Dynamic rheological behavior of flocculated fumed silica suspensions

• Published in: Journal of rheology (New York : 1978) Vol. 37; no. 6; pp. 1225 - 1235
• Main Authors: Khan, Saad A., Zoeller, Nancy J.
• Format: Journal Article
• Language: English
• Published: Melville, NY Society of Rheology 01.11.1993
• Subjects: Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Physical and chemical studies. Granulometry. Electrokinetic phenomena; FLOCCULATION; OILS; RHEOLOGY; Colloidal suspensions; COLLOIDS; SOL−GEL PROCESS; Sol‐gel transitions; POLYPROPYLENE; Particle interactions; GLYCOLS; LIGHT SCATTERING; SILICA; Suspensions; Light scattering, of suspensions; Dynamic rheological behavior; Solvent effect; Thixotropy; Particle suspension; Sol gel transition; Dynamic elastic modulus; Silica; Rheological properties
• ISSN: 0148-6055; 1520-8516
• DOI: 10.1122/1.550378

Fumed silica suspensions in low molecular weight solvents are used in many photonic and microelectronic applications. The rheology of these thixotropic systems plays a major role in the effectiveness of their usage. In this study, we use dynamic rheological measurements to examine the particle–particle and particle–solvent interactions of fumed silica with hydrophilic and hydrophobic surface groups dispersed in both polar and nonpolar solvents, polypropylene glycol and mineral oil, respectively. We find the mineral oil‐based suspensions to have a frequency‐independent elastic modulus (G ’) for all solids concentration, whereas the polypropylene glycol‐based systems exhibit a ‘‘sol–gel’’ transition to a frequency‐independent G ’ at high concentrations. The results are explained in terms of different solvent particle mechanisms present in the two systems. The behavior of the mineral oil suspensions are dominated by particle–particle interactions through hydrogen bonds, resulting in a gel structure. The polypropylene glycol systems, on the other hand, are dominated by the interactions of the polar solvent with the fumed silica thereby preventing the formation of a 3D gel network. Static light‐scattering experiments are used to probe the microstructure of both suspensions. We find the presence of a gel‐like network in mineral oil but not in polypropylene glycol, corroborating the rheological results. In addition, both rheology and light‐scattering data for the mineral oil suspensions are consistent with the prediction of a diffusion‐limited cluster–cluster aggregation model.