How to Modulate Catalytic Properties in Nanosystems: The Case of Iron-Ruthenium Nanoparticles

Ultrasmall FeRu bimetallic nanoparticles were prepared by co‐decomposition of two organometallic precursors, {Fe[N(Si(CH3)3)2]2}2 and (η4‐1,5‐cyclooctadiene)(η6‐1,3,5‐cyclooctatriene)ruthenium(0) (Ru(COD)(COT)), under dihydrogen at 150 °C in mesitylene. A series of FeRu nanoparticles of sizes of app...

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Published inChemCatChem Vol. 6; no. 6; pp. 1714 - 1720
Main Authors Kelsen, Vinciane, Meffre, Anca, Fazzini, Pier-Francesco, Lecante, Pierre, Chaudret, Bruno
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.06.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Wiley
Subjects
electron microscopy
hydrogenation
iron
Magnetism
Nanoparticles
Physics
ruthenium
Wide angle X-ray scattering
Organometallic precursors
Organometallics
Ruthenium
Catalyst selectivity
Catalytic properties
High-resolution TEM
Ruthenium complexes
Iron
Electron microscopy
Bimetallic nanoparticles
Hydrogenation
Nanoparticle catalysts
Ruthenium compounds
Synthesis (chemical)
Nanoparticles
Iron compounds
Hydrogenation reactions
Styrene
SQUIDs
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Abstract Ultrasmall FeRu bimetallic nanoparticles were prepared by co‐decomposition of two organometallic precursors, {Fe[N(Si(CH3)3)2]2}2 and (η4‐1,5‐cyclooctadiene)(η6‐1,3,5‐cyclooctatriene)ruthenium(0) (Ru(COD)(COT)), under dihydrogen at 150 °C in mesitylene. A series of FeRu nanoparticles of sizes of approximately 1.8 nm and incorporating different ratios of iron to ruthenium were synthesized by varying the quantity of the ruthenium complex introduced (Fe/Ru=1:1, 1:0.5, 1:0.2, and 1:0.1). FeRu nanoparticles were characterized by TEM, high‐resolution TEM, and wide‐angle X‐ray scattering analyses. Their surface was studied by hydride titration and IR spectroscopy after CO adsorption and their magnetic properties were analyzed by using a superconducting quantum interference device (SQUID). The FeRu nanoparticles were used as catalysts in the hydrogenation of styrene and 2‐butanone. The results indicate that the selectivity of the nanoparticle catalysts can be modulated according to their composition and therefore represent a case study on fine‐tuning the reactivity of nanocatalysts and adjusting their selectivity in a given reaction. Singing a bimetallic tune: The selectivity of FeRu nanocatalysts in hydrogenation reactions can be tuned by adjusting the Ru content in bimetallic FeRu ultrasmall nanoparticles.
AbstractList Abstract Ultrasmall FeRu bimetallic nanoparticles were prepared by co‐decomposition of two organometallic precursors, {Fe[N(Si(CH 3 ) 3 ) 2 ] 2 } 2 and (η 4 ‐1,5‐cyclooctadiene)(η 6 ‐1,3,5‐cyclooctatriene)ruthenium(0) (Ru(COD)(COT)), under dihydrogen at 150 °C in mesitylene. A series of FeRu nanoparticles of sizes of approximately 1.8 nm and incorporating different ratios of iron to ruthenium were synthesized by varying the quantity of the ruthenium complex introduced (Fe/Ru=1:1, 1:0.5, 1:0.2, and 1:0.1). FeRu nanoparticles were characterized by TEM, high‐resolution TEM, and wide‐angle X‐ray scattering analyses. Their surface was studied by hydride titration and IR spectroscopy after CO adsorption and their magnetic properties were analyzed by using a superconducting quantum interference device (SQUID). The FeRu nanoparticles were used as catalysts in the hydrogenation of styrene and 2‐butanone. The results indicate that the selectivity of the nanoparticle catalysts can be modulated according to their composition and therefore represent a case study on fine‐tuning the reactivity of nanocatalysts and adjusting their selectivity in a given reaction.
