Simultaneous Determination of Cr(III) and Cr(VI) by Differential Pulse Voltammetry Using Modified Screen-Printed Carbon Electrodes in Array Mode
A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen‐printed carbon electrodes (SPCEs) has been proposed. Two different modified carbon working, a Ag/AgCl reference and a carbon counter screen‐printed electrodes have been connected in array mode for...
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Published in | Electroanalysis (New York, N.Y.) Vol. 22; no. 24; pp. 2924 - 2930 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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Weinheim
WILEY-VCH Verlag
01.12.2010
WILEY‐VCH Verlag |
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Abstract | A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen‐printed carbon electrodes (SPCEs) has been proposed. Two different modified carbon working, a Ag/AgCl reference and a carbon counter screen‐printed electrodes have been connected in array mode for the simultaneous determination of Cr(III) and Cr(VI). Mercury films or gold nanoparticles have been ground onto the SPCEs in order to improve their selectivity to each chromium species. The quantification of the peak currents observed at −1.25 V in Hg‐SPCE and −0.1 V in AuNPs‐SPCE were carried out. The method has been applied to the speciation of chromium in waste water from a tannery factory. |
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AbstractList | A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen-printed carbon electrodes (SPCEs) has been proposed. Two different modified carbon working, a Ag/AgCl reference and a carbon counter screen-printed electrodes have been connected in array mode for the simultaneous determination of Cr(III) and Cr(VI). Mercury films or gold nanoparticles have been ground onto the SPCEs in order to improve their selectivity to each chromium species. The quantification of the peak currents observed at -1.25V in Hg-SPCE and -0.1V in AuNPs-SPCE were carried out. The method has been applied to the speciation of chromium in waste water from a tannery factory. A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen‐printed carbon electrodes (SPCEs) has been proposed. Two different modified carbon working, a Ag/AgCl reference and a carbon counter screen‐printed electrodes have been connected in array mode for the simultaneous determination of Cr(III) and Cr(VI). Mercury films or gold nanoparticles have been ground onto the SPCEs in order to improve their selectivity to each chromium species. The quantification of the peak currents observed at −1.25 V in Hg‐SPCE and −0.1 V in AuNPs‐SPCE were carried out. The method has been applied to the speciation of chromium in waste water from a tannery factory. Abstract A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen‐printed carbon electrodes (SPCEs) has been proposed. Two different modified carbon working, a Ag/AgCl reference and a carbon counter screen‐printed electrodes have been connected in array mode for the simultaneous determination of Cr(III) and Cr(VI). Mercury films or gold nanoparticles have been ground onto the SPCEs in order to improve their selectivity to each chromium species. The quantification of the peak currents observed at −1.25 V in Hg‐SPCE and −0.1 V in AuNPs‐SPCE were carried out. The method has been applied to the speciation of chromium in waste water from a tannery factory. |
Author | Arcos-Martínez, M. Julia Calvo-Pérez, Ana Alonso-Lomillo, M. Asunción Domínguez-Renedo, Olga |
Author_xml | – sequence: 1 givenname: Ana surname: Calvo-Pérez fullname: Calvo-Pérez, Ana organization: Department of Chemistry. Faculty of Sciences. University of Burgos. Plaza Misael Bañuelos s/n, 09001 Burgos, Spain – sequence: 2 givenname: Olga surname: Domínguez-Renedo fullname: Domínguez-Renedo, Olga email: olgado@ubu.es, malomillo@ubu.es organization: Department of Chemistry. Faculty of Sciences. University of Burgos. Plaza Misael Bañuelos s/n, 09001 Burgos, Spain – sequence: 3 givenname: M. Asunción surname: Alonso-Lomillo fullname: Alonso-Lomillo, M. Asunción organization: Department of Chemistry. Faculty of Sciences. University of Burgos. Plaza Misael Bañuelos s/n, 09001 Burgos, Spain – sequence: 4 givenname: M. Julia surname: Arcos-Martínez fullname: Arcos-Martínez, M. Julia organization: Department of Chemistry. Faculty of Sciences. University of Burgos. Plaza Misael Bañuelos s/n, 09001 Burgos, Spain |
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Snippet | A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen‐printed carbon electrodes (SPCEs) has been proposed. Two... Abstract A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen‐printed carbon electrodes (SPCEs) has been... A new procedure for the speciation of chromium by means of differential pulse voltammetry using screen-printed carbon electrodes (SPCEs) has been proposed. Two... |
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SubjectTerms | Arrays Carbon Chromium Chromium speciation Differential pulse voltammetry Electrodes Gold nanoparticles Manufacturing engineering Mercury film Nanoparticles Screen-printed electrodes Speciation Statistical process control Voltammetry |
Title | Simultaneous Determination of Cr(III) and Cr(VI) by Differential Pulse Voltammetry Using Modified Screen-Printed Carbon Electrodes in Array Mode |
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