High mass loading additive-free LiFePO4 cathodes with 500 μm thickness for high areal capacity Li-ion batteries
We report the preparation of thick ceramic electrodes of the olivine LiFePO4 (LFP) with high mass loading. These electrodes are preparated by means of Powder Extrusion Moulding (PEM), which is a technology easily scalable and cheap. These LFP cathodes are additive-free (neither binder nor extra carb...
Saved in:
| Published in | Journal of power sources Vol. 458; p. 228033 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
15.05.2020
Elsevier |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | We report the preparation of thick ceramic electrodes of the olivine LiFePO4 (LFP) with high mass loading. These electrodes are preparated by means of Powder Extrusion Moulding (PEM), which is a technology easily scalable and cheap. These LFP cathodes are additive-free (neither binder nor extra carbon black) with ~0.5 mm thickness, allowing to develop very high areal capacity (13.7 mA h cm−2). By means of a strict control of sintering process, the carbon coating of the commercial LFP powder remains and the decomposition of the active material is prevented. The optimized self-supported LFP cathode presents good cyclability over 20 cycles at C/10 with no capacity loss. The good electrochemical performance of these novel LFP thick electrodes and their non-flammability make them interesting candidates for both mobile and stationary applications.
[Display omitted]
•Thick ceramic electrodes of LiFePO4 with high areal capacities (13.7 mA h cm-2).•Self-supported LFP cathode with good cyclability at C/10.•New generation of high performances and sustainable ultra-thick electrodes.•Thick electrodes (~500 μm) prepared by an easily scalable manufacturing process. |
|---|---|
| AbstractList | We report the preparation of thick ceramic electrodes of the olivine LiFePO (LFP) with high mass loading is reported. These electrodes are preparated by means of Powder Extrusion Moulding (PEM), which is a technology easily scalable and cheap. These LFP cathodes are additive-free (neither binder nor extra carbon black) with ~0.5 mm thickness, allowing to develop very high areal capacity (13.7 mA h cm-2). By means of a strict control of sintering process, the carbon coating of the commercial LFP powder remains and the decomposition of the active material is prevented. The optimized self-supported LFP cathode presents good cyclability over 20 cycles at C/10 with no capacity loss. The good electrochemical performance of these novel LFP thick electrodes and their non-flammability make them interesting candidates for both mobile and stationary applications. We report the preparation of thick ceramic electrodes of the olivine LiFePO4 (LFP) with high mass loading. These electrodes are preparated by means of Powder Extrusion Moulding (PEM), which is a technology easily scalable and cheap. These LFP cathodes are additive-free (neither binder nor extra carbon black) with ~0.5 mm thickness, allowing to develop very high areal capacity (13.7 mA h cm−2). By means of a strict control of sintering process, the carbon coating of the commercial LFP powder remains and the decomposition of the active material is prevented. The optimized self-supported LFP cathode presents good cyclability over 20 cycles at C/10 with no capacity loss. The good electrochemical performance of these novel LFP thick electrodes and their non-flammability make them interesting candidates for both mobile and stationary applications. [Display omitted] •Thick ceramic electrodes of LiFePO4 with high areal capacities (13.7 mA h cm-2).•Self-supported LFP cathode with good cyclability at C/10.•New generation of high performances and sustainable ultra-thick electrodes.•Thick electrodes (~500 μm) prepared by an easily scalable manufacturing process. |
| ArticleNumber | 228033 |
| Author | Várez, Alejandro de la Torre-Gamarra, Carmen Levenfeld, Belén Sotomayor, María Eugenia Sanchez, Jean-Yves Pereira-Ramos, Jean-Pierre Laïk, Barbara |