Ultrasmall FeRu bimetallic nanoparticles were prepared by co-decomposition of two organometallic precursors, {Fe[N(Si(CH3)3)2]2}2 and (η4-1,5-cyclooctadiene)(η6-1,3,5-cyclooctatriene)ruthenium(0) (Ru(COD)(COT)), under dihydrogen at 150°C in mesitylene. A series of FeRu nanoparticles of sizes of approximately 1.8nm and incorporating different ratios of iron to ruthenium were synthesized by varying the quantity of the ruthenium complex introduced (Fe/Ru=1:1, 1:0.5, 1:0.2, and 1:0.1). FeRu nanoparticles were characterized by TEM, high-resolution TEM, and wide-angle X-ray scattering analyses. Their surface was studied by hydride titration and IR spectroscopy after CO adsorption and their magnetic properties were analyzed by using a superconducting quantum interference device (SQUID). The FeRu nanoparticles were used as catalysts in the hydrogenation of styrene and 2-butanone. The results indicate that the selectivity of the nanoparticle catalysts can be modulated according to their composition and therefore represent a case study on fine-tuning the reactivity of nanocatalysts and adjusting their selectivity in a given reaction. [PUBLICATION ABSTRACT]
Ultrasmall FeRu bimetallic nanoparticles were prepared by co‐decomposition of two organometallic precursors, {Fe[N(Si(CH3)3)2]2}2 and (η4‐1,5‐cyclooctadiene)(η6‐1,3,5‐cyclooctatriene)ruthenium(0) (Ru(COD)(COT)), under dihydrogen at 150 °C in mesitylene. A series of FeRu nanoparticles of sizes of approximately 1.8 nm and incorporating different ratios of iron to ruthenium were synthesized by varying the quantity of the ruthenium complex introduced (Fe/Ru=1:1, 1:0.5, 1:0.2, and 1:0.1). FeRu nanoparticles were characterized by TEM, high‐resolution TEM, and wide‐angle X‐ray scattering analyses. Their surface was studied by hydride titration and IR spectroscopy after CO adsorption and their magnetic properties were analyzed by using a superconducting quantum interference device (SQUID). The FeRu nanoparticles were used as catalysts in the hydrogenation of styrene and 2‐butanone. The results indicate that the selectivity of the nanoparticle catalysts can be modulated according to their composition and therefore represent a case study on fine‐tuning the reactivity of nanocatalysts and adjusting their selectivity in a given reaction. Singing a bimetallic tune: The selectivity of FeRu nanocatalysts in hydrogenation reactions can be tuned by adjusting the Ru content in bimetallic FeRu ultrasmall nanoparticles.
Ultrasmall FeRu bimetallic nanoparticles were prepared by co-decomposition of two organometallic precursors, Fe[N(Si(CH3)3) 2]22 and (η4-1,5- cyclooctadiene)(η6-1,3,5-cyclooctatriene)ruthenium(0) (Ru(COD)(COT)), under dihydrogen at 150 °C in mesitylene. A series of FeRu nanoparticles of sizes of approximately 1.8 nm and incorporating different ratios of iron to ruthenium were synthesized by varying the quantity of the ruthenium complex introduced (Fe/Ru=1:1, 1:0.5, 1:0.2, and 1:0.1). FeRu nanoparticles were characterized by TEM, high-resolution TEM, and wide-angle X-ray scattering analyses. Their surface was studied by hydride titration and IR spectroscopy after CO adsorption and their magnetic properties were analyzed by using a superconducting quantum interference device (SQUID). The FeRu nanoparticles were used as catalysts in the hydrogenation of styrene and 2-butanone. The results indicate that the selectivity of the nanoparticle catalysts can be modulated according to their composition and therefore represent a case study on fine-tuning the reactivity of nanocatalysts and adjusting their selectivity in a given reaction. Singing a bimetallic tune: The selectivity of FeRu nanocatalysts in hydrogenation reactions can be tuned by adjusting the Ru content in bimetallic FeRu ultrasmall nanoparticles.
Author Chaudret, Bruno
Meffre, Anca
Kelsen, Vinciane
Fazzini, Pier-Francesco
Lecante, Pierre
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  fullname: Chaudret, Bruno
  email: chaudret@insa-toulouse.fr
  organization: LPCNO-INSA, Université de Toulouse, 135 avenue de Rangueil 31077 Toulouse Cedex 4 (France), Fax: (+33) 05-62-17-28-16
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Issue 6
Keywords Wide angle X-ray scattering
Organometallic precursors
Organometallics
Ruthenium
Catalyst selectivity
Catalytic properties
High-resolution TEM
Ruthenium complexes
Iron
Electron microscopy
Bimetallic nanoparticles
Hydrogenation
Nanoparticle catalysts
Ruthenium compounds
Synthesis (chemical)
Nanoparticles
Iron compounds
Hydrogenation reactions
Styrene
SQUIDs
Language English
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Snippet Ultrasmall FeRu bimetallic nanoparticles were prepared by co‐decomposition of two organometallic precursors, {Fe[N(Si(CH3)3)2]2}2 and...
Abstract Ultrasmall FeRu bimetallic nanoparticles were prepared by co‐decomposition of two organometallic precursors, {Fe[N(Si(CH 3 ) 3 ) 2 ] 2 } 2 and (η 4...
Ultrasmall FeRu bimetallic nanoparticles were prepared by co-decomposition of two organometallic precursors, {Fe[N(Si(CH3)3)2]2}2 and...
Ultrasmall FeRu bimetallic nanoparticles were prepared by co-decomposition of two organometallic precursors, Fe[N(Si(CH3)3) 2]22 and (η4-1,5-...
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SubjectTerms electron microscopy
hydrogenation
iron
Magnetism
Nanoparticles
Physics
ruthenium
Title How to Modulate Catalytic Properties in Nanosystems: The Case of Iron-Ruthenium Nanoparticles
URI https://api.istex.fr/ark:/67375/WNG-NBLZ80J8-S/fulltext.pdf
https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fcctc.201300907
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https://hal.science/hal-01766219
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