Novel Co/UiO-66 metal organic framework catalyst for oxygen reduction reaction in microbial fuel cells

To improve the power generation of microbial fuel cell (MFC), the cathode is modified to increase its oxygen reduction reaction (ORR) activity by using Co/UiO-66, which derived from pyrolyzing the mixture of Co(NO3) 2 as the metal precursor incorporated with NH2-UiO-66. It was found that Co/UiO-66 (...

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Published inE3S web of conferences Vol. 245; p. 3017
Main Authors Chen, Zhenxin, Wu, Qikai, Zhang, Hongguo
Format Journal Article Conference Proceeding
LanguageEnglish
Published Les Ulis EDP Sciences 01.01.2021
Subjects
Biochemical fuel cells
Carbon
Catalysts
Cathodes
Chemical reduction
Electrocatalysis
Electrocatalysts
Electrodes
Electrolytes
Electrons
Fuel cells
Fuel technology
Metal-organic frameworks
Microorganisms
Nitrogen
Oxygen
Oxygen reduction reactions
Porous materials
Pyrolysis
Sustainable development
Voltammetry
Work stations
China
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Abstract To improve the power generation of microbial fuel cell (MFC), the cathode is modified to increase its oxygen reduction reaction (ORR) activity by using Co/UiO-66, which derived from pyrolyzing the mixture of Co(NO3) 2 as the metal precursor incorporated with NH2-UiO-66. It was found that Co/UiO-66 (MOF-900) has been developed as a high-performance electrocatalyst for ORR at a pyrolysis temperature of 900 °C. Therefore, Co/UiO-66 should be a promising oxygen reduction catalyst for application in MFCs. This study provides technical and theoretical validation for the MFC performance improvement by ORR active MOF-derived catalysts modified cathodes.
AbstractList To improve the power generation of microbial fuel cell (MFC), the cathode is modified to increase its oxygen reduction reaction (ORR) activity by using Co/UiO-66, which derived from pyrolyzing the mixture of Co(NO3)2 as the metal precursor incorporated with NH2-UiO-66. It was found that Co/UiO-66 (MOF-900) has been developed as a high-performance electrocatalyst for ORR at a pyrolysis temperature of 900 °C. Therefore, Co/UiO-66 should be a promising oxygen reduction catalyst for application in MFCs. This study provides technical and theoretical validation for the MFC performance improvement by ORR active MOF-derived catalysts modified cathodes.
To improve the power generation of microbial fuel cell (MFC), the cathode is modified to increase its oxygen reduction reaction (ORR) activity by using Co/UiO-66, which derived from pyrolyzing the mixture of Co(NO3) 2 as the metal precursor incorporated with NH2-UiO-66. It was found that Co/UiO-66 (MOF-900) has been developed as a high-performance electrocatalyst for ORR at a pyrolysis temperature of 900 °C. Therefore, Co/UiO-66 should be a promising oxygen reduction catalyst for application in MFCs. This study provides technical and theoretical validation for the MFC performance improvement by ORR active MOF-derived catalysts modified cathodes.
Author Wu, Qikai
Chen, Zhenxin
Zhang, Hongguo
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StartPage 3017
SubjectTerms Biochemical fuel cells
Carbon
Catalysts
Cathodes
Chemical reduction
Electrocatalysis
Electrocatalysts
Electrodes
Electrolytes
Electrons
Fuel cells
Fuel technology
Metal-organic frameworks
Microorganisms
Nitrogen
Oxygen
Oxygen reduction reactions
Porous materials
Pyrolysis
Sustainable development
Voltammetry
Work stations
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Title Novel Co/UiO-66 metal organic framework catalyst for oxygen reduction reaction in microbial fuel cells
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