Increased selectivity for allylic oxidation of cyclohexene using TiO2 modified V2O5/MoO3 catalysts
V2O5 and MoO3 mixed oxides supported by SiO2 were studied as the catalysts in the aqueous phase allylic oxidation of cyclohexene to unsaturated alcohol 2-cyclohexene-1-ol and unsaturated ketone 2-cyclohexene-1-one. The additional layer of TiO2 deposited by atomic layer deposition significantly suppr...
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| Published in | Catalysis communications Vol. 99; pp. 43 - 48 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.08.2017
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| Subjects | |
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| Abstract | V2O5 and MoO3 mixed oxides supported by SiO2 were studied as the catalysts in the aqueous phase allylic oxidation of cyclohexene to unsaturated alcohol 2-cyclohexene-1-ol and unsaturated ketone 2-cyclohexene-1-one. The additional layer of TiO2 deposited by atomic layer deposition significantly suppresses the epoxidation pathway and the formation of cyclohexane oxide and cyclohexane-1, 2-diol. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) were used to study the relationship between the structure of the catalysts and their catalytic performance. The effects on the catalytic activity of different solvent, hydrogen peroxide to cyclohexene ratio, and reusability were investigated.
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•V2O5-MoO3 mixed oxides are effective catalysts for selective oxidation of cyclohexene.•Atomic layer deposition was used to precisely deposit a uniform layer of TiO2.•The presence of TiO2 significantly suppressed the formation of byproducts.•The reaction pathways can be controlled by tuning reaction conditions. |
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| AbstractList | V2O5 and MoO3 mixed oxides supported by SiO2 were studied as the catalysts in the aqueous phase allylic oxidation of cyclohexene to unsaturated alcohol 2-cyclohexene-1-ol and unsaturated ketone 2-cyclohexene-1-one. The additional layer of TiO2 deposited by atomic layer deposition significantly suppresses the epoxidation pathway and the formation of cyclohexane oxide and cyclohexane-1, 2-diol. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM) were used to study the relationship between the structure of the catalysts and their catalytic performance. The effects on the catalytic activity of different solvent, hydrogen peroxide to cyclohexene ratio, and reusability were investigated.
[Display omitted]
•V2O5-MoO3 mixed oxides are effective catalysts for selective oxidation of cyclohexene.•Atomic layer deposition was used to precisely deposit a uniform layer of TiO2.•The presence of TiO2 significantly suppressed the formation of byproducts.•The reaction pathways can be controlled by tuning reaction conditions. |
| Author | Yang, Guoqiang Du, Huiyuan Zhang, Zhibing Huff, Matthew D. Lei, Yu |
| Author_xml | – sequence: 1 givenname: Guoqiang surname: Yang fullname: Yang, Guoqiang organization: School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China – sequence: 2 givenname: Matthew D. surname: Huff fullname: Huff, Matthew D. organization: Department of Chemical and Materials Engineering, University of Alabama in Huntsville, Huntsville, AL 35899, USA – sequence: 3 givenname: Huiyuan surname: Du fullname: Du, Huiyuan organization: School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China – sequence: 4 givenname: Zhibing surname: Zhang fullname: Zhang, Zhibing email: zbzhang@nju.edu.cn organization: School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China – sequence: 5 givenname: Yu surname: Lei fullname: Lei, Yu email: yu.lei@uah.edu organization: Department of Chemical and Materials Engineering, University of Alabama in Huntsville, Huntsville, AL 35899, USA |
