Innovative Methylcellulose-Polyvinyl Pyrrolidone-Based Solid Polymer Electrolytes Impregnated with Potassium Salt: Ion Conduction and Thermal Properties

In this research, innovative green and sustainable solid polymer electrolytes (SPEs) based on plasticized methylcellulose/polyvinyl pyrrolidone/potassium carbonate (MC/PVP/K2CO3) were examined. The MC/PVP/K2CO3 SPE system with five distinct ethylene carbonate (EC) concentrations as a plasticizer was...

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Published inPolymers Vol. 14; no. 15; p. 3055
Main Authors Adam, Abdullahi Abbas, Ali, Mohammed Khalil Mohammed, Dennis, John Ojur, Soleimani, Hassan, Shukur, Muhammad Fadhlullah Bin Abd, Ibnaouf, Khalid Hassan, Aldaghri, Osamah A., Ibrahem, Moez A., Abdel All, Naglaa F. M., Bashir Abdulkadir, Abubakar
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 28.07.2022
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Abstract In this research, innovative green and sustainable solid polymer electrolytes (SPEs) based on plasticized methylcellulose/polyvinyl pyrrolidone/potassium carbonate (MC/PVP/K2CO3) were examined. The MC/PVP/K2CO3 SPE system with five distinct ethylene carbonate (EC) concentrations as a plasticizer was successfully designed. Frequency-dependent conductivity plots were used to investigate the conduction mechanism of the SPEs. Electrochemical potential window stability and the cation transfer number of the SPEs were studied via linear sweep voltammetry (LSV) and transference number measurement (TNM), respectively. Additionally, the structural behavior of the SPEs was analyzed using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), X-ray diffractometry (XRD), and differential scanning calorimetry (DSC) techniques. The SPE film complexed with 15 wt.% EC measured a maximum conductivity of 3.88 × 10−4 Scm−1. According to the results of the transference number examination, cations that record a transference number of 0.949 are the primary charge carriers. An EDLC was fabricated based on the highest conducting sample that recorded a specific capacitance of 54.936 Fg−1 at 5 mVs−1.
AbstractList In this research, innovative green and sustainable solid polymer electrolytes (SPEs) based on plasticized methylcellulose/polyvinyl pyrrolidone/potassium carbonate (MC/PVP/K2CO3) were examined. The MC/PVP/K2CO3 SPE system with five distinct ethylene carbonate (EC) concentrations as a plasticizer was successfully designed. Frequency-dependent conductivity plots were used to investigate the conduction mechanism of the SPEs. Electrochemical potential window stability and the cation transfer number of the SPEs were studied via linear sweep voltammetry (LSV) and transference number measurement (TNM), respectively. Additionally, the structural behavior of the SPEs was analyzed using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), X-ray diffractometry (XRD), and differential scanning calorimetry (DSC) techniques. The SPE film complexed with 15 wt.% EC measured a maximum conductivity of 3.88 × 10−4 Scm−1. According to the results of the transference number examination, cations that record a transference number of 0.949 are the primary charge carriers. An EDLC was fabricated based on the highest conducting sample that recorded a specific capacitance of 54.936 Fg−1 at 5 mVs−1.
In this research, innovative green and sustainable solid polymer electrolytes (SPEs) based on plasticized methylcellulose/polyvinyl pyrrolidone/potassium carbonate (MC/PVP/K 2 CO 3 ) were examined. The MC/PVP/K 2 CO 3 SPE system with five distinct ethylene carbonate (EC) concentrations as a plasticizer was successfully designed. Frequency-dependent conductivity plots were used to investigate the conduction mechanism of the SPEs. Electrochemical potential window stability and the cation transfer number of the SPEs were studied via linear sweep voltammetry (LSV) and transference number measurement (TNM), respectively. Additionally, the structural behavior of the SPEs was analyzed using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), X-ray diffractometry (XRD), and differential scanning calorimetry (DSC) techniques. The SPE film complexed with 15 wt.% EC measured a maximum conductivity of 3.88 × 10 −4 Scm −1 . According to the results of the transference number examination, cations that record a transference number of 0.949 are the primary charge carriers. An EDLC was fabricated based on the highest conducting sample that recorded a specific capacitance of 54.936 Fg −1 at 5 mVs −1 .
Author Bashir Abdulkadir, Abubakar
Abdel All, Naglaa F. M.
Dennis, John Ojur
Aldaghri, Osamah A.
Ali, Mohammed Khalil Mohammed
Soleimani, Hassan
Shukur, Muhammad Fadhlullah Bin Abd
Ibrahem, Moez A.
Adam, Abdullahi Abbas
Ibnaouf, Khalid Hassan
AuthorAffiliation 4 Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh 13318, Saudi Arabia; khiahmed@imamu.edu.sa (K.H.I.); odaghri@imamu.edu.sa (O.A.A.); 9@imamm.org (M.A.I.); nfabdelall@imamu.edu.sa (N.F.M.A.A.)
2 Centre of Innovative Nanoscience and Nanotechnology (COINN), Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
1 Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia; jdennis100@gmail.com (J.O.D.); hassan.soleimani@utp.edu.my (H.S.); mfadhlullah.ashukur@utp.edu.my (M.F.B.A.S.); abubakarbashir150@gmail.com (A.B.A.)
3 Department of Physics, Al-Qalam University Katsina, Katsina 820252, Nigeria
AuthorAffiliation_xml – name: 2 Centre of Innovative Nanoscience and Nanotechnology (COINN), Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
– name: 4 Department of Physics, College of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh 13318, Saudi Arabia; khiahmed@imamu.edu.sa (K.H.I.); odaghri@imamu.edu.sa (O.A.A.); 9@imamm.org (M.A.I.); nfabdelall@imamu.edu.sa (N.F.M.A.A.)
– name: 1 Department of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia; jdennis100@gmail.com (J.O.D.); hassan.soleimani@utp.edu.my (H.S.); mfadhlullah.ashukur@utp.edu.my (M.F.B.A.S.); abubakarbashir150@gmail.com (A.B.A.)
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SSID ssj0000456617
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Snippet In this research, innovative green and sustainable solid polymer electrolytes (SPEs) based on plasticized methylcellulose/polyvinyl pyrrolidone/potassium...
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proquest
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StartPage 3055
SubjectTerms Cations
Cellulose
Conduction
Current carriers
Electrochemical potential
Electrolytes
Emission analysis
Field emission microscopy
Field emission spectroscopy
Fluorides
Fourier transforms
Infrared analysis
Molten salt electrolytes
Polymer blends
Polymers
Polyvinyl alcohol
Potassium
Potassium carbonate
Potassium salts
Solid electrolytes
Thermodynamic properties
Viscosity
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  providerName: ProQuest
Title Innovative Methylcellulose-Polyvinyl Pyrrolidone-Based Solid Polymer Electrolytes Impregnated with Potassium Salt: Ion Conduction and Thermal Properties
URI https://www.proquest.com/docview/2700762754
https://search.proquest.com/docview/2702180686
https://pubmed.ncbi.nlm.nih.gov/PMC9370478
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