Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption
[Display omitted] •C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate and heptanoate.•Longer carboxylates were also easier desorbed, allowing their enrichment.•Hexanoate and heptanoate were concentrated up to 0.2...
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Published in | Bioresource technology Vol. 319; p. 124178 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Elsevier Ltd
01.01.2021
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Abstract | [Display omitted]
•C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate and heptanoate.•Longer carboxylates were also easier desorbed, allowing their enrichment.•Hexanoate and heptanoate were concentrated up to 0.29 mol/kg and 0.18 mol/kg, respectively.
The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO2-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates. |
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AbstractList | [Display omitted]
•C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate and heptanoate.•Longer carboxylates were also easier desorbed, allowing their enrichment.•Hexanoate and heptanoate were concentrated up to 0.29 mol/kg and 0.18 mol/kg, respectively.
The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO2-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates. |
ArticleNumber | 124178 |
Author | Fernando-Foncillas, Clara Straathof, Adrie J.J. Cabrera-Rodríguez, Carlos I. Caparrós-Salvador, Francisco Varrone, Cristiano |
Author_xml | – sequence: 1 givenname: Clara surname: Fernando-Foncillas fullname: Fernando-Foncillas, Clara organization: Section for Sustainable Biotechnology, Aalborg University Copenhagen, A.C. Meyers Vænge 15, 2450 Copenhagen, Denmark – sequence: 2 givenname: Carlos I. surname: Cabrera-Rodríguez fullname: Cabrera-Rodríguez, Carlos I. organization: Greencovery, Droevendaalsesteeg 4, 6708 PB Wageningen, The Netherlands – sequence: 3 givenname: Francisco surname: Caparrós-Salvador fullname: Caparrós-Salvador, Francisco organization: Greencovery, Droevendaalsesteeg 4, 6708 PB Wageningen, The Netherlands – sequence: 4 givenname: Cristiano surname: Varrone fullname: Varrone, Cristiano organization: Section for Sustainable Biotechnology, Aalborg University Copenhagen, A.C. Meyers Vænge 15, 2450 Copenhagen, Denmark – sequence: 5 givenname: Adrie J.J. surname: Straathof fullname: Straathof, Adrie J.J. email: A.J.J.Straathof@tudelft.nl organization: Department of Biotechnology, Delft University of Technology, van der Maasweg 9, 2629 HZ Delft, The Netherlands |
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Keywords | Medium chain carboxylic acids Hexanoic acid CO2-expanded methanol Anion exchange chromatography Co-fermentation of organic wastes |
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•C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate... |
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SubjectTerms | Anion exchange chromatography Co-fermentation of organic wastes CO2-expanded methanol Hexanoic acid Medium chain carboxylic acids |
Title | Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption |
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