| Author_xml | – sequence: 1 givenname: Carmen surname: de la Torre-Gamarra fullname: de la Torre-Gamarra, Carmen organization: Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química, Universidad Carlos III de Madrid, Avda. Universidad 30, 28911, Leganés, Spain – sequence: 2 givenname: María Eugenia surname: Sotomayor fullname: Sotomayor, María Eugenia organization: Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química, Universidad Carlos III de Madrid, Avda. Universidad 30, 28911, Leganés, Spain – sequence: 3 givenname: Jean-Yves surname: Sanchez fullname: Sanchez, Jean-Yves organization: Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química, Universidad Carlos III de Madrid, Avda. Universidad 30, 28911, Leganés, Spain – sequence: 4 givenname: Belén surname: Levenfeld fullname: Levenfeld, Belén organization: Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química, Universidad Carlos III de Madrid, Avda. Universidad 30, 28911, Leganés, Spain – sequence: 5 givenname: Alejandro surname: Várez fullname: Várez, Alejandro email: alvar@ing.uc3m.es organization: Departamento de Ciencia e Ingeniería de Materiales e Ingeniería Química, Universidad Carlos III de Madrid, Avda. Universidad 30, 28911, Leganés, Spain – sequence: 6 givenname: Barbara surname: Laïk fullname: Laïk, Barbara organization: CNRS, UMR 7182, Institut de Chimie et des Matériaux Paris Est, GESMAT, UPEC, Université Paris Est, 2 Rue Henri Dunant, F-94320, Thiais, France – sequence: 7 givenname: Jean-Pierre surname: Pereira-Ramos fullname: Pereira-Ramos, Jean-Pierre organization: CNRS, UMR 7182, Institut de Chimie et des Matériaux Paris Est, GESMAT, UPEC, Université Paris Est, 2 Rue Henri Dunant, F-94320, Thiais, France |
| BackLink | https://hal.science/hal-03030919$$DView record in HAL |
| BookMark | eNqFkM9qGzEQh0VJoM6fVwi69rDOSCuttLeG0NQFQ3pIzkKRRlm59sqVVIe8TR6kpzxAnilr3PZa5jAw_L4fzHdCjsY0IiEXDOYMWHe5mq-26amkX3nOgcOccw1t-4HMmFZtw5WUR2QGrdKNUrL9SE5KWQEAYwpm5OciPg50Y0uh62R9HB-p9T7WuMMmZES6jDf4_VZQZ-uQPBb6FOtAJcDry9vvDa1DdD9GnPCQMh32ZTajXU_5rXWxPk8FTUwjfbC1Yo5YzshxsOuC53_2Kbm_-XJ3vWiWt1-_XV8tG9f2ojYiCEQtHzgTAZgAzTRg30vHueReoRYetQ-coZBBSdGJrg9Ws855p5Xo21Py6dA72LXZ5rix-dkkG83iamn2N2in6Vm_Y1O2O2RdTqVkDP8ABmYv2azMX8lmL9kcJE_g5wOI0ye7iNkUF3F06GNGV41P8X8V79kDi6o |
| CitedBy_id | crossref_primary_10_1016_j_ceramint_2024_06_109 crossref_primary_10_1016_j_matt_2022_01_011 crossref_primary_10_1016_j_ceramint_2023_05_180 crossref_primary_10_1007_s13391_021_00305_9 crossref_primary_10_1016_j_nwnano_2024_100034 crossref_primary_10_4028_www_scientific_net_KEM_905_147 crossref_primary_10_1016_j_rser_2023_113515 crossref_primary_10_1016_j_jcis_2023_03_117 crossref_primary_10_1134_S0036024422070287 crossref_primary_10_1134_S0036024423020279 crossref_primary_10_3390_batteries10010039 crossref_primary_10_1002_celc_202400288 crossref_primary_10_1007_s12598_021_01838_6 crossref_primary_10_1016_j_jallcom_2023_173127 crossref_primary_10_4028_p_DwbbY4 crossref_primary_10_1002_batt_202200050 crossref_primary_10_1016_j_jpowsour_2022_232176 crossref_primary_10_3390_polym13030323 crossref_primary_10_1016_j_jpowsour_2021_230299 crossref_primary_10_1021_acsaem_1c02135 crossref_primary_10_1088_2515_7655_ac8e30 crossref_primary_10_3390_nano13111771 crossref_primary_10_1002_aenm_202003663 crossref_primary_10_1016_j_jpowsour_2021_230955 crossref_primary_10_3389_fenrg_2023_1336344 crossref_primary_10_3390_en14071902 crossref_primary_10_1016_j_cej_2024_151957 crossref_primary_10_1016_j_jpowsour_2020_228704 crossref_primary_10_1134_S0036024423130216 crossref_primary_10_1007_s41918_020_00093_0 crossref_primary_10_1002_batt_202300441 crossref_primary_10_1016_j_jechem_2022_04_038 crossref_primary_10_1007_s10904_021_02043_9 crossref_primary_10_3390_nanoenergyadv3020008 crossref_primary_10_1016_j_jcis_2023_09_133 crossref_primary_10_3390_ma17102349 crossref_primary_10_1016_j_jallcom_2021_158776 crossref_primary_10_1016_j_jeurceramsoc_2020_07_049 crossref_primary_10_3390_batteries8100133 crossref_primary_10_1039_D1TA02209A crossref_primary_10_1088_2515_7655_ace850 crossref_primary_10_3390_batteries9030151 crossref_primary_10_1002_cey2_308 |
