Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption

[Display omitted] •C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate and heptanoate.•Longer carboxylates were also easier desorbed, allowing their enrichment.•Hexanoate and heptanoate were concentrated up to 0.2...

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Published inBioresource technology Vol. 319; p. 124178
Main Authors Fernando-Foncillas, Clara, Cabrera-Rodríguez, Carlos I., Caparrós-Salvador, Francisco, Varrone, Cristiano, Straathof, Adrie J.J.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.01.2021
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Abstract [Display omitted] •C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate and heptanoate.•Longer carboxylates were also easier desorbed, allowing their enrichment.•Hexanoate and heptanoate were concentrated up to 0.29 mol/kg and 0.18 mol/kg, respectively. The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO2-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates.
AbstractList [Display omitted] •C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate and heptanoate.•Longer carboxylates were also easier desorbed, allowing their enrichment.•Hexanoate and heptanoate were concentrated up to 0.29 mol/kg and 0.18 mol/kg, respectively. The aim of this work was to recover a mixture of carboxylates ranging from 2 to 7 carbon atoms using a strong anion exchange resin, followed by desorption with CO2-expanded methanol. Medium chain carboxylates hexanoate and heptanoate adsorbed better than acetate, and the corresponding medium chain carboxylic acids desorbed easier than acetic acid. Consequently, hexanoate and heptanoate were concentrated up to 14.6 and 20.7 times, respectively. These findings will enable effective separation and purification of the produced carboxylic acids. Notably, the presence of inorganic ions in the sample, such as chloride, decreased the adsorption affinity compared to a synthetic mixture only of carboxylates.
ArticleNumber 124178
Author Fernando-Foncillas, Clara
Straathof, Adrie J.J.
Cabrera-Rodríguez, Carlos I.
Caparrós-Salvador, Francisco
Varrone, Cristiano
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Keywords Medium chain carboxylic acids
Hexanoic acid
CO2-expanded methanol
Anion exchange chromatography
Co-fermentation of organic wastes
Language English
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Snippet [Display omitted] •C1-C7 carboxylates were successfully recovered from fermented organic waste.•Strong anion exchange resin preferentially adsorbed hexanoate...
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StartPage 124178
SubjectTerms Anion exchange chromatography
Co-fermentation of organic wastes
CO2-expanded methanol
Hexanoic acid
Medium chain carboxylic acids
Title Highly selective recovery of medium chain carboxylates from co-fermented organic wastes using anion exchange with carbon dioxide expanded methanol desorption
URI https://dx.doi.org/10.1016/j.biortech.2020.124178
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