Extinction Coefficients of Triplet–Triplet Absorption Spectra of Organic Molecules in Condensed Phases: A Least‐Squares Analysis

• Published in: Journal of physical and chemical reference data Vol. 16; no. 2; pp. 239 - 260
• Main Authors: Carmichael, Ian, Helman, W. P., Hug, G. L.
• Format: Journal Article
• Language: English
• Published: Melville, NY American Institute of Physics 01.04.1987
• Subjects: Atomic and molecular physics; Exact sciences and technology; Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion); Molecular properties and interactions with photons; Physics; free radicals; LEAST SQUARE FIT; TRIPLETS; ABSORPTION SPECTRA; ORGANIC COMPOUNDS; electronic molecular spectra; transition probabilities for atoms and molecules; EXTINCTION; DATA EVALUATION; Solvent effect; Triplet state; Chemical solution; Statistical analysis; Extinction; Least squares method; Data table; Data processing; Review; Triplet triplet transition; Experimental study; Organic compounds

A global least‐squares technique is developed to assist in the critical evaluation of data consisting of large sets of measurements. The technique is particularly designed to handle sets of data where many of the measurements are relative measurements. A linearization procedure is used to reduce the...