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| CitedBy_id | crossref_primary_10_1016_j_poly_2023_116281 crossref_primary_10_1080_00958972_2018_1434516 crossref_primary_10_1016_j_mcat_2023_113104 crossref_primary_10_1016_j_ceramint_2018_02_167 crossref_primary_10_1002_slct_201802811 crossref_primary_10_1016_j_catcom_2023_106754 crossref_primary_10_1016_j_micromeso_2019_06_022 crossref_primary_10_1039_C9RA04685B crossref_primary_10_1007_s10562_020_03205_z crossref_primary_10_1007_s13399_023_05102_y crossref_primary_10_1039_C7RA11245A crossref_primary_10_1021_acs_iecr_1c04108 crossref_primary_10_1002_aoc_5094 |
| Cites_doi | 10.1007/s10562-015-1660-y 10.1016/j.catcom.2004.03.005 10.1126/science.281.5383.1646 10.1016/j.apcatb.2014.05.008 10.1016/j.catcom.2008.03.036 10.1002/admi.201600564 10.1016/j.tsf.2007.12.007 10.1016/S0926-860X(01)00472-0 10.1021/cr900056b 10.1016/j.elspec.2004.03.004 10.1006/jcat.1996.0140 10.1366/0003702914336651 10.1021/ar0400140 10.1016/j.jcat.2008.02.007 10.1016/j.molcata.2016.06.002 10.1021/jp5067567 10.1039/C3CY20728E 10.1080/01614940.2015.1041849 10.1021/cs400996j 10.1006/jcat.2001.3355 10.1016/j.apcata.2016.10.010 10.1016/j.surfrep.2016.03.003 10.1021/cs500187q |
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| Keywords | Epoxidation Mixed metal oxides Allylic oxidation Cyclohexene Zeolite Atomic layer deposition |
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| References | Sato, Aoki, Noyori (bb0015) 1998; 281 Silversmit, Depla, Poelman, Marin, De Gryse (bb0105) 2004; 135 Schuchardt, Cardoso, Sercheli, Pereira, da Cruz, Guerreiro, Mandelli, Spinace, Pires (bb0125) 2001; 211 Weissermel, Arpe (bb0010) 2003 Kim, Wachs (bb0045) 2008; 255 Conte, Liu, Murphy, Taylor, Whiston, Hutchings (bb0035) 2016; 146 Meng, Wang, Chen, Zhao, Ma, Gong (bb0050) 2014; 160–161 George (bb0075) 2010; 110 Zimowska, Latka, Mucha, Gurgul, Matachowski (bb0100) 2016; 423 Deubel, Frenking, Gisdakis, Herrmann, Rosch, Sundermeyer (bb0040) 2004; 37 Dou, Tao (bb0025) 2017; 529 Lapisardi, Chiker, Launay, Nogier, Bonardet (bb0065) 2004; 5 Li, Xin, Wang, Guo (bb0120) 1991; 45 Khatib, Oyama (bb0060) 2015; 57 Piernavieja-Hermida, Lu, White, Low, Wu, Elam, Wu, Lei (bb0090) 2016; 8 Lei, Liu, Lu, Libera, Greeley, Elam (bb0095) 2014; 118 Lu, Nuwayhid, Wu, Lei, Amine, Lu (bb0080) 2016; 3 Lu, Elam, Stair (bb0085) 2016; 71 Fraile, Garcia, Mayoral, Vispe (bb0070) 2001; 204 Caetano, Fonseca, Ramos, Vital, Castanheiro (bb0115) 2008; 9 Das, Ferraioli, Bettotti, De Angelis, Mariotto, Pavesi, Di Fabrizio, Soraru (bb0110) 2008; 516 Van de Vyver, Roman-Leshkov (bb0005) 2013; 3 Faraldos, Banares, Anderson, Hu, Wachs, Fierro (bb0055) 1996; 160 Cao, Yu, Peng, Wang (bb0020) 2014; 4 Dou, Zeng (bb0030) 2014; 4 Faraldos (10.1016/j.catcom.2017.05.023_bb0055) 1996; 160 Lei (10.1016/j.catcom.2017.05.023_bb0095) 2014; 118 Sato (10.1016/j.catcom.2017.05.023_bb0015) 1998; 281 Deubel (10.1016/j.catcom.2017.05.023_bb0040) 2004; 37 Zimowska (10.1016/j.catcom.2017.05.023_bb0100) 2016; 423 Piernavieja-Hermida (10.1016/j.catcom.2017.05.023_bb0090) 2016; 8 Lu (10.1016/j.catcom.2017.05.023_bb0085) 