Ryabchikovite, CuMg(Si2O6), a new pyroxene group mineral, and some genetic features of natural anhydrous copper silicates

• Published in: The American mineralogist Vol. 108; no. 7; pp. 1399 - 1408
• Main Authors: Shchipalkina, Nadezhda V, Vereshchagin, Oleg S, Pekov, Igor V, Belakovskiy, Dmitry I, Koshlyakova, Natalia N, Shilovskikh, Vladimir V, Pankin, Dmitriy V, Britvin, Sergey N, Sandalov, Fedor D, Sidorov, Evgeny G
• Format: Journal Article
• Language: English
• Published: Washington Mineralogical Society of America 26.07.2023; Walter de Gruyter GmbH
• Subjects: Aluminum oxide; Anhydrite; aphthialite; Arsenatnaya Fumarole; Asia; Calcium magnesium silicates; chain silicates; Chemical composition; clinoenstatite; clinopyroxene; Commonwealth of Independent States; Concretions; Copper; copper minerals; copper ores; copper silicate; copper silicates; Crusts; crystal chemistry; crystal structure; Crystallization; Crystals; description; Diopside; Economic geology; Electron back scatter; Electron microprobe; Electron probes; exhalative processes; Ferric oxide; Fluorophlogopite; formula; fumarole sublimate; fumaroles; gas transport reaction; Haematite; Hematite; High temperature; Kamchatka Peninsula; Kamchatka Russian Federation; lattice parameters; metal ores; mineral deposits, genesis; Mineralogy; Minerals; naturally anhydrous copper silicates; new mineral; new minerals; pyroxene; pyroxene group; Pyroxenes; Russian Federation; Ryabchikovite; Silica; Silicates; Silicon dioxide; space groups; Tolbachik; Tolbachik volcano; Unit cell; Volcanoes; Zinc oxide
• ISSN: 0003-004X; 1945-3027
• DOI: 10.2138/am-2022-8620

Ryabchikovite, ideally CuMg(Si2O6), a new pyroxene-group mineral (IMA No. 2021-011) was discovered in exhalations of the active Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. The associated minerals are diopside, hematite, cuprospinel, fluorophlogopite, anhydrite, johillerite, tilasite, and aphthitalite-group sulfates. Ryabchikovite forms thin (up to 25 µm), light brown to reddish-brown epitactic crusts on short-prismatic brownish-gray crystals of diopside (up to 0.5 mm). The new mineral is optically biaxial (+), α = 1.685(5), β = 1.690(5), γ = 1.703(4), and 2V (meas) = 60(15)°. The average chemical composition (wt%, electron microprobe data) is: MgO 18.05, CaO 0.77, CuO 26.46, ZnO 2.23, Al2O3 0.93, Fe2O3 1.89, SiO2 50.10, total 100.43. The empirical formula calculated based on 6 O atoms per formulas unit is (Mg1.05Cu0.78Zn0.06Fe0.063+Ca0.03)(Si1.96Al0.04O6). Electron backscattered diffraction and powder X-ray diffraction show that ryabchikovite is a Cu,Mg-ordered analog of clinoenstatite. Ryabchikovite adopts the space group P21/c and has the following unit-cell parameters: a = 9.731(9), b = 8.929(8), c = 5.221(4) A, β = 110.00(6)°, V = 426.3(7) A3, and Z = 4. Ryabchikovite is named in honor of the outstanding Russian geochemist and petrologist Igor Dmitrievich Ryabchikov (1937-2017). Our studies reveal that copper analogs of rock-forming minerals could be found in fumarolic systems. Their crystallization does not require high temperatures or/and pressures (below 500 °C/Pa).