Emergence of Copper‐Mediated Formation of C–C Bonds
Copper‐catalyzed cross‐coupling reactions have found widespread application in carbon–carbon or carbon–heteroatom bond formation. The relatively low toxicity, ease of handling, and low cost of these versatile complexes make them attractive for the elaboration of new methodologies and for the obtaini...
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Published in | European journal of organic chemistry Vol. 2017; no. 2; pp. 209 - 228 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Wiley Subscription Services, Inc
10.01.2017
Wiley-VCH Verlag |
Subjects | |
Online Access | Get full text |
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Abstract | Copper‐catalyzed cross‐coupling reactions have found widespread application in carbon–carbon or carbon–heteroatom bond formation. The relatively low toxicity, ease of handling, and low cost of these versatile complexes make them attractive for the elaboration of new methodologies and for the obtaining of new compounds. We focus on recent methods for the copper‐mediated formation of carbon–carbon bonds illustrated by different coupling reactions: cross‐dehydrogenative coupling, decarboxylative cross‐coupling, Sonogashira‐type reactions, Suzuki‐type reactions, and Neigishi‐type reactions. Domino reactions and, finally, more atypical reactions are also illustrated.
An overview of copper‐catalyzed C–C bond reactions through the main recently developed methodologies is presented. |
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AbstractList | Copper-catalyzed cross-coupling reactions have found widespread application in carbon-carbon or carbon-heteroatom bond formation. The relatively low toxicity, ease of handling, and low cost of these versatile complexes make them attractive for the elaboration of new methodologies and for the obtaining of new compounds. We focus on recent methods for the copper-mediated formation of carbon-carbon bonds illustrated by different coupling reactions: cross-dehydrogenative coupling, decarboxylative cross-coupling, Sonogashira-type reactions, Suzuki-type reactions, and Neigishi-type reactions. Domino reactions and, finally, more atypical reactions are also illustrated. Copper‐catalyzed cross‐coupling reactions have found widespread application in carbon–carbon or carbon–heteroatom bond formation. The relatively low toxicity, ease of handling, and low cost of these versatile complexes make them attractive for the elaboration of new methodologies and for the obtaining of new compounds. We focus on recent methods for the copper‐mediated formation of carbon–carbon bonds illustrated by different coupling reactions: cross‐dehydrogenative coupling, decarboxylative cross‐coupling, Sonogashira‐type reactions, Suzuki‐type reactions, and Neigishi‐type reactions. Domino reactions and, finally, more atypical reactions are also illustrated. An overview of copper‐catalyzed C–C bond reactions through the main recently developed methodologies is presented. |
Author | Maaliki, Carine Thibonnet, Jérôme Thiery, Emilie |
Author_xml | – sequence: 1 givenname: Carine surname: Maaliki fullname: Maaliki, Carine organization: Université François‐Rabelais – sequence: 2 givenname: Emilie surname: Thiery fullname: Thiery, Emilie email: emilie.thiery@univ‐tours.fr organization: Université François‐Rabelais – sequence: 3 givenname: Jérôme surname: Thibonnet fullname: Thibonnet, Jérôme email: jerome.thibonnet@univ‐tours.fr organization: Université François‐Rabelais |
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Copyright | 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Distributed under a Creative Commons Attribution 4.0 International License |
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Keywords | C-C coupling carbon carbon bond liaison carbone carbone décarboxylation déhydrogenase domini reactions decarboxylative coupling dehydrogenative coupling Copper synthetic methods |
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Snippet | Copper‐catalyzed cross‐coupling reactions have found widespread application in carbon–carbon or carbon–heteroatom bond formation. The relatively low toxicity,... Copper-catalyzed cross-coupling reactions have found widespread application in carbon-carbon or carbon-heteroatom bond formation. The relatively low toxicity,... |
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StartPage | 209 |
SubjectTerms | Carbon Chemical Sciences Copper C–C coupling Decarboxylative coupling Dehydrogenative coupling Domino reactions Organic chemistry Synthetic methods |
Title | Emergence of Copper‐Mediated Formation of C–C Bonds |
URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fejoc.201600540 https://www.proquest.com/docview/1859418633 https://hal.science/hal-01601331 |
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