2016; 71 Kim (10.1016/j.catcom.2017.05.023_bb0045) 2008; 255 Khatib (10.1016/j.catcom.2017.05.023_bb0060) 2015; 57 Caetano (10.1016/j.catcom.2017.05.023_bb0115) 2008; 9 Weissermel (10.1016/j.catcom.2017.05.023_bb0010) 2003 Li (10.1016/j.catcom.2017.05.023_bb0120) 1991; 45 Conte (10.1016/j.catcom.2017.05.023_bb0035) 2016; 146 Das (10.1016/j.catcom.2017.05.023_bb0110) 2008; 516 Schuchardt (10.1016/j.catcom.2017.05.023_bb0125) 2001; 211 Silversmit (10.1016/j.catcom.2017.05.023_bb0105) 2004; 135 Meng (10.1016/j.catcom.2017.05.023_bb0050) 2014; 160–161 Van de Vyver (10.1016/j.catcom.2017.05.023_bb0005) 2013; 3 Dou (10.1016/j.catcom.2017.05.023_bb0030) 2014; 4 Lu (10.1016/j.catcom.2017.05.023_bb0080) 2016; 3 Fraile (10.1016/j.catcom.2017.05.023_bb0070) 2001; 204 Lapisardi (10.1016/j.catcom.2017.05.023_bb0065) 2004; 5 George (10.1016/j.catcom.2017.05.023_bb0075) 2010; 110 Dou (10.1016/j.catcom.2017.05.023_bb0025) 2017; 529 Cao (10.1016/j.catcom.2017.05.023_bb0020) 2014; 4 |
| References_xml | – volume: 529 start-page: 134 year: 2017 end-page: 142 ident: bb0025 article-title: Selectie epoxidation of cyclohexene with molecular oxygen on catalyst of nanoporous au integrated with MoO publication-title: Appl. Catal. A contributor: fullname: Tao – volume: 4 start-page: 566 year: 2014 end-page: 576 ident: bb0030 article-title: Integrated networks of mesoporous silica nanowires and their bifunctional catalysis-sorption application for oxidative desulfurization publication-title: ACS Catal. contributor: fullname: Zeng – volume: 5 start-page: 277 year: 2004 end-page: 281 ident: bb0065 article-title: A “one-pot” synthesis of adipic acid from cyclohexene under mild conditions with new bifunctional Ti-AlSBA mesostructured catalysts publication-title: Catal. Commun. contributor: fullname: Bonardet – volume: 146 start-page: 126 year: 2016 end-page: 135 ident: bb0035 article-title: Insights into the reaction mechanism of cyclohexane oxidation catalysed by molybdenum blue nanorings publication-title: Catal. Lett. contributor: fullname: Hutchings – volume: 281 start-page: 1646 year: 1998 end-page: 1647 ident: bb0015 article-title: A “green” route to adipic acid: direct oxidation of cyclohexenes with 30 percent hydrogen peroxide publication-title: Science contributor: fullname: Noyori – volume: 160 start-page: 214 year: 1996 end-page: 221 ident: bb0055 article-title: Comparison of silica-supported MoO publication-title: J. Catal. contributor: fullname: Fierro – volume: 118 start-page: 22611 year: 2014 end-page: 22619 ident: bb0095 article-title: Effects of chlorine in titanium oxide on palladium atomic layer deposition publication-title: J. Phys. Chem. C contributor: fullname: Elam – volume: 4 start-page: 1617 year: 2014 end-page: 1625 ident: bb0020 article-title: Selective allylic oxidation of cyclohexene catalyzed by nitrogen-doped carbon nanotubes publication-title: ACS Catal. contributor: fullname: Wang – volume: 160–161 start-page: 161 year: 2014 end-page: 172 ident: bb0050 article-title: Selective oxidation of methanol to dimethoxymethane on V publication-title: Appl. Catal. B contributor: fullname: Gong – volume: 255 start-page: 197 year: 2008 end-page: 205 ident: bb0045 article-title: CH publication-title: J. Catal. contributor: fullname: Wachs – volume: 45 start-page: 874 year: 1991 end-page: 882 ident: bb0120 article-title: FT-IR emission spectroscopy studies of molybdenum oxide and supported molybdena on alumina, silica, zirconia, and