| Cites_doi | 10.1039/C5RA28183K 10.1002/aenm.201000050 10.1595/205651318X696747 10.1002/aenm.201703031 10.1002/aenm.201100261 10.1149/1.1391633 10.1149/2.0401507jes 10.1021/acs.jpclett.7b02880 10.1016/j.jpowsour.2019.226923 10.1149/1.2129668 10.1002/adfm.201102479 10.1016/j.mattod.2014.10.040 10.1016/j.electacta.2012.03.161 10.1038/nmat732 10.1016/j.jpowsour.2008.03.026 10.1039/C0EE00029A 10.1016/j.ijhydene.2014.01.010 10.1111/j.1744-7402.2008.02286.x 10.1016/j.ensm.2017.05.013 10.1016/j.jpowsour.2011.06.071 10.1016/j.jpowsour.2006.01.042 10.1007/s11581-017-2177-8 10.1016/j.matchar.2013.09.020 10.1016/j.jmatprotec.2006.10.039 10.1039/C7TA10683A 10.1007/BF01431449 |
| ContentType | Journal Article |
| Copyright | 2020 Elsevier B.V. Distributed under a Creative Commons Attribution 4.0 International License |
| Copyright_xml | – notice: 2020 Elsevier B.V. – notice: Distributed under a Creative Commons Attribution 4.0 International License |
| DBID | AAYXX CITATION 1XC VOOES |
| DOI | 10.1016/j.jpowsour.2020.228033 |
| DatabaseName | CrossRef Hyper Article en Ligne (HAL) Hyper Article en Ligne (HAL) (Open Access) |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1873-2755 |
| ExternalDocumentID | oai_HAL_hal_03030919v1 10_1016_j_jpowsour_2020_228033 S0378775320303360 |
| GroupedDBID | --K --M .~1 0R~ 1B1 1~. 1~5 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 9JN AABNK AABXZ AACTN AAEDT AAEDW AAEPC AAHCO AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AARJD AARLI AAXUO ABFNM ABMAC ABXRA ABYKQ ACDAQ ACGFS ACRLP ADBBV ADECG ADEZE AEBSH AEKER AENEX AEZYN AFKWA AFRZQ AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHIDL AIEXJ AIKHN AITUG AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BELTK BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EO8 EO9 EP2 EP3 F5P FDB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA IHE J1W JARJE KOM LX7 LY6 M41 MAGPM MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RNS ROL RPZ SDF SDG SDP SES SPC SPCBC SSK SSM SSR SSZ T5K XPP ZMT ~G- 29L AAQXK AAXKI AAYXX ABXDB ACNNM ADMUD AFJKZ AI. AKRWK ASPBG AVWKF AZFZN BBWZM CITATION EJD FEDTE FGOYB G-2 HLY HVGLF HZ~ NDZJH R2- RIG SAC SCB SCE SEW T9H VH1 VOH WUQ 1XC VOOES |
| ID | FETCH-LOGICAL-c394t-4f4ee85b214f01408180e995c2252d7e84de8df21e45f7546469fa816cdc87493 |
| IEDL.DBID | AIKHN |
| ISSN | 0378-7753 |
| IngestDate | Tue Oct 15 15:46:56 EDT 2024 Thu Sep 26 16:49:48 EDT 2024 Fri Feb 23 02:50:29 EST 2024 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Thick electrode High mass loading Binder-free Solvent-free Areal capacity solvent-free high mass loading areal capacity thick electrode binder-free |
| Language | English |
| License | Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c394t-4f4ee85b214f01408180e995c2252d7e84de8df21e45f7546469fa816cdc87493 |
| ORCID | 0000-0001-5194-4210 0000-0001-5381-900X |
| OpenAccessLink | https://hal.science/hal-03030919 |
| ParticipantIDs | hal_primary_oai_HAL_hal_03030919v1 crossref_primary_10_1016_j_jpowsour_2020_228033 elsevier_sciencedirect_doi_10_1016_j_jpowsour_2020_228033 |
| PublicationCentury | 2000 |
| PublicationDate | 2020-05-15 |
| PublicationDateYYYYMMDD | 2020-05-15 |
| PublicationDate_xml | – month: 05 year: 2020 text: 2020-05-15 day: 15 |
| PublicationDecade | 2020 |
| PublicationTitle | Journal of power sources |
| PublicationYear | 2020 |
| Publisher | Elsevier B.V Elsevier |
| Publisher_xml | – name: Elsevier B.V – name: Elsevier |
| References | Wang, Liu, Sherman, Verbrugge, Tataria (bib6) 2011; 196 Kato, Shiotani, Morita, Suzuki, Hirayama, Kanno (bib19) 2018; 9 Chung, Bloking, Chiang (bib26) 2002; 1 Monzón, Laguna-Bercero, Larrea, Arias, Várez, Levenfeld (bib13) 2014 Arias-Serrano, Sotomayor, Várez, Levenfeld, Monzón, Laguna-Bercero, Larrea (bib12) 2016; 6 Sotomayor, de la Torre-Gamarra, Levenfeld, Sanchez, Varez, Kim, Varzi, Passerini (bib20) 2019; 437 Sotomayor, de la Torre-Gamarra, Bucheli, Amarilla, Varez, Levenfeld, Sanchez (bib15) 2018; 6 Aboulaich, Bouchet, Delaizir, Seznec, Tortet, Morcrette, Rozier, Tarascon, Viallet, Dollé (bib32) 2011; 1 Mauger, Julien (bib3) 2017; 23 Kasemchainan, Bruce (bib10) 2018; 62 Singh, Kaiser, Hahn (bib9) 2015; 162 Sotomayor, Ospina, Levenfeld, Várez (bib14) 2013; 86 Delaizir, Viallet, Aboulaich, Bouchet, Tortet, Seznec, Morcrette, Tarascon, Rozier, Dollé (bib18) 2012; 22 Feng, Ouyang, Liu, Lu, Xia, He (bib16) 2018; 10 Smart (bib29) 2002; 