053 - 1063 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Oxford
Elsevier Ltd
05.03.2017
Elsevier BV |
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Abstract | •Castor pyrolytic oil exhibits a smaller micro-explosion than that of emulsion fuel.•The residue after combustion is only 0.18% of the weight of the pyrolytic oil.•Three different stages of micro-explosion are identified.•During the combustion process, the variation of droplet diameter follows d2-law.
In the study, castor pyrolytic oil is produced from castor seeds by thermal pyrolysis and its pyrolysis reaction and oxidation reactions are investigated using thermogravimetric analysis. The results are also used to evaluate the characteristic combustion properties, such as the ignition temperature, burnout temperature and combustion characteristics index. The suspended droplet experimental system is also used to explore the micro-explosion phenomena and combustion modes of castor pyrolytic oil under different ambient temperatures. The castor pyrolytic oil is a multi-component fuel and has a complex process during the heating process and micro-explosion occurs, causing the droplet surface distortion. According to the timing and strength of the micro-explosion, there are three different stages: low intensity micro-explosion in the first stage, high intensity micro-explosion in the second stage and medium intensity micro-explosion in the final stage. After high-intensity micro-explosion occurred at 550°C, more volatile vapors were released and the flammable mixture will formed a flame wrapping around droplets after ignition. During the droplet combustion process, the micro-explosion occurred continuously, but the droplet still maintained a sphere-like appearance. The variation of droplet size generally followed d2-law and the combustion rate constant is approximately 1.483mm2/s. |
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AbstractList | In the study, castor pyrolytic oil is produced from castor seeds by thermal pyrolysis and its pyrolysis reaction and oxidation reactions are investigated using thermogravimetric analysis. The results are also used to evaluate the characteristic combustion properties, such as the ignition temperature, burnout temperature and combustion characteristics index. The suspended droplet experimental system is also used to explore the micro-explosion phenomena and combustion modes of castor pyrolytic oil under different ambient temperatures. The castor pyrolytic oil is a multi-component fuel and has a complex process during the heating process and micro-explosion occurs, causing the droplet surface distortion. According to the timing and strength of the micro-explosion, there are three different stages: low intensity micro-explosion in the first stage, high intensity micro-explosion in the second stage and medium intensity micro-explosion in the final stage. After high-intensity micro-explosion occurred at 550 °C, more volatile vapors were released and the flammable mixture will formed a flame wrapping around droplets after ignition. During the droplet combustion process, the micro-explosion occurred continuously, but the droplet still maintained a sphere-like appearance. The variation of droplet size generally followed d2-law and the combustion rate constant is approximately 1.483 mm2/s. •Castor pyrolytic oil exhibits a smaller micro-explosion than that of emulsion fuel.•The residue after combustion is only 0.18% of the weight of the pyrolytic oil.•Three different stages of micro-explosion are identified.•During the combustion process, the variation of droplet diameter follows d2-law. In the study, castor pyrolytic oil is produced from castor seeds by thermal pyrolysis and its pyrolysis reaction and oxidation reactions are investigated using thermogravimetric analysis. The results are also used to evaluate the characteristic combustion properties, such as the ignition temperature, burnout temperature and combustion characteristics index. The suspended droplet experimental system is also used to explore the micro-explosion phenomena and combustion modes of castor pyrolytic oil under different ambient temperatures. The castor pyrolytic oil is a multi-component fuel and has a complex process during the heating process and micro-explosion occurs, causing the droplet surface distortion. According to the timing and strength of the micro-explosion, there are three different stages: low intensity micro-explosion in the first stage, high intensity micro-explosion in the second stage and medium intensity micro-explosion in the final stage. After high-intensity micro-explosion occurred at 550°C, more volatile vapors were released and the flammable mixture will formed a flame wrapping around droplets after ignition. During the droplet combustion process, the micro-explosion occurred continuously, but the droplet still maintained a sphere-like appearance. The variation of droplet size generally followed d2-law and the combustion rate constant is approximately 1.483mm2/s. |
Author | Chao, Yei-Chin Chen, Guan-Bang Lan, Ching-Hsien Lin, Hsien-Tsung Li, Yueh-Heng |
Author_xml | – sequence: 1 givenname: Guan-Bang surname: Chen fullname: Chen, Guan-Bang email: gbchen26@gmail.com organization: Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan 701, Taiwan, ROC – sequence: 2 givenname: Yueh-Heng surname: Li fullname: Li, Yueh-Heng organization: Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan 701, Taiwan, ROC – sequence: 3 givenname: Ching-Hsien surname: Lan fullname: Lan, Ching-Hsien organization: Department of Aeronautics and Astronautics, National Cheng Kung University, Tainan 701, Taiwan, ROC – sequence: 4 givenname: Hsien-Tsung surname: Lin fullname: Lin, Hsien-Tsung organization: Department of Aeronautics and Astronautics, National Cheng Kung University, Tainan 701, Taiwan, ROC – sequence: 5 givenname: Yei-Chin surname: Chao fullname: Chao, Yei-Chin email: ycchao@mail.ncku.edu.tw organization: Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan 701, Taiwan, ROC |
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Keywords | Micro-explosion Thermal pyrolysis Pyrolytic castor oil Droplet combustion Suspended droplet experiment Castor seed |
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Snippet | •Castor pyrolytic oil exhibits a smaller micro-explosion than that of emulsion fuel.•The residue after combustion is only 0.18% of the weight of the pyrolytic... In the study, castor pyrolytic oil is produced from castor seeds by thermal pyrolysis and its pyrolysis reaction and oxidation reactions are investigated using... |
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SubjectTerms | Castor seed Chemical reactions Combustion Droplet combustion Flammability Fuel consumption Heating Ignition temperature Micro-explosion Oils & fats Oxidation Pyrolysis Pyrolytic castor oil Seeds Studies Surface distortion Suspended droplet experiment Thermal pyrolysis Thermogravimetric analysis |
Title | Micro-explosion and burning characteristics of a single droplet of pyrolytic oil from castor seeds |
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