A Highly Efficient BODIPY Based Turn-off Fluorescent Probe for Detecting Cu2
Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and characterized.The emission spectra of HHPBA-BODIPY exhibited an intensive green fluores...
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| Published in | Journal of fluorescence Vol. 30; no. 4; pp. 883 - 890 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
Springer US
01.07.2020
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1053-0509 1573-4994 1573-4994 |
| DOI | 10.1007/s10895-020-02544-9 |
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| Abstract | Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and characterized.The emission spectra of HHPBA-BODIPY exhibited an intensive green fluorescence around 510 nm, with a maximum absorption near 500 nm. When Cu
2+
ions are present, the fluorescence at 510 nm can be quenched with a good linearity between the copper ion concentrationand the fluorescence intensity and the detection limit is 0.35 μM. HHPBA-BODIPY is also selective toward Cu
2+
, while other metal ions show no interfere except Fe
3+
and Cr
3+
ions. In addition, HHPBA-BODIPY also proved efficient to detect Cu
2+
in water samples which offers the possibility to detect trace amount of Cu
2+
for environmental monitoring. Copper ions; BODIPY; fluorescent probe. |
|---|---|
| AbstractList | Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and characterized.The emission spectra of HHPBA-BODIPY exhibited an intensive green fluorescence around 510 nm, with a maximum absorption near 500 nm. When Cu2+ ions are present, the fluorescence at 510 nm can be quenched with a good linearity between the copper ion concentrationand the fluorescence intensity and the detection limit is 0.35 μM. HHPBA-BODIPY is also selective toward Cu2+, while other metal ions show no interfere except Fe3+ and Cr3+ ions. In addition, HHPBA-BODIPY also proved efficient to detect Cu2+ in water samples which offers the possibility to detect trace amount of Cu2+ for environmental monitoring. Copper ions; BODIPY; fluorescent probe.Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and characterized.The emission spectra of HHPBA-BODIPY exhibited an intensive green fluorescence around 510 nm, with a maximum absorption near 500 nm. When Cu2+ ions are present, the fluorescence at 510 nm can be quenched with a good linearity between the copper ion concentrationand the fluorescence intensity and the detection limit is 0.35 μM. HHPBA-BODIPY is also selective toward Cu2+, while other metal ions show no interfere except Fe3+ and Cr3+ ions. In addition, HHPBA-BODIPY also proved efficient to detect Cu2+ in water samples which offers the possibility to detect trace amount of Cu2+ for environmental monitoring. Copper ions; BODIPY; fluorescent probe. Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and characterized.The emission spectra of HHPBA-BODIPY exhibited an intensive green fluorescence around 510 nm, with a maximum absorption near 500 nm. When Cu 2+ ions are present, the fluorescence at 510 nm can be quenched with a good linearity between the copper ion concentrationand the fluorescence intensity and the detection limit is 0.35 μM. HHPBA-BODIPY is also selective toward Cu 2+ , while other metal ions show no interfere except Fe 3+ and Cr 3+ ions. In addition, HHPBA-BODIPY also proved efficient to detect Cu 2+ in water samples which offers the possibility to detect trace amount of Cu 2+ for environmental monitoring. Copper ions; BODIPY; fluorescent probe. Based on boron-dipyrromethene (BODIPY), taking 2-hydroxy-N-(2-hydroxyphenyl)benzamide as recognition site, a new fluorescent probe HHPBA-BODIPY aimed at sensitively detecting Cu ions was designed, synthesized and characterized.The emission spectra of HHPBA-BODIPY exhibited an intensive green fluorescence around 510 nm, with a maximum absorption near 500 nm. When Cu2+ ions are present, the fluorescence at 510 nm can be quenched with a good linearity between the copper ion concentrationand the fluorescence intensity and the detection limit is 0.35 μM. HHPBA-BODIPY is also selective toward Cu2+, while other metal ions show no interfere except Fe3+ and Cr3+ ions. In addition, HHPBA-BODIPY also proved efficient to detect Cu2+ in water samples which offers the possibility to detect trace amount of Cu2+ for environmental monitoring. Copper ions; BODIPY; fluorescent probe. |
| Author | Du, Ziyao Sun, Ruopei Chen, Suwen Wu, Wangsuo Jiang, Chao Wang, Lusheng |
| Author_xml | – sequence: 1 givenname: Ruopei surname: Sun fullname: Sun, Ruopei organization: School of Nuclear Science and Technology, Lanzhou University – sequence: 2 givenname: Lusheng surname: Wang fullname: Wang, Lusheng organization: School of Nuclear Science and Technology, Lanzhou University – sequence: 3 givenname: Chao surname: Jiang fullname: Jiang, Chao organization: School of Nuclear Science and Technology, Lanzhou University – sequence: 4 givenname: Ziyao surname: Du fullname: Du, Ziyao organization: School of Nuclear Science and Technology, Lanzhou University – sequence: 5 givenname: Suwen orcidid: 0000-0001-8083-0052 surname: Chen fullname: Chen, Suwen email: chensuwen@lzu.edu.cn organization: School of Nuclear Science and Technology, Lanzhou University – sequence: 6 givenname: Wangsuo surname: Wu fullname: Wu, Wangsuo organization: School of Nuclear Science and Technology, Lanzhou University |
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| SubjectTerms | Analytical Chemistry Benzamide Biochemistry Biological and Medical Physics Biomedical and Life Sciences Biomedicine Biophysics Biotechnology Boron Chemical synthesis Copper Emission spectra Environmental monitoring Fluorescent indicators Linearity Original Article Water sampling |
| Title | A Highly Efficient BODIPY Based Turn-off Fluorescent Probe for Detecting Cu2 |
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