MnO modified carbon nanotubes as a sulfur host with enhanced performance in Li/S batteries
Lithium/sulfur (Li/S) batteries have become promising future power sources owing to the high energy density. Carbon materials are the most used sulfur hosts, but their ability to adsorb polysulfide intermediates has been unreliable, thus recently many researchers have turned their interest to metal...
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| Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 4; no. 33; pp. 12858 - 12864 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.2016
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| Subjects | |
| Online Access | Get full text |
| ISSN | 2050-7488 2050-7496 2050-7496 |
| DOI | 10.1039/c6ta04445j |
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| Abstract | Lithium/sulfur (Li/S) batteries have become promising future power sources owing to the high energy density. Carbon materials are the most used sulfur hosts, but their ability to adsorb polysulfide intermediates has been unreliable, thus recently many researchers have turned their interest to metal oxide materials. Here, we manufactured a composite of carbon nanotubes modified with manganese oxide nanoparticles (CNTs/MnO) as a sulfur host material. In Li/S cells, the CNTs/MnOS cathode showed a rather better cycling stability over 100 cycles than a CNTsS cathode with the same carbon/sulfur weight ratio of about 1:8. In addition, the CNTs/MnOS cathode presented an initial discharge capacity of 716 mA h g
1
at a high current density of 5.0C, in contrast to the result of only 415 mA h g
1
with the CNTsS cathode. Physical and electrochemical characterization proved that the MnO modification does not vary the surface area of the CNTs but lowers their electrical conductivity. By carefully comparing the differences in the 1
st
discharge capacities of the two cathodes, the MnO modification could obviously improve the initial utilization of S especially at high current densities. The improved electrochemical characteristics of the CNTs/MnOS electrode can be attributed to its properties of a stronger adsorption capability for polysulfides.
MnO modified CNTs are applied as an efficient sulfur host to improve the performance of Li/S batteries due to the strong polysulfide adsorbability. |
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| AbstractList | Lithium/sulfur (Li/S) batteries have become promising future power sources owing to the high energy density. Carbon materials are the most used sulfur hosts, but their ability to adsorb polysulfide intermediates has been unreliable, thus recently many researchers have turned their interest to metal oxide materials. Here, we manufactured a composite of carbon nanotubes modified with manganese oxide nanoparticles (CNTs/MnO) as a sulfur host material. In Li/S cells, the CNTs/MnO–S cathode showed a rather better cycling stability over 100 cycles than a CNTs–S cathode with the same carbon/sulfur weight ratio of about 1 : 8. In addition, the CNTs/MnO–S cathode presented an initial discharge capacity of 716 mA h g⁻¹ at a high current density of 5.0C, in contrast to the result of only 415 mA h g⁻¹ with the CNTs–S cathode. Physical and electrochemical characterization proved that the MnO modification does not vary the surface area of the CNTs but lowers their electrical conductivity. By carefully comparing the differences in the 1ˢᵗ discharge capacities of the two cathodes, the MnO modification could obviously improve the initial utilization of S especially at high current densities. The improved electrochemical characteristics of the CNTs/MnO–S electrode can be attributed to its properties of a stronger adsorption capability for polysulfides. Lithium/sulfur (Li/S) batteries have become promising future power sources owing to the high energy density. Carbon materials are the most used sulfur hosts, but their ability to adsorb polysulfide intermediates has been unreliable, thus recently many researchers have turned their interest to metal oxide materials. Here, we manufactured a composite of carbon nanotubes modified with manganese oxide nanoparticles (CNTs/MnO) as a sulfur host material. In Li/S cells, the CNTs/MnOS cathode showed a rather better cycling stability over 100 cycles than a CNTsS cathode with the same carbon/sulfur weight ratio of about 1:8. In addition, the CNTs/MnOS cathode presented an initial discharge capacity of 716 mA h g 1 at a high current density of 5.0C, in contrast to the result of only 415 mA h g 1 with the CNTsS cathode. Physical and electrochemical characterization proved that the MnO modification does not vary the surface area of the CNTs but lowers their electrical conductivity. By carefully comparing the differences in the 1 st discharge capacities of the two cathodes, the MnO modification could obviously improve the initial utilization of S especially at high current densities. The improved electrochemical characteristics of the CNTs/MnOS electrode can be attributed to its