146 Li, Li, Khalil (bib24) 2007; 183 de Waele (bib22) 1923; 6 Yuan, Wang, Zhang, Hu, Chen, Huang, Goodenough (bib4) 2011; 4 Hu, La Mantia, Wu, Xie, McDonough, Pasta, Cui (bib7) 2011; 1 Nitta, Wu, Lee, Yushin (bib5) 2015; 18 Elango, Demortière, De Andrade, Morcrette, Seznec (bib17) 2018; 8 Mutsuddy (bib25) 1983; 25 Ho, Raistrick, Huggins (bib30) 1980; 127 Xu, Lu, Yan, Yang, Yang (bib27) 2006; 160 Manas-Zloczower (bib21) 2009 Mizushima, Jones, Wiseman, Goodenough (bib1) 1980; 15 Zheng, Li, Song, Liu, Battaglia (bib8) 2012; 71 Lin, Gao, Zhu, Liu, Pan (bib28) 2008; 184 Jardiel, Sotomayor, Levenfeld, Várez (bib11) 2008; 5 Dunn, Dunn, Kamath, Tarascon (bib2) 2011; 334 Ostwald (bib23) 1925; 36 Levenfeld, Sotomayor, Bucheli, Sanchez, Varez, Amarilla (bib31) 2017 Mizushima (10.1016/j.jpowsour.2020.228033_bib1) 1980; 15 Feng (10.1016/j.jpowsour.2020.228033_bib16) 2018; 10 Lin (10.1016/j.jpowsour.2020.228033_bib28) 2008; 184 Smart (10.1016/j.jpowsour.2020.228033_bib29) 2002; 146 Xu (10.1016/j.jpowsour.2020.228033_bib27) 2006; 160 de Waele (10.1016/j.jpowsour.2020.228033_bib22) 1923; 6 Ho (10.1016/j.jpowsour.2020.228033_bib30) 1980; 127 Arias-Serrano (10.1016/j.jpowsour.2020.228033_bib12) 2016; 6 Dunn (10.1016/j.jpowsour.2020.228033_bib2) 2011; 334 Kato (10.1016/j.jpowsour.2020.228033_bib19) 2018; 9 Delaizir (10.1016/j.jpowsour.2020.228033_bib18) 2012; 22 Jardiel (10.1016/j.jpowsour.2020.228033_bib11) 2008; 5 Ostwald (10.1016/j.jpowsour.2020.228033_bib23) 1925; 36 Sotomayor (10.1016/j.jpowsour.2020.228033_bib14) 2013; 86 Levenfeld (10.1016/j.jpowsour.2020.228033_bib31) 2017 Sotomayor (10.1016/j.jpowsour.2020.228033_bib20) 2019; 437 Singh (10.1016/j.jpowsour.2020.228033_bib9) 2015; 162 Wang (10.1016/j.jpowsour.2020.228033_bib6) 2011; 196 Li (10.1016/j.jpowsour.2020.228033_bib24) 2007; 183 Yuan (10.1016/j.jpowsour.2020.228033_bib4) 2011; 4 Mauger (10.1016/j.jpowsour.2020.228033_bib3) 2017; 23 Sotomayor (10.1016/j.jpowsour.2020.228033_bib15) 2018; 6 Hu (10.1016/j.jpowsour.2020.228033_bib7) 2011; 1 Manas-Zloczower (10.1016/j.jpowsour.2020.228033_bib21) 2009 Monzón (10.1016/j.jpowsour.2020.228033_bib13) 2014 Aboulaich (10.1016/j.jpowsour.2020.228033_bib32) 2011; 1 Nitta (10.1016/j.jpowsour.2020.228033_bib5) 2015; 18 Kasemchainan (10.1016/j.jpowsour.2020.228033_bib10) 2018; 62 Zheng (10.1016/j.jpowsour.2020.228033_bib8) 2012; 71 Elango (10.1016/j.jpowsour.2020.228033_bib17) 2018; 8 Mutsuddy (10.1016/j.jpowsour.2020.228033_bib25) 1983; 25 Chung (10.1016/j.jpowsour.2020.228033_bib26) 2002; 1 |
| References_xml | – volume: 23 start-page: 1933 year: 2017 end-page: 1947 ident: bib3 article-title: Critical review on lithium-ion batteries: are they safe? Sustainable? publication-title: Ionics contributor: fullname: Julien – volume: 62 start-page: 177 year: 2018 end-page: 180 ident: bib10 article-title: All-solid-state batteries and their remaining challenges publication-title: Johns. Matthey Technol. Rev. contributor: fullname: Bruce – volume: 15 start-page: 783 year: 1980 end-page: 789 ident: bib1 article-title: LixCoO publication-title: Solid State Ionics contributor: fullname: Goodenough – volume: 36 start-page: 99 year: 1925 end-page: 117 ident: bib23 article-title: Speed function of viscosity of disperse systems I publication-title: Kolloid Z. contributor: fullname: Ostwald – volume: 146 start-page: 486 year: 2002 ident: bib29 article-title: Electrolytes for low-temperature lithium batteries based on ternary mixtures of aliphatic carbonates publication-title: J. Electrochem. Soc. contributor: fullname: Smart – volume: 334 start-page: 928 year: 2011 end-page: 936 ident: bib2 article-title: Electrical energy storage for the Grid : a Battery of choices publication-title: Sci. Magna contributor: fullname: Tarascon – volume: 160 start-page: 570 year: 2006 end-page: 576 ident: bib27 article-title: Synthesis and effect of forming Fe publication-title: J. Power Sources contributor: fullname: Yang – volume: 1 start-page: 179 year: 2011 end-page: 183 ident: bib32 article-title: A new approach to develop safe all-inorganic monolithic li-ion batteries publication-title: Adv. Energy Mater. contributor: fullname: Dollé – volume: 1 start-page: 123 year: 2002 end-page: 