titania publication-title: Appl. Spectrosc. contributor: fullname: Guo – volume: 3 start-page: 1465 year: 2013 end-page: 1479 ident: bb0005 article-title: Emerging catalytic processes for the production of Adipic acid publication-title: Catal. Sci. Tech. contributor: fullname: Roman-Leshkov – volume: 8 start-page: 15348 year: 2016 end-page: 15356 ident: bb0090 article-title: Towards ALD thin film stabilized single-atom Pd publication-title: Nano contributor: fullname: Lei – volume: 516 start-page: 6804 year: 2008 end-page: 6807 ident: bb0110 article-title: Si-nanocrystals/SiO publication-title: Thin Solid Films contributor: fullname: Soraru – volume: 204 start-page: 146 year: 2001 end-page: 156 ident: bb0070 article-title: Effect of the reaction conditions on the epoxidation of alkenes with hydrogen peroxide catalyzed by silica-supported titanium derivatives publication-title: J. Catal. contributor: fullname: Vispe – volume: 9 start-page: 1996 year: 2008 end-page: 1999 ident: bb0115 article-title: Esterification of free fatty acids with methanol using heteropolyacids immobilized on silica publication-title: Catal. Commun. contributor: fullname: Castanheiro – volume: 57 start-page: 1 year: 2015 end-page: 39 ident: bb0060 article-title: Direct oxidation of propylene to propylene oxide with molecular oxygen: a review publication-title: Catal. Rev. Sci. Eng. contributor: fullname: Oyama – volume: 135 start-page: 167 year: 2004 end-page: 175 ident: bb0105 article-title: Determination of the V2p XPS binding energies for different vanadium oxidation states (V publication-title: J. Electron Spectrosc. Relat. Phenom. contributor: fullname: De Gryse – volume: 211 start-page: 1 year: 2001 end-page: 17 ident: bb0125 article-title: Cyclohexane oxidation continues to be a challenge publication-title: Appl. Catal. A contributor: fullname: Pires – volume: 37 start-page: 645 year: 2004 end-page: 652 ident: bb0040 article-title: Olefin epoxidation with inorganic peroxides. Solutions to four long-standing controversies on the mechanism of oxygen transfer publication-title: Acc. Chem. Res. contributor: fullname: Sundermeyer – volume: 3 start-page: 1600564 year: 2016 ident: bb0080 article-title: Atomic layer deposition for lithium-based batteries publication-title: Adv. Mater. Interfaces contributor: fullname: Lu – year: 2003 ident: bb0010 article-title: Industrial Organic Chemistry contributor: fullname: Arpe – volume: 71 start-page: 410 year: 2016 end-page: 472 ident: bb0085 article-title: Atomic layer deposition-sequential self-limiting surface reactions for advanced catalyst “bottom-up” synthesis publication-title: Surf. Sci. Rep. contributor: fullname: Stair – volume: 423 start-page: 92 year: 2016 end-page: 104 ident: bb0100 article-title: The continuous conversion of ethanol and water mixtures into hydrogen over Fe publication-title: J. Mol. Catal. A Chem. contributor: fullname: Matachowski – volume: 110 start-page: 111 year: 2010 end-page: 131 ident: bb0075 article-title: Atomic layer deposition: an overview publication-title: Chem. Rev. contributor: fullname: George – volume: 146 start-page: 126 year: 2016 ident: 10.1016/j.catcom.2017.05.023_bb0035 article-title: Insights into the reaction mechanism of cyclohexane oxidation catalysed by molybdenum blue nanorings publication-title: Catal. Lett. doi: 10.1007/s10562-015-1660-y contributor: fullname: Conte – volume: 5 start-page: 277 year: 2004 ident: 10.1016/j.catcom.2017.05.023_bb0065 