Achieving High Density of Adsorbed Hydrogen in Microporous Metal Organic Frameworks
Two microporous metal organic framework structures are shown to possess hydrogen uptake capacities reaching 1.74 and 1.98 wt.‐% at 77 K (1, 2, see Figure). These give the highest adsorbed H2 density reported thus far for metal‐organic‐based porous materials. The estimated pore volumes are 0.33 and 0...
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| Published in | Advanced materials (Weinheim) Vol. 17; no. 22; pp. 2703 - 2706 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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Weinheim
WILEY-VCH Verlag
18.11.2005
WILEY‐VCH Verlag |
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| Abstract | Two microporous metal organic framework structures are shown to possess hydrogen uptake capacities reaching 1.74 and 1.98 wt.‐% at 77 K (1, 2, see Figure). These give the highest adsorbed H2 density reported thus far for metal‐organic‐based porous materials. The estimated pore volumes are 0.33 and 0.38 cm3 g–1 for 1 and 2. |
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| AbstractList | Two microporous metal organic framework structures are shown to possess hydrogen uptake capacities reaching 1.74 and 1.98 wt.‐% at 77 K (1, 2, see Figure). These give the highest adsorbed H2 density reported thus far for metal‐organic‐based porous materials. The estimated pore volumes are 0.33 and 0.38 cm3 g–1 for 1 and 2. |
| Author | Pan, L. Jagiello, J. Li, J. Kelly, S. P. Lee, J. Y. Emge, T. J. |
| Author_xml | – sequence: 1 givenname: J. Y. surname: Lee fullname: Lee, J. Y. organization: Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA – sequence: 2 givenname: L. surname: Pan fullname: Pan, L. organization: Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA – sequence: 3 givenname: S. P. surname: Kelly fullname: Kelly, S. P. organization: Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA – sequence: 4 givenname: J. surname: Jagiello fullname: Jagiello, J. organization: Quantachrome Instruments, 1900 Corporate Drive, Boynton Beach, FL 33426, USA – sequence: 5 givenname: T. J. surname: Emge fullname: Emge, T. J. organization: Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA – sequence: 6 givenname: J. surname: Li fullname: Li, J. email: jingli@rutchem.rutgers.edu organization: Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA |
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| Copyright | Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | istex:E6D231F3EA052544E512636D9F61E356154EDB90 ArticleID:ADMA200500867 ark:/67375/WNG-R0KFMM2Q-P We are grateful to the financial support from the National Science Foundation (DMR-0422932). Acknowledgment is also made to the donors of The Petroleum Research Fund, administrated by the ACS, for the partial support of this research. Supporting Information is available online from Wiley InterScience or from the author. We are grateful to the financial support from the National Science Foundation (DMR‐0422932). Acknowledgment is also made to the donors of The Petroleum Research Fund, administrated by the ACS, for the partial support of this research. Supporting Information is available online from Wiley InterScience or from the author. ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
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| Snippet | Two microporous metal organic framework structures are shown to possess hydrogen uptake capacities reaching 1.74 and 1.98 wt.‐% at 77 K (1, 2, see Figure).... |
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| SubjectTerms | Hydrogen storage Metal-organic materials Nanoporous materials |
| Title | Achieving High Density of Adsorbed Hydrogen in Microporous Metal Organic Frameworks |
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