128 ident: bib26 article-title: Electronically conductive phospho-olivines as lithium storage electrodes publication-title: Nat. Mater. contributor: fullname: Chiang – volume: 86 start-page: 108 year: 2013 end-page: 115 ident: bib14 article-title: Characterization of 430L porous supports obtained by powder extrusion moulding for their application in solid oxide fuel cells publication-title: Mater. Character contributor: fullname: Várez – volume: 25 start-page: 76 year: 1983 end-page: 80 ident: bib25 article-title: Injection-Molding research paves way to ceramic engine parts publication-title: Ind. Res. Dev. contributor: fullname: Mutsuddy – year: 2017 ident: bib31 publication-title: Electrodes for Rechargeable Lithium Batteries contributor: fullname: Amarilla – volume: 8 start-page: 1 year: 2018 end-page: 8 ident: bib17 article-title: Thick binder-free electrodes for Li–ion battery fabricated using templating approach and spark Plasma sintering reveals high areal capacity publication-title: Adv. Energy Mater. contributor: fullname: Seznec – volume: 437 start-page: 226923 year: 2019 ident: bib20 article-title: Ultra-thick battery electrodes for high gravimetric and volumetric energy density Li-ion batteries publication-title: J. Power Sources contributor: fullname: Passerini – volume: 22 start-page: 2140 year: 2012 end-page: 2147 ident: bib18 article-title: The stone age revisited: building a monolithic inorganic lithium-ion battery publication-title: Adv. Funct. Mater. contributor: fullname: Dollé – volume: 127 start-page: 343 year: 1980 end-page: 350 ident: bib30 article-title: Application of A-C techniques to the study of lithium diffusion in tungsten trioxide thin films publication-title: J. Electrochem. Soc. contributor: fullname: Huggins – volume: 10 start-page: 246 year: 2018 end-page: 267 ident: bib16 article-title: Thermal runaway mechanism of lithium ion battery for electric vehicles: a review publication-title: Energy Storage Mater. contributor: fullname: He – volume: 183 start-page: 432 year: 2007 end-page: 439 ident: bib24 article-title: Effect of powder loading on metal injection molding stainless steels publication-title: J. Mater. Process. Technol. contributor: fullname: Khalil – volume: 184 start-page: 444 year: 2008 end-page: 448 ident: bib28 article-title: Effects of carbon coating and iron phosphides on the electrochemical properties of LiFePO publication-title: J. Power Sources contributor: fullname: Pan – volume: 4 start-page: 269 year: 2011 end-page: 284 ident: bib4 article-title: Development and challenges of LiFePO publication-title: Energy Environ. Sci. contributor: fullname: Goodenough – volume: 5 start-page: 574 year: 2008 end-page: 581 ident: bib11 article-title: Optimization of the processing of 8-YSZ powder by powder injection molding for SOFC electrolytes publication-title: Int. J. Appl. Ceram. Technol. contributor: fullname: Várez – volume: 1 start-page: 1012 year: 2011 end-page: 1017 ident: bib7 article-title: Lithium-ion textile batteries with large areal mass loading publication-title: Adv. Energy Mater. contributor: fullname: Cui – volume: 18 start-page: 252 year: 2015 end-page: 264 ident: bib5 article-title: Li-ion battery materials: present and future publication-title: Mater. Today contributor: fullname: Yushin – volume: 196 start-page: 8714 year: 2011 end-page: 8718 ident: bib6 article-title: Formulation and characterization of ultra-thick electrodes for high energy lithium-ion batteries employing tailored metal foams publication-title: J. Power Sources contributor: fullname: Tataria – volume: 162 start-page: A1196 year: 2015 end-page: A1201 ident: bib9 article-title: Thick electrodes for high energy lithium ion batteries publication-title: J. Electrochem. Soc. contributor: fullname: Hahn – volume: 9 start-page: 607 year: 2018 end-page: 613 ident: bib19 article-title: All-solid-state batteries with thick electrode configurations publication-title: J. Phys. Chem. Lett. contributor: fullname: Kanno – start-page: 5470 year: 2014 end-page: 5476 ident: bib13 article-title: Design of industrially scalable microtubular solid oxide fuel cells based on an extruded support publication-title: Int. J. Hydrogen Energy contributor: fullname: Levenfeld – volume: 6 start-page: 5952 year: 2018 end-page: 5961 ident: bib15 article-title: Additive-free Li publication-title: J. Mater. Chem. A. contributor: fullname: Sanchez – volume: 6 start-page: 33 year: 1923 end-page: 69 ident: bib22 article-title: Viscometry and plastometry publication-title: J. Oil Colour Chemists' Assoc. contributor: fullname: de Waele – volume: 6 start-page: 19007 year: 2016 end-page: 19015 ident: bib12 article-title: High-performance Ni-YSZ thin-walled microtubes for anode-supported solid oxide fuel cells obtained by powder extrusion moulding publication-title: RSC Adv. contributor: fullname: Larrea – volume: 71 start-page: 258 year: 2012 end-page: 265 ident: bib8 article-title: A comprehensive understanding of electrode thickness effects on the electrochemical performances of Li-ion battery cathodes publication-title: Electrochim. Acta contributor: fullname: Battaglia – year: 2009 ident: bib21 article-title: Mixing and Compounding of Polymers: Theory and Practice contributor: fullname: Manas-Zloczower – volume: 6 start-page: 19007 year: 2016 ident: 10.1016/j.jpowsour.2020.228033_bib12 article-title: High-performance Ni-YSZ thin-walled microtubes for anode-supported solid oxide fuel cells obtained by powder extrusion moulding publication-title: RSC Adv. doi: 10.1039/C5RA28183K contributor: fullname: Arias-Serrano – volume: 1 start-page: 179 year: 2011 ident: 10.1016/j.jpowsour.2020.228033_bib32 article-title: A new approach to develop safe all-inorganic monolithic li-ion batteries publication-title: Adv. Energy Mater. doi: 10.1002/aenm.201000050 contributor: fullname: Aboulaich – volume: 62 start-page: 177 year: 2018 ident: 10.1016/j.jpowsour.2020.228033_bib10 article-title: All-solid-state batteries and their remaining challenges publication-title: Johns. Matthey Technol. Rev. doi: 10.1595/205651318X696747 contributor: fullname: Kasemchainan – volume: 8 start-page: 1 year: 2018 ident: 10.1016/j.jpowsour.2020.228033_bib17 article-title: Thick binder-free electrodes for Li–ion battery fabricated using templating approach and spark Plasma sintering reveals high areal capacity publication-title: Adv. Energy Mater. doi: 10.1002/aenm.201703031 contributor: fullname: Elango – volume: 15 start-page: 783 year: 1980 ident: 10.1016/j.jpowsour.2020.228033_bib1 article-title: LixCoO2 (0<x≤1): a new cathode material for batteries of high energy density publication-title: Solid State Ionics contributor: fullname: Mizushima – volume: 1 start-page: 1012 year: 2011 ident: 10.1016/j.jpowsour.2020.228033_bib7 article-title: Lithium-ion textile batteries with large areal mass loading publication-title: Adv. Energy Mater. doi: 10.1002/aenm.201100261 contributor: fullname: Hu – volume: 146 start-page: 486 year: 2002 ident: 10.1016/j.jpowsour.2020.228033_bib29 article-title: Electrolytes for low-temperature lithium batteries based on ternary mixtures of aliphatic carbonates publication-title: J. Electrochem. Soc. doi: 10.1149/1.1391633 contributor: fullname: Smart – volume: 162 start-page: A1196 year: 2015 ident: 10.1016/j.jpowsour.2020.228033_bib9 article-title: Thick electrodes for high energy lithium ion batteries publication-title: J. Electrochem. Soc. doi: 10.1149/2.0401507jes contributor: fullname: Singh – volume: 9 start-page: 607 year: 2018 ident: 10.1016/j.jpowsour.2020.228033_bib19 article-title: All-solid-state batteries with thick electrode configurations publication-title: J. Phys. Chem. Lett. doi: 10.1021/acs.jpclett.7b02880 contributor: fullname: Kato – volume: 437 start-page: 226923 year: 2019 ident: 10.1016/j.jpowsour.2020.228033_bib20 article-title: Ultra-thick battery electrodes for high gravimetric and volumetric energy density Li-ion batteries publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2019.226923 contributor: fullname: Sotomayor – volume: 127 start-page: 343 year: 1980 ident: 10.1016/j.jpowsour.2020.228033_bib30 article-title: Application of A-C techniques to the study of lithium diffusion in tungsten trioxide thin films publication-title: J. Electrochem. Soc. doi: 10.1149/1.2129668 contributor: fullname: Ho – volume: 22 start-page: 2140 year: 