article-title: A “one-pot” synthesis of adipic acid from cyclohexene under mild conditions with new bifunctional Ti-AlSBA mesostructured catalysts publication-title: Catal. Commun. doi: 10.1016/j.catcom.2004.03.005 contributor: fullname: Lapisardi – volume: 281 start-page: 1646 year: 1998 ident: 10.1016/j.catcom.2017.05.023_bb0015 article-title: A “green” route to adipic acid: direct oxidation of cyclohexenes with 30 percent hydrogen peroxide publication-title: Science doi: 10.1126/science.281.5383.1646 contributor: fullname: Sato – volume: 160–161 start-page: 161 year: 2014 ident: 10.1016/j.catcom.2017.05.023_bb0050 article-title: Selective oxidation of methanol to dimethoxymethane on V2O5-MoO3/γ-Al2O3 catalysts publication-title: Appl. Catal. B doi: 10.1016/j.apcatb.2014.05.008 contributor: fullname: Meng – volume: 9 start-page: 1996 year: 2008 ident: 10.1016/j.catcom.2017.05.023_bb0115 article-title: Esterification of free fatty acids with methanol using heteropolyacids immobilized on silica publication-title: Catal. Commun. doi: 10.1016/j.catcom.2008.03.036 contributor: fullname: Caetano – volume: 3 start-page: 1600564 year: 2016 ident: 10.1016/j.catcom.2017.05.023_bb0080 article-title: Atomic layer deposition for lithium-based batteries publication-title: Adv. Mater. Interfaces doi: 10.1002/admi.201600564 contributor: fullname: Lu – volume: 8 start-page: 15348 year: 2016 ident: 10.1016/j.catcom.2017.05.023_bb0090 article-title: Towards ALD thin film stabilized single-atom Pd1 catalysts publication-title: Nano contributor: fullname: Piernavieja-Hermida – volume: 516 start-page: 6804 year: 2008 ident: 10.1016/j.catcom.2017.05.023_bb0110 article-title: Si-nanocrystals/SiO2 thin films obtained by pyrolysis of sol–gel precursors publication-title: Thin Solid Films doi: 10.1016/j.tsf.2007.12.007 contributor: fullname: Das – volume: 211 start-page: 1 year: 2001 ident: 10.1016/j.catcom.2017.05.023_bb0125 article-title: Cyclohexane oxidation continues to be a challenge publication-title: Appl. Catal. A doi: 10.1016/S0926-860X(01)00472-0 contributor: fullname: Schuchardt – volume: 110 start-page: 111 year: 2010 ident: 10.1016/j.catcom.2017.05.023_bb0075 article-title: Atomic layer deposition: an overview publication-title: Chem. Rev. doi: 10.1021/cr900056b contributor: fullname: George – volume: 135 start-page: 167 year: 2004 ident: 10.1016/j.catcom.2017.05.023_bb0105 article-title: Determination of the V2p XPS binding energies for different vanadium oxidation states (V5+ to V0+) publication-title: J. Electron Spectrosc. Relat. Phenom. doi: 10.1016/j.elspec.2004.03.004 contributor: fullname: Silversmit – volume: 160 start-page: 214 year: 1996 ident: 10.1016/j.catcom.2017.05.023_bb0055 article-title: Comparison of silica-supported MoO3 and V2O5 catalysts in the selective partial oxidation of methane publication-title: J. Catal. doi: 10.1006/jcat.1996.0140 contributor: fullname: Faraldos – volume: 45 start-page: 874 year: 1991 ident: 10.1016/j.catcom.2017.05.023_bb0120 article-title: FT-IR emission spectroscopy studies of molybdenum oxide and supported molybdena on alumina, silica, zirconia, and titania publication-title: Appl. Spectrosc. doi: 10.1366/0003702914336651 contributor: fullname: Li – volume: 37 start-page: 645 year: 2004 ident: 10.1016/j.catcom.2017.05.023_bb0040 article-title: Olefin epoxidation with inorganic peroxides. Solutions to four long-standing controversies on the mechanism of oxygen transfer publication-title: