Synthesis of Au-nanoparticle-loaded 1T@2H-MoS2 nanosheets with high photocatalytic performance

• Published in: Journal of materials science Vol. 54; no. 13; pp. 9656 - 9665
• Main Authors: Tian, Lie, Wu, Rong, Liu, HaiYang
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.07.2019; Springer Nature B.V
• Subjects: absorption; Characterization and Evaluation of Materials; Chemistry and Materials Science; Classical Mechanics; Crystallography and Scattering Methods; Electromagnetic absorption; Electron recombination; Electrons; Energy Materials; Gold; hot water treatment; Materials Science; Methylene blue; Molybdenum disulfide; nanogold; Nanoparticles; Nanosheets; Photocatalysis; Photodegradation; Polymer Sciences; Properties (attributes); Solid Mechanics; surface plasmon resonance; Transition metal compounds
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-019-03545-1

Although nanosheets of the transition metal dichalcogenides MoS 2 have been the subject of extensive attention and research due to their unique properties, little research has been conducted on hybrid-phase MoS 2 (1T@2H-MoS 2 ), which has high photocatalytic properties. In this study, we prepared 1T@2H-MoS 2 nanosheets loaded with Au nanoparticles (NPs) which exhibited high photocatalytic properties by a simple hydrothermal method, and the photocatalytic degradation of methylene blue by the 1T@2H-MoS 2 /Au nanosheets under visible light was 91.2%. This high degradation efficiency was due to the introduction of the Au NPs to produce localised surface plasmon resonance, which enhances the visible light absorption of 1T@2H-MoS 2 . The combination of a high content of the 1T phase and the Au NPs accelerates the transfer of photogenerated electrons, which inhibits the recombination of photogenerated electron–hole pairs and allows more electrons to participate in the catalytic reaction. The results showed that loading Au NPs on the 1T@2H-MoS 2 nanosheets promoted the conversion of the 2H phase to the 1T phase, which effectively improved the visible light catalytic performance.