Tetranortriterpenoid derivatives from Turraea parvifolia (Meliaceae)

The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A (12α-acetoxy-7α,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12α-acetoxy-7α,21-dihydroxy-24,25,26,27...

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Published inPhytochemistry (Oxford) Vol. 62; no. 8; pp. 1173 - 1178
Main Authors Cheplogoi, Peter K., Mulholland, Dulcie A.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 01.04.2003
Elsevier
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Abstract The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A (12α-acetoxy-7α,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12α-acetoxy-7α,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7α,12α-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11- epi-21-hydroxytoonacilide, 11- epi-23-hydroxytoonacilide and turraparvin D (12α-acetoxy-7α-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam). The methanol extract of the seed of Turraea parvifolia has yielded 12α-acetoxyazadironolide, 11- epi-21-hydroxytoonacilide, 11- epi-23-hydroxytoonacilide and turraparvins A, B, C and D ( 1).
AbstractList The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12alpha-acetoxyazadironolide, turraparvin A (12alpha-acetoxy-7alpha,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12alpha-acetoxy-7alpha,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7alpha,12alpha-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11-cpi-21-hydroxytoonacilide, 11-epi-23-hydroxytoonacilide and turraparvin D (12alpha-acetoxy-7alpha-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam). (C) 2003 Elsevier Science Ltd. All rights reserved.
The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12alpha-acetoxyazadironolide, turraparvin A (12alpha-acetoxy-7alpha,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12alpha-acetoxy-7alpha,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7alpha,12alpha-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11-epi-21-hydroxytoonacilide, 11-epi-23-hydroxytoonacilide and turraparvin D (12alpha-acetoxy-7alpha-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam).
The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A (12α-acetoxy-7α,23-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-olide), turraparvin B (12α-acetoxy-7α,21-dihydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), turraparvin C (7α,12α-diacetoxy-21-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-23,21-olide), 11- epi-21-hydroxytoonacilide, 11- epi-23-hydroxytoonacilide and turraparvin D (12α-acetoxy-7α-hydroxy-24,25,26,27-tetranor-3-oxoapotirucalla-1,14,20(22)-trien-21,23-lactam). The methanol extract of the seed of Turraea parvifolia has yielded 12α-acetoxyazadironolide, 11- epi-21-hydroxytoonacilide, 11- epi-23-hydroxytoonacilide and turraparvins A, B, C and D ( 1).
Author Mulholland, Dulcie A.
Cheplogoi, Peter K.
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Issue 8
Keywords 11- epi-21-Hydroxytoonacilide, 11- epi-23-Hydroxytoonacilide and turraparvin D
Turraea parvifolia
Turraparvin A
Turraparvin C
Meliaceae
12α-Acetoxyazadironolide
Turraparvin B
OBTUSIFOLIA
NILOTICA
HOLSTII
12 alpha-acetoxyazadironolide
TRITERPENOIDS
FLORIBUNDA
ROBUSTA
11-epi-23-hydroxytoonacilide and turraparvin D
turraparvin A
11-epi-21-hydroxytoonacilide
AZADIRACHTA-INDICA
LIMONOIDS
turraparvin B
turraparvin C
Terpenoid
Seeds
Molecular structure
Dicotyledones
Angiospermae
Triterpene
Isolation
Spermatophyta
Small tree
Turrdea parvifolia: 12α-Acetoxyazadironolide: Turraparvin A: Turraparvin B. Turraparvin C: 11-epi-21-Hydroxytoonacilide. 11-epi-23-Hydroxytoonacilide and turraparvin D
Language English
License CC BY 4.0
Copyright 2003 Elsevier Science Ltd.
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Snippet The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12α-acetoxyazadironolide, turraparvin A...
The methanol extract of the seeds of Turraea parvifolia has yielded seven novel triterpenoid derivatives: 12alpha-acetoxyazadironolide, turraparvin A...
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SubjectTerms 11- epi-21-Hydroxytoonacilide, 11- epi-23-Hydroxytoonacilide and turraparvin D
12α-Acetoxyazadironolide
Biochemistry & Molecular Biology
Biological and medical sciences
Chemical constitution
Fundamental and applied biological sciences. Psychology
Life Sciences & Biomedicine
Limonins - chemistry
Limonins - isolation & purification
Meliaceae
Meliaceae - chemistry
Nuclear Magnetic Resonance, Biomolecular
Plant physiology and development
Plant Sciences
Science & Technology
Seeds - chemistry
Turraea parvifolia
Turraparvin A
Turraparvin B
Turraparvin C
Title Tetranortriterpenoid derivatives from Turraea parvifolia (Meliaceae)
URI https://dx.doi.org/10.1016/S0031-9422(03)00028-1
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https://www.ncbi.nlm.nih.gov/pubmed/12648531
https://search.proquest.com/docview/73118747
Volume 62
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