High mass loading additive-free LiFePO4 cathodes with 500 μm thickness for high areal capacity Li-ion batteries
We report the preparation of thick ceramic electrodes of the olivine LiFePO4 (LFP) with high mass loading. These electrodes are preparated by means of Powder Extrusion Moulding (PEM), which is a technology easily scalable and cheap. These LFP cathodes are additive-free (neither binder nor extra carb...
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Published in | Journal of power sources Vol. 458; p. 228033 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
15.05.2020
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | We report the preparation of thick ceramic electrodes of the olivine LiFePO4 (LFP) with high mass loading. These electrodes are preparated by means of Powder Extrusion Moulding (PEM), which is a technology easily scalable and cheap. These LFP cathodes are additive-free (neither binder nor extra carbon black) with ~0.5 mm thickness, allowing to develop very high areal capacity (13.7 mA h cm−2). By means of a strict control of sintering process, the carbon coating of the commercial LFP powder remains and the decomposition of the active material is prevented. The optimized self-supported LFP cathode presents good cyclability over 20 cycles at C/10 with no capacity loss. The good electrochemical performance of these novel LFP thick electrodes and their non-flammability make them interesting candidates for both mobile and stationary applications.
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•Thick ceramic electrodes of LiFePO4 with high areal capacities (13.7 mA h cm-2).•Self-supported LFP cathode with good cyclability at C/10.•New generation of high performances and sustainable ultra-thick electrodes.•Thick electrodes (~500 μm) prepared by an easily scalable manufacturing process. |
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ISSN: | 0378-7753 1873-2755 |
DOI: | 10.1016/j.jpowsour.2020.228033 |