Metal chloride‐graphite intercalation compounds for rechargeable metal‐ion batteries

The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal‐ion batteries (MIBs). Notably, the...

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Published inCarbon energy Vol. 6; no. 10
Main Authors Lu, Anbang, Wang, Fei, Liu, Zhendong, Wang, Yuchen, Gu, Yue, Wang, Shuang, Ye, Chong, Liu, Quanbing, Zhang, Chengzhi, Tan, Jun
Format Journal Article
LanguageEnglish
Published Beijing John Wiley & Sons, Inc 01.10.2024
Wiley
Subjects
additional capacity
Alternative energy sources
Anodes
Batteries
Carbon
Chloride
Chlorides
Conductivity
Decoupling
Design
Design optimization
Electrodes
Energy storage
Graphite
graphite intercalation compounds
high conductivity
Intercalation
Intercalation compounds
Interlayers
Introduced species
Lithium
metal chloride
Metal chlorides
Metals
metal‐ion batteries
Phase transitions
Silicon
Tap density
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Abstract The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal‐ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC‐GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC‐GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC‐GICs, necessary improvements and prospects in the near future have been put forward. Metal chloride‐graphite intercalation compounds are recognized as promising alternative electrode materials of graphite. It presents unique electronic characteristics and allows more metal‐ion storage with several energy storage mechanisms. Based on the designing of the graphite host, intercalator, and electrode structure, metal chloride‐graphite intercalation compounds delivered high capacity, fast electrochemical kinetics, and superior cycling stability for rechargeable metal‐ion batteries.
AbstractList The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal‐ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC‐GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC‐GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC‐GICs, necessary improvements and prospects in the near future have been put forward.
Abstract The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal‐ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC‐GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC‐GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC‐GICs, necessary improvements and prospects in the near future have been put forward.
The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal‐ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC‐GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC‐GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC‐GICs, necessary improvements and prospects in the near future have been put forward.
The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density from graphite, and these are considered as one of the promising alternatives of graphite anode in rechargeable metal‐ion batteries (MIBs). Notably, the special interlayer decoupling effects and the introduction of extra conversion capacity by metal chloride could greatly break the capacity limitation of graphite anodes and achieve higher energy density in MIBs. The optimization of both graphite host and metal chloride species with specific structures endows MC‐GICs with design feasibility for different application requirements of different MIBs, such as several times the actual capacity compared to graphite anodes, rapid migration of large carriers, and other properties. Herein, a brief review has been provided with the latest understanding of conductivity characteristics and energy storage mechanisms of MC‐GICs and their interesting performance features of full potential application in rechargeable MIBs. Based on the existing research of MC‐GICs, necessary improvements and prospects in the near future have been put forward. Metal chloride‐graphite intercalation compounds are recognized as promising alternative electrode materials of graphite. It presents unique electronic characteristics and allows more metal‐ion storage with several energy storage mechanisms. Based on the designing of the graphite host, intercalator, and electrode structure, metal chloride‐graphite intercalation compounds delivered high capacity, fast electrochemical kinetics, and superior cycling stability for rechargeable metal‐ion batteries.
Author Tan, Jun
Wang, Fei
Lu, Anbang
Wang, Yuchen
Liu, Zhendong
Gu, Yue
Wang, Shuang
Zhang, Chengzhi
Ye, Chong
Liu, Quanbing
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  fullname: Tan, Jun
  email: tanjun@jihualab.ac.cn
  organization: Foshan University
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Snippet The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density from...
Abstract The typical metal chloride‐graphite intercalation compounds (MC‐GICs) inherit intercalation capacity, high charge conductivity, and high tap density...
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SubjectTerms additional capacity
Alternative energy sources
Anodes
Batteries
Carbon
Chloride
Chlorides
Conductivity
Decoupling
Design
Design optimization
Electrodes
Energy storage
Graphite
graphite intercalation compounds
high conductivity
Intercalation
Intercalation compounds
Interlayers
Introduced species
Lithium
metal chloride
Metal chlorides
Metals
metal‐ion batteries
Phase transitions
Silicon
Tap density
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Title Metal chloride‐graphite intercalation compounds for rechargeable metal‐ion batteries
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