properties of a stronger adsorption capability for polysulfides. MnO modified CNTs are applied as an efficient sulfur host to improve the performance of Li/S batteries due to the strong polysulfide adsorbability. Lithium/sulfur (Li/S) batteries have become promising future power sources owing to the high energy density. Carbon materials are the most used sulfur hosts, but their ability to adsorb polysulfide intermediates has been unreliable, thus recently many researchers have turned their interest to metal oxide materials. Here, we manufactured a composite of carbon nanotubes modified with manganese oxide nanoparticles (CNTs/MnO) as a sulfur host material. In Li/S cells, the CNTs/MnO-S cathode showed a rather better cycling stability over 100 cycles than a CNTs-S cathode with the same carbon/sulfur weight ratio of about 1 : 8. In addition, the CNTs/MnO-S cathode presented an initial discharge capacity of 716 mA h g-1 at a high current density of 5.0C, in contrast to the result of only 415 mA h g-1 with the CNTs-S cathode. Physical and electrochemical characterization proved that the MnO modification does not vary the surface area of the CNTs but lowers their electrical conductivity. By carefully comparing the differences in the 1st discharge capacities of the two cathodes, the MnO modification could obviously improve the initial utilization of S especially at high current densities. The improved electrochemical characteristics of the CNTs/MnO-S electrode can be attributed to its properties of a stronger adsorption capability for polysulfides. Lithium/sulfur (Li/S) batteries have become promising future power sources owing to the high energy density. Carbon materials are the most used sulfur hosts, but their ability to adsorb polysulfide intermediates has been unreliable, thus recently many researchers have turned their interest to metal oxide materials. Here, we manufactured a composite of carbon nanotubes modified with manganese oxide nanoparticles (CNTs/MnO) as a sulfur host material. In Li/S cells, the CNTs/MnO–S cathode showed a rather better cycling stability over 100 cycles than a CNTs–S cathode with the same carbon/sulfur weight ratio of about 1 : 8. In addition, the CNTs/MnO–S cathode presented an initial discharge capacity of 716 mA h g −1 at a high current density of 5.0C, in contrast to the result of only 415 mA h g −1 with the CNTs–S cathode. Physical and electrochemical characterization proved that the MnO modification does not vary the surface area of the CNTs but lowers their electrical conductivity. By carefully comparing the differences in the 1 st discharge capacities of the two cathodes, the MnO modification could obviously improve the initial utilization of S especially at high current densities. The improved electrochemical characteristics of the CNTs/MnO–S electrode can be attributed to its properties of a stronger adsorption capability for polysulfides. |
| Author | Wu, Qi-Hui Deng, Dingrong Tian, Zhaowu Lei, Ming Zheng, Mingsen Dong, Quanfeng An, Taihua |
| AuthorAffiliation | Department of Chemistry College of Chemical Engineering and Materials Science College of Chemistry and Chemical Engineering Xiamen University Collaborative Innovation Centre of Chemistry for Energy Materials State Key Lab. of Physical Chemistry of Solid Surfaces Quanzhou Normal University Department of Materials Chemistry |
| AuthorAffiliation_xml | – sequence: 0 name: Xiamen University Collaborative Innovation Centre of Chemistry for Energy Materials – sequence: 0 name: Department of Chemistry – sequence: 0 name: College of Chemistry and Chemical Engineering – sequence: 0 name: Department of Materials Chemistry – sequence: 0 name: State Key Lab. of Physical Chemistry of Solid Surfaces – sequence: 0 name: College of Chemical Engineering and Materials Science – sequence: 0 name: Quanzhou Normal University |
| Author_xml | – sequence: 1 givenname: Taihua surname: An fullname: An, Taihua – sequence: 2 givenname: Dingrong surname: Deng fullname: Deng, Dingrong – sequence: 3 givenname: Ming surname: Lei fullname: Lei, Ming – sequence: 4 givenname: Qi-Hui surname: Wu fullname: Wu, Qi-Hui – sequence: 5 givenname: Zhaowu surname: Tian fullname: Tian, Zhaowu – sequence: 6 givenname: Mingsen surname: Zheng fullname: Zheng, Mingsen – sequence: 7 givenname: Quanfeng surname: Dong fullname: Dong, Quanfeng |
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| Snippet | Lithium/sulfur (Li/S) batteries have become promising future power sources owing to the high energy density. Carbon materials are the most used sulfur hosts,... |
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| SubjectTerms | adsorption Carbon Carbon nanotubes Cathodes Electric batteries electrical conductivity electrochemistry energy density High current Lithium lithium batteries manganese oxides nanoparticles Polysulfides Sulfur surface area |
| Title | MnO modified carbon nanotubes as a sulfur host with enhanced performance in Li/S batteries |
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