Gas‐phase fluorination of conjugated microporous polymer microspheres for effective interfacial stabilization in lithium metal anodes

• Published in: Carbon energy Vol. 5; no. 10
• Main Authors: Li, Zihao, Kong, Lingchen, Peng, Cong, Feng, Wei
• Format: Journal Article
• Language: English
• Published: Beijing John Wiley & Sons, Inc 01.10.2023; Wiley
• Subjects: Alkynes; Anodes; Batteries; conjugated microporous polymers; Cycles; Density functional theory; Deposition; Electric properties; Electrochemistry; Electrodes; Electrolytes; Electrolytic cells; Electrons; Fluorides; fluorinated solid electrolyte interphase; Fluorination; Fluorine; Fourier transforms; gas‐phase fluorination; Interfaces; Interlayers; Lability; Lithium; Lithium batteries; Lithium fluoride; lithium metal anodes; Metals; Microcrystals; Microspheres; nonfluorinated electrolyte; Polymers; Solid electrolytes; Solvents
• ISSN: 2637-9368; 2637-9368
• DOI: 10.1002/cey2.354

Lithium (Li) metal anodes have attracted extensive attention due to their ultrahigh theoretical capacity and low potential. However, the uneven deposition of Li near the unstable electrode/electrolyte interfaces leads to the growth of Li dendrites and the degradation of active electrodes. Herein, we...