Bottlebrush polymers: From controlled synthesis, self-assembly, properties to applications
Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic optoelectronics, templates for crafting one-dimensional (1D) nanomaterials, energy storage, and biomedical devices. The densely-grafted side chains along th...
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Published in | Progress in polymer science Vol. 116; p. 101387 |
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Main Authors | , , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.05.2021
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Subjects | |
Online Access | Get full text |
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Abstract | Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic optoelectronics, templates for crafting one-dimensional (1D) nanomaterials, energy storage, and biomedical devices. The densely-grafted side chains along the linear backbones afford BBPs with extended cylindrical shapes and the absence of entanglements. The architectures of BBPs can be readily tuned by manipulating the chemical structures and compositions, both of which govern the viscoelastic properties, melt processability, and alignment of BBPs. This enables the crafting of BBPs with controlled dimensions, compositions, and architectures by capitalizing on advanced synthetic techniques. However, challenges remain in the synthesis and applications of BBPs with precisely controlled architectures. This review aims to provide a comprehensive and critical summary that highlights the recent advances in BBPs in terms of their controlled syntheses, self-assembly, properties, and applications. In addition, challenges facing the syntheses and applications of BBPs will be underscored, with the corresponding solutions to these issues for improving the control over chemical structures (e.g., introducing conjugated side chains), compositions (e.g., other than the widely used polynorbornene or polyacrylate backbone), and utilities (e.g., as solid-state electrolyte in energy storage devices) of BBPs.
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AbstractList | Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic optoelectronics, templates for crafting one-dimensional (1D) nanomaterials, energy storage, and biomedical devices. The densely-grafted side chains along the linear backbones afford BBPs with extended cylindrical shapes and the absence of entanglements. The architectures of BBPs can be readily tuned by manipulating the chemical structures and compositions, both of which govern the viscoelastic properties, melt processability, and alignment of BBPs. This enables the crafting of BBPs with controlled dimensions, compositions, and architectures by capitalizing on advanced synthetic techniques. However, challenges remain in the synthesis and applications of BBPs with precisely controlled architectures. This review aims to provide a comprehensive and critical summary that highlights the recent advances in BBPs in terms of their controlled syntheses, self-assembly, properties, and applications. In addition, challenges facing the syntheses and applications of BBPs will be underscored, with the corresponding solutions to these issues for improving the control over chemical structures (e.g., introducing conjugated side chains), compositions (e.g., other than the widely used polynorbornene or polyacrylate backbone), and utilities (e.g., as solid-state electrolyte in energy storage devices) of BBPs.
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ArticleNumber | 101387 |
Author | Lin, Zhiqun Tang, Miao Liang, Shuang Biesold, Gill M. Li, Zili Hao, Shu-Meng Peng, Juan Zhang, Mingyue He, Yanjie Liu, Yijiang Choi, Woosung |
Author_xml | – sequence: 1 givenname: Zili surname: Li fullname: Li, Zili organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 2 givenname: Miao surname: Tang fullname: Tang, Miao organization: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China – sequence: 3 givenname: Shuang surname: Liang fullname: Liang, Shuang organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 4 givenname: Mingyue surname: Zhang fullname: Zhang, Mingyue organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 5 givenname: Gill M. surname: Biesold fullname: Biesold, Gill M. organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 6 givenname: Yanjie surname: He fullname: He, Yanjie organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 7 givenname: Shu-Meng surname: Hao fullname: Hao, Shu-Meng organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 8 givenname: Woosung surname: Choi fullname: Choi, Woosung organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 9 givenname: Yijiang surname: Liu fullname: Liu, Yijiang organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States – sequence: 10 givenname: Juan surname: Peng fullname: Peng, Juan email: juanpeng@fudan.edu.cn organization: State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China – sequence: 11 givenname: Zhiqun surname: Lin fullname: Lin, Zhiqun email: zhiqun.lin@mse.gatech.edu organization: School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, United States |
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Snippet | Bottlebrush polymers (BBPs) have emerged as intriguing class of materials for an array of applications, including supersoft elastomers, organic... |
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SubjectTerms | 1D Cylindrical morphology Bottlebrush polymer Controlled radical polymerization Grafting density Self-assembly Structure-property relationship |
Title | Bottlebrush polymers: From controlled synthesis, self-assembly, properties to applications |
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