Acc. Chem. Res. doi: 10.1021/ar0400140 contributor: fullname: Deubel – volume: 255 start-page: 197 year: 2008 ident: 10.1016/j.catcom.2017.05.023_bb0045 article-title: CH3OH oxidation over well-defined supported V2O5/Al2O3 catalysts: influence of vanadium oxide loading and surface vanadium-oxygen functionalities publication-title: J. Catal. doi: 10.1016/j.jcat.2008.02.007 contributor: fullname: Kim – volume: 423 start-page: 92 year: 2016 ident: 10.1016/j.catcom.2017.05.023_bb0100 article-title: The continuous conversion of ethanol and water mixtures into hydrogen over FexOy/MoO3 catalytic system-XPS and mossbauer studies publication-title: J. Mol. Catal. A Chem. doi: 10.1016/j.molcata.2016.06.002 contributor: fullname: Zimowska – year: 2003 ident: 10.1016/j.catcom.2017.05.023_bb0010 contributor: fullname: Weissermel – volume: 118 start-page: 22611 year: 2014 ident: 10.1016/j.catcom.2017.05.023_bb0095 article-title: Effects of chlorine in titanium oxide on palladium atomic layer deposition publication-title: J. Phys. Chem. C doi: 10.1021/jp5067567 contributor: fullname: Lei – volume: 3 start-page: 1465 year: 2013 ident: 10.1016/j.catcom.2017.05.023_bb0005 article-title: Emerging catalytic processes for the production of Adipic acid publication-title: Catal. Sci. Tech. doi: 10.1039/C3CY20728E contributor: fullname: Van de Vyver – volume: 57 start-page: 1 year: 2015 ident: 10.1016/j.catcom.2017.05.023_bb0060 article-title: Direct oxidation of propylene to propylene oxide with molecular oxygen: a review publication-title: Catal. Rev. Sci. Eng. doi: 10.1080/01614940.2015.1041849 contributor: fullname: Khatib – volume: 4 start-page: 566 year: 2014 ident: 10.1016/j.catcom.2017.05.023_bb0030 article-title: Integrated networks of mesoporous silica nanowires and their bifunctional catalysis-sorption application for oxidative desulfurization publication-title: ACS Catal. doi: 10.1021/cs400996j contributor: fullname: Dou – volume: 204 start-page: 146 year: 2001 ident: 10.1016/j.catcom.2017.05.023_bb0070 article-title: Effect of the reaction conditions on the epoxidation of alkenes with hydrogen peroxide catalyzed by silica-supported titanium derivatives publication-title: J. Catal. doi: 10.1006/jcat.2001.3355 contributor: fullname: Fraile – volume: 529 start-page: 134 year: 2017 ident: 10.1016/j.catcom.2017.05.023_bb0025 article-title: Selectie epoxidation of cyclohexene with molecular oxygen on catalyst of nanoporous au integrated with MoO3 nanoparticles publication-title: Appl. Catal. A doi: 10.1016/j.apcata.2016.10.010 contributor: fullname: Dou – volume: 71 start-page: 410 year: 2016 ident: 10.1016/j.catcom.2017.05.023_bb0085 article-title: Atomic layer deposition-sequential self-limiting surface reactions for advanced catalyst “bottom-up” synthesis publication-title: Surf. Sci. Rep. doi: 10.1016/j.surfrep.2016.03.003 contributor: fullname: Lu – volume: 4 start-page: 1617 year: 2014 ident: 10.1016/j.catcom.2017.05.023_bb0020 article-title: Selective allylic oxidation of cyclohexene catalyzed by nitrogen-doped carbon nanotubes publication-title: ACS Catal. doi: 10.1021/cs500187q contributor: fullname: Cao |
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| SubjectTerms | Allylic oxidation Atomic layer deposition Cyclohexene Epoxidation Mixed metal oxides Zeolite |
| Title | Increased selectivity for allylic oxidation of cyclohexene using TiO2 modified V2O5/MoO3 catalysts |
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