The effects of graphene on the flammability and fire behavior of intumescent flame retardant polypropylene composites at different flame scenarios
This work explores the feasibility of using graphene as an effective synergist for intumescent flame retardant (IFR). The flammability test and fire behavior under different fire scenarios are investigated. The incorporation of graphene results in different responses of IFR/polypropylene (PP) compos...
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| Published in | Polymer degradation and stability Vol. 143; pp. 42 - 56 |
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| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Elsevier Ltd
01.09.2017
Elsevier BV |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0141-3910 1873-2321 |
| DOI | 10.1016/j.polymdegradstab.2017.06.015 |
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| Abstract | This work explores the feasibility of using graphene as an effective synergist for intumescent flame retardant (IFR). The flammability test and fire behavior under different fire scenarios are investigated. The incorporation of graphene results in different responses of IFR/polypropylene (PP) composites to small fire tests and burning under forced-flaming condition. The addition of graphene weakens the reaction of flame retardant PP to small flame. Lower loading of graphene is observed to improve the swelling of char, resulting in better insulation of the char and decrease in heat and smoke release. The further increase of graphene leads to the worsened fire safety. Flame retardant mechanism and model are proposed on the basis of the analyses of thermal decomposition products and process, and melt viscosity change. This works provides a solution to comprehensively assess the synergistic or antagonistic effect of graphene, and will be beneficial to developing its flame retardant mechanism. |
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| AbstractList | This work explores the feasibility of using graphene as an effective synergist for intumescent flame retardant (IFR). The flammability test and fire behavior under different fire scenarios are investigated. The incorporation of graphene results in different responses of IFR/polypropylene (PP) composites to small fire tests and burning under forced-flaming condition. The addition of graphene weakens the reaction of flame retardant PP to small flame. Lower loading of graphene is observed to improve the swelling of char, resulting in better insulation of the char and decrease in heat and smoke release. The further increase of graphene leads to the worsened fire safety. Flame retardant mechanism and model are proposed on the basis of the analyses of thermal decomposition products and process, and melt viscosity change. This works provides a solution to comprehensively assess the synergistic or antagonistic effect of graphene, and will be beneficial to developing its flame retardant mechanism. |
| Author | Chen, Xianfeng Bao, Chenlu Niu, Yi Yuan, Bihe Dai, Huaming Fan, Ao Jiang, Saihua Zhang, Ying Hu, Yuan Yang, Man He, Song |
| Author_xml | – sequence: 1 givenname: Bihe surname: Yuan fullname: Yuan, Bihe email: yuanbh@whut.edu.cn organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China – sequence: 2 givenname: Ao surname: Fan fullname: Fan, Ao organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China – sequence: 3 givenname: Man surname: Yang fullname: Yang, Man organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China – sequence: 4 givenname: Xianfeng surname: Chen fullname: Chen, Xianfeng email: cxf618@whut.edu.cn organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China – sequence: 5 givenname: Yuan surname: Hu fullname: Hu, Yuan email: yuanhu@ustc.edu.cn organization: State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei 230026, China – sequence: 6 givenname: Chenlu surname: Bao fullname: Bao, Chenlu organization: School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China – sequence: 7 givenname: Saihua surname: Jiang fullname: Jiang, Saihua organization: School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510641, China – sequence: 8 givenname: Yi surname: Niu fullname: Niu, Yi organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China – sequence: 9 givenname: Ying surname: Zhang fullname: Zhang, Ying organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China – sequence: 10 givenname: Song surname: He fullname: He, Song organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China – sequence: 11 givenname: Huaming surname: Dai fullname: Dai, Huaming organization: School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China |
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| SubjectTerms | Antagonism burning Effects fire behavior Fire protection fire safety fire testing Flame retardant flame retardants Flammability Graphene heat insulating materials Insulation melting Polymer matrix composites Polypropylene polypropylenes Smoke Synergy Thermal decomposition thermal degradation Viscosity |
| Title | The effects of graphene on the flammability and fire behavior of intumescent flame retardant polypropylene composites at different flame scenarios |
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