Synthesis and characterization of flame retardant rigid polyurethane foam based on a reactive flame retardant containing phosphazene and cyclophosphonate
A reactive flame retardant hexa-(5,5-dimethyl-1,3,2- dioxaphosphinane-hydroxyl-methyl-phenoxyl)-cyclotriphosphazene (HDPCP) was synthesized by using 5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide and hexa-(4-aldehyde-phenoxy)-cyclotriphosphazene via P-H addition reaction. And it was used to prepare fla...
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| Published in | Polymer degradation and stability Vol. 144; pp. 62 - 69 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Elsevier Ltd
01.10.2017
Elsevier BV |
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| Online Access | Get full text |
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| Abstract | A reactive flame retardant hexa-(5,5-dimethyl-1,3,2- dioxaphosphinane-hydroxyl-methyl-phenoxyl)-cyclotriphosphazene (HDPCP) was synthesized by using 5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide and hexa-(4-aldehyde-phenoxy)-cyclotriphosphazene via P-H addition reaction. And it was used to prepare flame retardant rigid polyurethane foams (FR-RPUFs). The effect of flame retardant HDPCP on physical-mechanical, thermal degradation and fire behavior properties of FR-RPUFs system has been investigated. The results suggested that HDPCP showed no obviously negative influence on physical-mechanical property of RPUF. The thermal stability and char residue at 700 °C of RPUF were enhanced by introducing HDPCP. HDPCP is benefit to improve flame retardance of RPUF. The limiting oxygen index (LOI) increased from 19 to 25% with incorporation of 25% HDPCP. Moreover, the peak heat release rate (PHRR), total heat release rate (THR), total smoke rate (TSR) and total smoke production (TSP) of RPUFs decreased due to a good char-forming ability of HDPCP. |
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| AbstractList | A reactive flame retardant hexa-(5,5-dimethyl-1,3,2- dioxaphosphinane-hydroxyl-methyl-phenoxyl)-cyclotriphosphazene (HDPCP) was synthesized by using 5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide and hexa-(4-aldehyde-phenoxy)-cyclotriphosphazene via P-H addition reaction. And it was used to prepare flame retardant rigid polyurethane foams (FR-RPUFs). The effect of flame retardant HDPCP on physical-mechanical, thermal degradation and fire behavior properties of FR-RPUFs system has been investigated. The results suggested that HDPCP showed no obviously negative influence on physical-mechanical property of RPUF. The thermal stability and char residue at 700 °C of RPUF were enhanced by introducing HDPCP. HDPCP is benefit to improve flame retardance of RPUF. The limiting oxygen index (LOI) increased from 19 to 25% with incorporation of 25% HDPCP. Moreover, the peak heat release rate (PHRR), total heat release rate (THR), total smoke rate (TSR) and total smoke production (TSP) of RPUFs decreased due to a good char-forming ability of HDPCP. A reactive flame retardant hexa-(5,5-dimethyl-1,3,2- dioxaphosphinane-hydroxyl-methyl-phenoxyl)-cyclotriphosphazene (HDPCP) was synthesized by using 5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide and hexa-(4-aldehyde-phenoxy)-cyclotriphosphazene via P-H addition reaction. And it was used to prepare flame retardant rigid polyurethane foams (FR-RPUFs). The effect of flame retardant HDPCP on physical-mechanical, thermal degradation and fire behavior properties of FR-RPUFs system has been investigated. The results suggested that HDPCP showed no obviously negative influence on physical-mechanical property of RPUF. The thermal stability and char residue at 700 °C of RPUF were enhanced by introducing HDPCP. HDPCP is benefit to improve flame retardance of RPUF. The limiting oxygen index (LOI) increased from 19 to 25% with incorporation of 25% HDPCP. Moreover, the peak heat release rate (PHRR), total heat release rate (THR), total smoke rate (TSR) and total smoke production (TSP) of RPUFs decreased due to a good char-forming ability of HDPCP. |
| Author | Yang, Rong Wang, Bo Han, Xiaofeng Ma, Binbin Li, Jinchun |
| Author_xml | – sequence: 1 givenname: Rong orcidid: 0000-0002-0193-6949 surname: Yang fullname: Yang, Rong email: cloudyyang@cczu.edu.cn – sequence: 2 givenname: Bo surname: Wang fullname: Wang, Bo – sequence: 3 givenname: Xiaofeng surname: Han fullname: Han, Xiaofeng – sequence: 4 givenname: Binbin surname: Ma fullname: Ma, Binbin – sequence: 5 givenname: Jinchun surname: Li fullname: Li, Jinchun |
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| Keywords | Rigid polyurethane foam Flame retardancy Physical mechanical property Reactive flame retardant |
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| SubjectTerms | Chemical synthesis Enthalpy fire behavior Flame retardancy Flame retardants foams heat Heat release rate oxygen Phosphazene Physical mechanical property Plastic foam Polyurethane Polyurethane foam polyurethanes Reactive flame retardant Rigid polyurethane foam Smoke Thermal degradation Thermal stability |
| Title | Synthesis and characterization of flame retardant rigid polyurethane foam based on a reactive flame retardant containing phosphazene and cyclophosphonate |
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