Synthesis and Reactivity of Monocyclopentadienyltantalum(V) Siloxide Complexes

The new tantalum siloxide complex [TaCp*Me3(OSiPh3)] (1; Cp* = η5‐C5Me5) has been synthesized. The reaction of complex 1 with isocyanides yields the respective azatantalacyclopropanes [TaCp*(η2‐Me2CNxylyl)Me(OSiPh3)] (2; xylyl = 2,6‐dimethylphenyl) and [TaCp*(η2‐Me2CNtBu)Me(OSiPh3)] (3). The molecul...

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Published in	European Journal of Inorganic Chemistry Vol. 2008; no. 19; pp. 3062 - 3067
Main Authors	Conde, Ana, Fandos, Rosa, Otero, Antonio, Rodríguez, Ana, Terreros, Pilar
Format	Book Review Journal Article
Language	English
Published	Weinheim WILEY-VCH Verlag 01.07.2008 WILEY‐VCH Verlag Wiley
Subjects	Chemistry Chemistry, Inorganic & Nuclear Cyclopentadienyl ligands Physical Sciences Science & Technology Silicon Tantalum OLEFIN POLYMERIZATION CATALYSTS EPOXIDATION CATALYSTS ACTIVE-SITES CRYSTAL-STRUCTURES SILSESQUIOXANE COMPLEXES ETHYLENE POLYMERIZATION silicon MOLECULAR-STRUCTURES cyclopentadienyl ligands TERT-BUTYL ISOCYANIDE tantalum CARBON-MONOXIDE REDUCTION SOLUBLE MODEL SYSTEMS
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Abstract	The new tantalum siloxide complex [TaCpMe3(OSiPh3)] (1; Cp = η5‐C5Me5) has been synthesized. The reaction of complex 1 with isocyanides yields the respective azatantalacyclopropanes [TaCp(η2‐Me2CNxylyl)Me(OSiPh3)] (2; xylyl = 2,6‐dimethylphenyl) and [TaCp(η2‐Me2CNtBu)Me(OSiPh3)] (3). The molecular structure of complex 2 has been established by X‐ray diffraction. Complex 2 reacts with a second mol‐equiv. of 2,6‐xylyl isocyanide to yield [TaCp(Nxylyl)[N(xylyl)CMe=CMe2)(OSiPh3)] (4). The reaction of 1 with carbon monoxide gives [TaCp(O)(OCMe=CMe2)(OSiPh3)] (5), whereas 1 reacts with B(C6F5)3 to give the corresponding cationic compound [TaCp*Me2(OSiPh3)][MeB(C6F5)3] (6). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) We report the reactivity of tantalum complexes containing a siloxide group as anancillary ligand with several unsaturated organic molecules such as isocyanides or carbon monoxide.
AbstractList	The new tantalum siloxide complex [TaCpMe3(OSiPh3)] (1; Cp = η5‐C5Me5) has been synthesized. The reaction of complex 1 with isocyanides yields the respective azatantalacyclopropanes [TaCp(η2‐Me2CNxylyl)Me(OSiPh3)] (2; xylyl = 2,6‐dimethylphenyl) and [TaCp(η2‐Me2CNtBu)Me(OSiPh3)] (3). The molecular structure of complex 2 has been established by X‐ray diffraction. Complex 2 reacts with a second mol‐equiv. of 2,6‐xylyl isocyanide to yield [TaCp(Nxylyl)[N(xylyl)CMe=CMe2)(OSiPh3)] (4). The reaction of 1 with carbon monoxide gives [TaCp(O)(OCMe=CMe2)(OSiPh3)] (5), whereas 1 reacts with B(C6F5)3 to give the corresponding cationic compound [TaCpMe2(OSiPh3)][MeB(C6F5)3] (6). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) We report the reactivity of tantalum complexes containing a siloxide group as anancillary ligand with several unsaturated organic molecules such as isocyanides or carbon monoxide. Abstract The new tantalum siloxide complex [TaCpMe 3 (OSiPh 3 )] ( 1 ; Cp* = η 5 ‐C 5 Me 5 ) has been synthesized. The reaction of complex 1 with isocyanides yields the respective azatantalacyclopropanes [TaCp(η 2 ‐Me 2 CNxylyl)Me(OSiPh 3 )] ( 2 ; xylyl = 2,6‐dimethylphenyl) and [TaCp(η 2 ‐Me 2 CN t Bu)Me(OSiPh 3 )] ( 3 ). The molecular structure of complex 2 has been established by X‐ray diffraction. Complex 2 reacts with a second mol‐equiv. of 2,6‐xylyl isocyanide to yield [TaCp(Nxylyl)[N(xylyl)CMe=CMe 2 )(OSiPh 3 )] ( 4 ). The reaction of 1 with carbon monoxide gives [TaCp(O)(OCMe=CMe 2 )(OSiPh 3 )] ( 5 ), whereas 1 reacts with B(C 6 F 5 ) 3 to give the corresponding cationic compound [TaCpMe 2 (OSiPh 3 )][MeB(C 6 F 5 ) 3 ] ( 6 ). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008) The new tantalum siloxide complex [TaCpMe-3(OSiPh3)] (1; Cp* = eta(5)-C5Me5)) has been synthesized. The reaction of complex 1 with isocyanides yields the respective azatantalacyclopropanes [TaCp(eta(5)-Me(2)CNxylyl)Me(OSiPh3)] (2; xylyl = 2,6-dimethylphenyl) and [TaCp(eta(2)-Me(2)CNtBu)Me(OSiPh3)] (3). The molecular structure of complex 2 has been established by X-ray diffraction. Complex 2 reacts with a second mol-equiv. of 2,6-xylyl isocyanide to yield [TaCp(Nxylyl)-[N(xylyl)CMe=CMe2)(OSiPh3)] (4). The reaction of 1 with carbon monoxide gives [TaCp(O)(OCMe=CMe2)(OSiPh3)] (5), whereas 1 reacts with B(C6F5)(3) to give the corresponding cationic compound [TaCp*Me-2(OSiPh3)][MeB(C6F5)(3)] (6). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
Author	Terreros, Pilar Otero, Antonio Rodríguez, Ana Conde, Ana Fandos, Rosa
Author_xml	– sequence: 1 givenname: Ana surname: Conde fullname: Conde, Ana organization: Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, Facultad de Ciencias del Medio Ambiente, Avda. Carlos III, s/n, 45071 Toledo, Spain – sequence: 2 givenname: Rosa surname: Fandos fullname: Fandos, Rosa organization: Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, Facultad de Ciencias del Medio Ambiente, Avda. Carlos III, s/n, 45071 Toledo, Spain – sequence: 3 givenname: Antonio surname: Otero fullname: Otero, Antonio organization: Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, Facultad de Químicas, Campus de Ciudad Real, Avda. Camilo José Cela, 10, 13071 Ciudad Real, Spain – sequence: 4 givenname: Ana surname: Rodríguez fullname: Rodríguez, Ana organization: Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, ETS Ingenieros Industriales, Campus de Ciudad Real, Avda. Camilo José Cela, 3,13071 Ciudad Real, Spain – sequence: 5 givenname: Pilar surname: Terreros fullname: Terreros, Pilar organization: Instituto de Catálisis y Petroleoquímica, CSIC, Cantoblanco, 28049 Madrid, Spain
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SSID	ssj0003036
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Snippet	The new tantalum siloxide complex [TaCpMe3(OSiPh3)] (1; Cp = η5‐C5Me5) has been synthesized. The reaction of complex 1 with isocyanides yields the respective... The new tantalum siloxide complex [TaCpMe-3(OSiPh3)] (1; Cp = eta(5)-C5Me5)) has been synthesized. The reaction of complex 1 with isocyanides yields the... Abstract The new tantalum siloxide complex [TaCpMe 3 (OSiPh 3 )] ( 1 ; Cp = η 5 ‐C 5 Me 5 ) has been synthesized. The reaction of complex 1 with isocyanides...
Source	Web of Science
SourceID	crossref webofscience wiley istex
SourceType	Aggregation Database Enrichment Source Index Database Publisher
StartPage	3062
SubjectTerms	Chemistry Chemistry, Inorganic & Nuclear Cyclopentadienyl ligands Physical Sciences Science & Technology Silicon Tantalum
Title	Synthesis and Reactivity of Monocyclopentadienyltantalum(V) Siloxide Complexes
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