A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities

Hydrogen is seen as a sustainable fuel of the future, yet the vast majority of global hydrogen production comes from the reformation of fossil fuels. Electrolytic water splitting using proton exchange membrane electrolysers (PEMEs) provides a pathway to sustainable hydrogen production through coupli...

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Published inChemical science (Cambridge) Vol. 9; no. 6; pp. 1621 - 1626
Main Authors Kirkaldy, Niall, Chisholm, Greig, Chen, Jia-Jia, Cronin, Leroy
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 14.02.2018
Subjects
Current density
Decoupling
Electrolysis
Fossil fuels
Gas evolution
Gas mixtures
High current
Hydrogen
Hydrogen production
Hydrogen storage
Oxygen production
Rechargeable batteries
Renewable energy sources
Water splitting
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Abstract Hydrogen is seen as a sustainable fuel of the future, yet the vast majority of global hydrogen production comes from the reformation of fossil fuels. Electrolytic water splitting using proton exchange membrane electrolysers (PEMEs) provides a pathway to sustainable hydrogen production through coupling to renewable energy sources, but can suffer from gas crossover at low current densities and high operating pressures, causing explosive gas mixtures and decreasing cell lifetimes. Here we demonstrate the application of a highly stable, organic electron-coupled proton buffer (ECPB) which allows the decoupling of hydrogen and oxygen production during water splitting. By merging concepts from redox flow battery and PEM electrolysis research, we have built a hybrid electrolyser device capable of decoupling the gas evolution reactions during water splitting. The device improves on both gas purity and operational safety, while still working at industrially relevant, high current density. Anthraquinone-2,7-disulfonic acid was used as an organic redox mediator in this two-step process, producing H at current densities of up to 3.71 A cm at 2.00 V, extending the concept of the ECPB.
AbstractList Hydrogen is seen as a sustainable fuel of the future, yet the vast majority of global hydrogen production comes from the reformation of fossil fuels. Electrolytic water splitting using proton exchange membrane electrolysers (PEMEs) provides a pathway to sustainable hydrogen production through coupling to renewable energy sources, but can suffer from gas crossover at low current densities and high operating pressures, causing explosive gas mixtures and decreasing cell lifetimes. Here we demonstrate the application of a highly stable, organic electron-coupled proton buffer (ECPB) which allows the decoupling of hydrogen and oxygen production during water splitting. By merging concepts from redox flow battery and PEM electrolysis research, we have built a hybrid electrolyser device capable of decoupling the gas evolution reactions during water splitting. The device improves on both gas purity and operational safety, while still working at industrially relevant, high current density. Anthraquinone-2,7-disulfonic acid was used as an organic redox mediator in this two-step process, producing H 2 at current densities of up to 3.71 A cm −2 at 2.00 V, extending the concept of the ECPB.
Hydrogen is seen as a sustainable fuel of the future, yet the vast majority of global hydrogen production comes from the reformation of fossil fuels. Electrolytic water splitting using proton exchange membrane electrolysers (PEMEs) provides a pathway to sustainable hydrogen production through coupling to renewable energy sources, but can suffer from gas crossover at low current densities and high operating pressures, causing explosive gas mixtures and decreasing cell lifetimes. Here we demonstrate the application of a highly stable, organic electron-coupled proton buffer (ECPB) which allows the decoupling of hydrogen and oxygen production during water splitting. By merging concepts from redox flow battery and PEM electrolysis research, we have built a hybrid electrolyser device capable of decoupling the gas evolution reactions during water splitting. The device improves on both gas purity and operational safety, while still working at industrially relevant, high current density. Anthraquinone-2,7-disulfonic acid was used as an organic redox mediator in this two-step process, producing H at current densities of up to 3.71 A cm at 2.00 V, extending the concept of the ECPB.
Hydrogen is seen as a sustainable fuel of the future, yet the vast majority of global hydrogen production comes from the reformation of fossil fuels. Electrolytic water splitting using proton exchange membrane electrolysers (PEMEs) provides a pathway to sustainable hydrogen production through coupling to renewable energy sources, but can suffer from gas crossover at low current densities and high operating pressures, causing explosive gas mixtures and decreasing cell lifetimes. Here we demonstrate the application of a highly stable, organic electron-coupled proton buffer (ECPB) which allows the decoupling of hydrogen and oxygen production during water splitting. By merging concepts from redox flow battery and PEM electrolysis research, we have built a hybrid electrolyser device capable of decoupling the gas evolution reactions during water splitting. The device improves on both gas purity and operational safety, while still working at industrially relevant, high current density. Anthraquinone-2,7-disulfonic acid was used as an organic redox mediator in this two-step process, producing H2 at current densities of up to 3.71 A cm−2 at 2.00 V, extending the concept of the ECPB.
Author Chisholm, Greig
Cronin, Leroy
Chen, Jia-Jia
Kirkaldy, Niall
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  givenname: Jia-Jia
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  surname: Chen
  fullname: Chen, Jia-Jia
  email: Lee.Cronin@glasgow.ac.uk
  organization: WestCHEM , School of Chemistry , University of Glasgow , University Avenue , Glasgow , G12 8QQ , UK . Email: Lee.Cronin@glasgow.ac.uk
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  surname: Cronin
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  organization: WestCHEM , School of Chemistry , University of Glasgow , University Avenue , Glasgow , G12 8QQ , UK . Email: Lee.Cronin@glasgow.ac.uk
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Snippet Hydrogen is seen as a sustainable fuel of the future, yet the vast majority of global hydrogen production comes from the reformation of fossil fuels....
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SubjectTerms Current density
Decoupling
Electrolysis
Fossil fuels
Gas evolution
Gas mixtures
High current
Hydrogen
Hydrogen production
Hydrogen storage
Oxygen production
Rechargeable batteries
Renewable energy sources
Water splitting
Title A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities
URI https://www.ncbi.nlm.nih.gov/pubmed/29675207
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