Tetranortriterpenoid derivatives from Turraea parvifolia (Meliaceae)
The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A (12α-acetoxy-7α,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12α-acetoxy-7α,21-dihydroxy-24,25,26,27...
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Published in | Phytochemistry (Oxford) Vol. 62; no. 8; pp. 1173 - 1178 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
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Elsevier Ltd
01.04.2003
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Abstract | The methanol extract of the seeds of
Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A (12α-acetoxy-7α,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12α-acetoxy-7α,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7α,12α-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11-
epi-21-hydroxytoonacilide, 11-
epi-23-hydroxytoonacilide and turraparvin D (12α-acetoxy-7α-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam).
The methanol extract of the seed of
Turraea parvifolia has yielded 12α-acetoxyazadironolide, 11-
epi-21-hydroxytoonacilide, 11-
epi-23-hydroxytoonacilide and turraparvins A, B, C and D (
1). |
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AbstractList | The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12alpha-acetoxyazadironolide, turraparvin A (12alpha-acetoxy-7alpha,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12alpha-acetoxy-7alpha,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7alpha,12alpha-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11-cpi-21-hydroxytoonacilide, 11-epi-23-hydroxytoonacilide and turraparvin D (12alpha-acetoxy-7alpha-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam). (C) 2003 Elsevier Science Ltd. All rights reserved. The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12alpha-acetoxyazadironolide, turraparvin A (12alpha-acetoxy-7alpha,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12alpha-acetoxy-7alpha,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7alpha,12alpha-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11-epi-21-hydroxytoonacilide, 11-epi-23-hydroxytoonacilide and turraparvin D (12alpha-acetoxy-7alpha-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam). The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A (12α-acetoxy-7α,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12α-acetoxy-7α,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7α,12α-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11- epi-21-hydroxytoonacilide, 11- epi-23-hydroxytoonacilide and turraparvin D (12α-acetoxy-7α-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam). The methanol extract of the seed of Turraea parvifolia has yielded 12α-acetoxyazadironolide, 11- epi-21-hydroxytoonacilide, 11- epi-23-hydroxytoonacilide and turraparvins A, B, C and D ( 1). |
Author | Mulholland, Dulcie A. Cheplogoi, Peter K. |
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CitedBy_id | crossref_primary_10_1039_C4RA04652H crossref_primary_10_1016_S0031_9422_03_00342_X crossref_primary_10_1021_ol102745h crossref_primary_10_1016_j_phytochem_2004_06_019 crossref_primary_10_1021_np070476x crossref_primary_10_1016_j_tet_2007_05_107 crossref_primary_10_1016_j_bjp_2014_11_009 crossref_primary_10_1039_c1cc11388g crossref_primary_10_1039_b501301c crossref_primary_10_3762_bjoc_10_15 crossref_primary_10_1016_j_tet_2019_130779 crossref_primary_10_1021_cr9004023 crossref_primary_10_1080_00032719_2017_1327536 crossref_primary_10_1021_ol061466a crossref_primary_10_1111_jen_12485 crossref_primary_10_1021_acs_jnatprod_4c00313 crossref_primary_10_1016_j_phytochem_2014_05_019 crossref_primary_10_1016_j_phytochem_2021_112661 crossref_primary_10_1002_hlca_200890055 crossref_primary_10_1177_1934578X1000500606 crossref_primary_10_1016_j_fitote_2015_01_018 crossref_primary_10_1016_j_steroids_2006_04_010 crossref_primary_10_1016_j_tet_2016_09_061 crossref_primary_10_1016_j_indcrop_2020_112275 crossref_primary_10_1021_np401089h |
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Keywords | 11- epi-21-Hydroxytoonacilide, 11- epi-23-Hydroxytoonacilide and turraparvin D Turraea parvifolia Turraparvin A Turraparvin C Meliaceae 12α-Acetoxyazadironolide Turraparvin B OBTUSIFOLIA NILOTICA HOLSTII 12 alpha-acetoxyazadironolide TRITERPENOIDS FLORIBUNDA ROBUSTA 11-epi-23-hydroxytoonacilide and turraparvin D turraparvin A 11-epi-21-hydroxytoonacilide AZADIRACHTA-INDICA LIMONOIDS turraparvin B turraparvin C Terpenoid Seeds Molecular structure Dicotyledones Angiospermae Triterpene Isolation Spermatophyta Small tree Turrdea parvifolia: 12α-Acetoxyazadironolide: Turraparvin A: Turraparvin B. Turraparvin C: 11-epi-21-Hydroxytoonacilide. 11-epi-23-Hydroxytoonacilide and turraparvin D |
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Snippet | The methanol extract of the seeds of
Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A... The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12alpha-acetoxyazadironolide, turraparvin A... |
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SubjectTerms | 11- epi-21-Hydroxytoonacilide, 11- epi-23-Hydroxytoonacilide and turraparvin D 12α-Acetoxyazadironolide Biochemistry & Molecular Biology Biological and medical sciences Chemical constitution Fundamental and applied biological sciences. Psychology Life Sciences & Biomedicine Limonins - chemistry Limonins - isolation & purification Meliaceae Meliaceae - chemistry Nuclear Magnetic Resonance, Biomolecular Plant physiology and development Plant Sciences Science & Technology Seeds - chemistry Turraea parvifolia Turraparvin A Turraparvin B Turraparvin C |
Title | Tetranortriterpenoid derivatives from Turraea parvifolia (Meliaceae) |
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