2012 ident: 10.1016/j.jpowsour.2020.228033_bib18 article-title: The stone age revisited: building a monolithic inorganic lithium-ion battery publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201102479 contributor: fullname: Delaizir – volume: 6 start-page: 33 year: 1923 ident: 10.1016/j.jpowsour.2020.228033_bib22 article-title: Viscometry and plastometry publication-title: J. Oil Colour Chemists' Assoc. contributor: fullname: de Waele – volume: 18 start-page: 252 year: 2015 ident: 10.1016/j.jpowsour.2020.228033_bib5 article-title: Li-ion battery materials: present and future publication-title: Mater. Today doi: 10.1016/j.mattod.2014.10.040 contributor: fullname: Nitta – volume: 71 start-page: 258 year: 2012 ident: 10.1016/j.jpowsour.2020.228033_bib8 article-title: A comprehensive understanding of electrode thickness effects on the electrochemical performances of Li-ion battery cathodes publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2012.03.161 contributor: fullname: Zheng – volume: 1 start-page: 123 year: 2002 ident: 10.1016/j.jpowsour.2020.228033_bib26 article-title: Electronically conductive phospho-olivines as lithium storage electrodes publication-title: Nat. Mater. doi: 10.1038/nmat732 contributor: fullname: Chung – volume: 184 start-page: 444 year: 2008 ident: 10.1016/j.jpowsour.2020.228033_bib28 article-title: Effects of carbon coating and iron phosphides on the electrochemical properties of LiFePO4/C publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2008.03.026 contributor: fullname: Lin – volume: 4 start-page: 269 year: 2011 ident: 10.1016/j.jpowsour.2020.228033_bib4 article-title: Development and challenges of LiFePO4 cathode material for lithium-ion batteries publication-title: Energy Environ. Sci. doi: 10.1039/C0EE00029A contributor: fullname: Yuan – volume: 25 start-page: 76 year: 1983 ident: 10.1016/j.jpowsour.2020.228033_bib25 article-title: Injection-Molding research paves way to ceramic engine parts publication-title: Ind. Res. Dev. contributor: fullname: Mutsuddy – start-page: 5470 year: 2014 ident: 10.1016/j.jpowsour.2020.228033_bib13 article-title: Design of industrially scalable microtubular solid oxide fuel cells based on an extruded support publication-title: Int. J. Hydrogen Energy doi: 10.1016/j.ijhydene.2014.01.010 contributor: fullname: Monzón – volume: 5 start-page: 574 year: 2008 ident: 10.1016/j.jpowsour.2020.228033_bib11 article-title: Optimization of the processing of 8-YSZ powder by powder injection molding for SOFC electrolytes publication-title: Int. J. Appl. Ceram. Technol. doi: 10.1111/j.1744-7402.2008.02286.x contributor: fullname: Jardiel – volume: 10 start-page: 246 year: 2018 ident: 10.1016/j.jpowsour.2020.228033_bib16 article-title: Thermal runaway mechanism of lithium ion battery for electric vehicles: a review publication-title: Energy Storage Mater. doi: 10.1016/j.ensm.2017.05.013 contributor: fullname: Feng – volume: 196 start-page: 8714 year: 2011 ident: 10.1016/j.jpowsour.2020.228033_bib6 article-title: Formulation and characterization of ultra-thick electrodes for high energy lithium-ion batteries employing tailored metal foams publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2011.06.071 contributor: fullname: Wang – volume: 160 start-page: 570 year: 2006 ident: 10.1016/j.jpowsour.2020.228033_bib27 article-title: Synthesis and effect of forming Fe2P phase on the physics and electrochemical properties of LiFePO4/C materials publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2006.01.042 contributor: fullname: Xu – year: 2017 ident: 10.1016/j.jpowsour.2020.228033_bib31 contributor: fullname: Levenfeld – volume: 23 start-page: 1933 year: 2017 ident: 10.1016/j.jpowsour.2020.228033_bib3 article-title: Critical review on lithium-ion batteries: are they safe? Sustainable? publication-title: Ionics doi: 10.1007/s11581-017-2177-8 contributor: fullname: Mauger – volume: 86 start-page: 108 year: 2013 ident: 10.1016/j.jpowsour.2020.228033_bib14 article-title: Characterization of 430L porous supports obtained by powder extrusion moulding for their application in solid oxide fuel cells publication-title: Mater. Character doi: 10.1016/j.matchar.2013.09.020 