Bottlebrush polymers: From controlled synthesis, self-assembly, properties to applications

Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic optoelectronics, templates for crafting one-dimensional (1D) nanomaterials, energy storage, and biomedical devices. The densely-grafted side chains along th...

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Published inProgress in polymer science Vol. 116; p. 101387
Main Authors Li, Zili, Tang, Miao, Liang, Shuang, Zhang, Mingyue, Biesold, Gill M., He, Yanjie, Hao, Shu-Meng, Choi, Woosung, Liu, Yijiang, Peng, Juan, Lin, Zhiqun
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2021
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Abstract Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic optoelectronics, templates for crafting one-dimensional (1D) nanomaterials, energy storage, and biomedical devices. The densely-grafted side chains along the linear backbones afford BBPs with extended cylindrical shapes and the absence of entanglements. The architectures of BBPs can be readily tuned by manipulating the chemical structures and compositions, both of which govern the viscoelastic properties, melt processability, and alignment of BBPs. This enables the crafting of BBPs with controlled dimensions, compositions, and architectures by capitalizing on advanced synthetic techniques. However, challenges remain in the synthesis and applications of BBPs with precisely controlled architectures. This review aims to provide a comprehensive and critical summary that highlights the recent advances in BBPs in terms of their controlled syntheses, self-assembly, properties, and applications. In addition, challenges facing the syntheses and applications of BBPs will be underscored, with the corresponding solutions to these issues for improving the control over chemical structures (e.g., introducing conjugated side chains), compositions (e.g., other than the widely used polynorbornene or polyacrylate backbone), and utilities (e.g., as solid-state electrolyte in energy storage devices) of BBPs. [Display omitted]
AbstractList Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic optoelectronics, templates for crafting one-dimensional (1D) nanomaterials, energy storage, and biomedical devices. The densely-grafted side chains along the linear backbones afford BBPs with extended cylindrical shapes and the absence of entanglements. The architectures of BBPs can be readily tuned by manipulating the chemical structures and compositions, both of which govern the viscoelastic properties, melt processability, and alignment of BBPs. This enables the crafting of BBPs with controlled dimensions, compositions, and architectures by capitalizing on advanced synthetic techniques. However, challenges remain in the synthesis and applications of BBPs with precisely controlled architectures. This review aims to provide a comprehensive and critical summary that highlights the recent advances in BBPs in terms of their controlled syntheses, self-assembly, properties, and applications. In addition, challenges facing the syntheses and applications of BBPs will be underscored, with the corresponding solutions to these issues for improving the control over chemical structures (e.g., introducing conjugated side chains), compositions (e.g., other than the widely used polynorbornene or polyacrylate backbone), and utilities (e.g., as solid-state electrolyte in energy storage devices) of BBPs. [Display omitted]
ArticleNumber 101387
Author Lin, Zhiqun
Tang, Miao
Liang, Shuang
Biesold, Gill M.
Li, Zili
Hao, Shu-Meng
Peng, Juan
Zhang, Mingyue
He, Yanjie
Liu, Yijiang
Choi, Woosung
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  fullname: Li, Zili
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
– sequence: 2
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  surname: Tang
  fullname: Tang, Miao
  organization: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China
– sequence: 3
  givenname: Shuang
  surname: Liang
  fullname: Liang, Shuang
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
– sequence: 4
  givenname: Mingyue
  surname: Zhang
  fullname: Zhang, Mingyue
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
– sequence: 5
  givenname: Gill M.
  surname: Biesold
  fullname: Biesold, Gill M.
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
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  surname: He
  fullname: He, Yanjie
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
– sequence: 7
  givenname: Shu-Meng
  surname: Hao
  fullname: Hao, Shu-Meng
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
– sequence: 8
  givenname: Woosung
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  fullname: Choi, Woosung
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
– sequence: 9
  givenname: Yijiang
  surname: Liu
  fullname: Liu, Yijiang
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
– sequence: 10
  givenname: Juan
  surname: Peng
  fullname: Peng, Juan
  email: juanpeng@fudan.edu.cn
  organization: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China
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  givenname: Zhiqun
  surname: Lin
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  email: zhiqun.lin@mse.gatech.edu
  organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States
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Structure-property relationship
PNB
ROMP
NVP
SPE
P3HT
DP
PBA
TFA
VOAc
0D
TSCT
RAFT
PPFA
PEGMEMA
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FRET
Bottlebrush polymer
Grafting density
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PNIPAM
PCs
SAXS
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NMP
CTA
PAA
NMR
CTC
PEG
LB
TAD
PG
BBPs
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PCMS
PET
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Snippet Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic...
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StartPage 101387
SubjectTerms 1D Cylindrical morphology
Bottlebrush polymer
Controlled radical polymerization
Grafting density
Self-assembly
Structure-property relationship
Title Bottlebrush polymers: From controlled synthesis, self-assembly, properties to applications
URI https://dx.doi.org/10.1016/j.progpolymsci.2021.101387
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