Highly Active and Selective Platinum(0)-Carbene Complexes. Efficient, Catalytic Hydrosilylation of Functionalised Olefins

Readily available N‐heterocyclic platinum‐carbene complexes 1 are highly efficient catalysts for the regioselective hydrosilylation of alkenes. These novel organometallics tolerate a wide range of functional and protecting groups, can be stored for prolonged periods of time and are particularly acti...

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Published inAdvanced synthesis & catalysis Vol. 346; no. 12; pp. 1429 - 1434
Main Authors Markó, István E., Stérin, Sébastien, Buisine, Olivier, Berthon, Guillaume, Michaud, Guillaume, Tinant, Bernard, Declercq, Jean-Paul
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.10.2004
WILEY‐VCH Verlag
Wiley
Subjects
alkenes
Chemistry
Chemistry, Applied
Chemistry, Organic
homogeneous catalysis
hydrosilylation
N-heterocyclic carbenes
Physical Sciences
platinum
Science & Technology
ORGANIC-SYNTHESIS
platinum
homogeneous catalysis
LIGANDS
PT
hydrosilylation
CRYSTAL
STYRENE
HYDROSILATION
alkenes
N-heterocyclic carbenes
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Summary:Readily available N‐heterocyclic platinum‐carbene complexes 1 are highly efficient catalysts for the regioselective hydrosilylation of alkenes. These novel organometallics tolerate a wide range of functional and protecting groups, can be stored for prolonged periods of time and are particularly active (TON>106).
Bibliography:ArticleID:ADSC200404048
istex:27D5FF5A3ECE7BF67EE44207439187F51EF93DA8
ark:/67375/WNG-36C79KWZ-2
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200404048