contributor: fullname: Sotomayor – volume: 183 start-page: 432 year: 2007 ident: 10.1016/j.jpowsour.2020.228033_bib24 article-title: Effect of powder loading on metal injection molding stainless steels publication-title: J. Mater. Process. Technol. doi: 10.1016/j.jmatprotec.2006.10.039 contributor: fullname: Li – volume: 334 start-page: 928 year: 2011 ident: 10.1016/j.jpowsour.2020.228033_bib2 article-title: Electrical energy storage for the Grid : a Battery of choices publication-title: Sci. Magna contributor: fullname: Dunn – year: 2009 ident: 10.1016/j.jpowsour.2020.228033_bib21 contributor: fullname: Manas-Zloczower – volume: 6 start-page: 5952 year: 2018 ident: 10.1016/j.jpowsour.2020.228033_bib15 article-title: Additive-free Li4Ti5O12 thick electrodes for Li-ion batteries with high electrochemical performance publication-title: J. Mater. Chem. A. doi: 10.1039/C7TA10683A contributor: fullname: Sotomayor – volume: 36 start-page: 99 year: 1925 ident: 10.1016/j.jpowsour.2020.228033_bib23 article-title: Speed function of viscosity of disperse systems I publication-title: Kolloid Z. doi: 10.1007/BF01431449 contributor: fullname: Ostwald |
| SSID | ssj0001170 |
| Score | 2.5381782 |
| Snippet | We report the preparation of thick ceramic electrodes of the olivine LiFePO4 (LFP) with high mass loading. These electrodes are preparated by means of Powder... We report the preparation of thick ceramic electrodes of the olivine LiFePO (LFP) with high mass loading is reported. These electrodes are preparated by means... |
| SourceID | hal crossref elsevier |
| SourceType | Open Access Repository Aggregation Database Publisher |
| StartPage | 228033 |
| SubjectTerms | Areal capacity Binder-free Chemical Sciences High mass loading Solvent-free Thick electrode |
| Title | High mass loading additive-free LiFePO4 cathodes with 500 μm thickness for high areal capacity Li-ion batteries |
| URI | https://dx.doi.org/10.1016/j.jpowsour.2020.228033 https://hal.science/hal-03030919 |
| Volume | 458 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3JTsMwELWgXOCAWEXZZCGubhPb2Y4Voio7EiD1FiXOWLR0Awrc-BY-hBMfwDcxkyYVHBAHjrbsOBpPnudNxjOM7Sc2MTZVgYgcrYX2wRFppkAgHUqyUCbWGPJDnp37rRt93PbaM-ygvAtDYZUF9k8wPUfroqdeSLM-6nTqV45CZQuosAHCsPKRt8_hcSTDCptrHJ20zqeATMVV8p8JSJhowreLwt1adzR8IT85UkXp1Cg5jFK_nVGzt6W3NT99mktssTAbeWPyZstsBgYrbOFbMsFVdk8hG7yPxjDvDfPIeE7BQgRnwj4A8NNOEy4vNKdMrcMMHjn5YLnnOB9vn-99ToHvdwR8HO1YTmmMeYIWZQ_HI69GYx0fIHAXeZqn5ESGvcZumofXBy1RFFQQRkV6LLTVAKGXSldbYlZ0zxuiyDP4UcssgFBnEGZWuqA9G3jaR-5sk9D1TWbCQEdqnVUGwwFsMK5l6ktQfmBplA0T1xoHwFiJbe2YKquXIoxHk7wZcRlQ1o1Locck9Hgi9CqLSknHPzQgRnD_c-4ebs10IUqZ3WqcxtRHyoE2UfTsbv5jgS02Ty0KG3C9bVYZPzzBDloj43SXzdZe3d1C574AE1jgPw |
| link.rule.ids | 230,315,783,787,888,4509,24128,27936,27937,45597,45691 |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LTsMwELWgLIAF4iv-WIitaRI7v2VVUQUoBQmQ2FmJMxYt0BYocB0OwooDcCZm0gTBArFgGcdOorH9_N5kPGZsL7WpsZkMRewoJVQAjshyCQLlUJpHXmqNIT_kSSdILtXRlX81wZrVXhgKqyyxf4zpBVqXJfXSmvVht1s_dyQOtpAONkAYlgHq9ilkAzHOzqnG4XHS-QJkOlyl-JmAgokafNso3NvvDQcv5CdHqeg5-5QcRsrf1qjJ68rbWqw-rXk2V9JG3hh_2QKbgP4im_2WTHCJ3VPIBr9DMsxvB0VkPKdgIYIzYR8AeLvbgrNTxSlT6yCHR04-WO47zvvrx9sdp8D3GwI-jjyWUxpjniKjvMX6qKuRrOMDBPYiz4qUnKiwl9ll6-CimYjyQAVhZKxGQlkFEPmZ5ypLyor2eUMc-wYntZeHEKkcotx6Lijfhr4KUDvbNHIDk5soVLFcYbX-oA-rjCsvCzyQQWiplo1S1xoHwFgPr5Vj1li9MqEejvNm6CqgrKcro2syuh4bfY3FlaX1jxGgEdz_bLuLXfP1IkqZnTTamspocCAnip_d9X-8YIdNJxcnbd0-7BxvsBm6QyEErr_JaqOHJ9hCZjLKtsuR9wmCMOIz |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=High+mass+loading+additive-free+LiFePO4+cathodes+with+500%C2%A0%CE%BCm+thickness+for+high+areal+capacity+Li-ion+batteries&rft.jtitle=Journal+of+power+sources&rft.au=de+La+Torre-Gamarra%2C+Carmen&rft.au=Sotomayor%2C+Mar%C3%ADa+Eugenia&rft.au=Sanchez%2C+Jean-Yves&rft.au=Levenfeld%2C+Bel%C3%A9n&rft.date=2020-05-15&rft.pub=Elsevier&rft.issn=0378-7753&rft.eissn=1873-2755&rft.volume=458&rft_id=info:doi/10.1016%2Fj.jpowsour.2020.228033&rft.externalDBID=HAS_PDF_LINK&rft.externalDocID=oai_HAL_hal_03030919v1 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0378-7753&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0378-7753&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0378-7753&client=summon |