Updated Excitation and Ionization Cross Sections for Electron Impact on Atomic Oxygen

Cross sections for the excitation and ionization of atomic oxygen by electron impact are presented as the result of a critical review of experimental and theoretical work on this subject. An effort has been made to compile the most accurate and complete set of cross sections available. More than 60...

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Published inJournal of physical and chemical reference data Vol. 19; no. 1; pp. 277 - 305
Main Authors Laher, Russ R., Gilmore, Forrest R.
Format Journal Article
LanguageEnglish
Published United States 01.01.1990
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ISSN0047-2689
1529-7845
DOI10.1063/1.555872

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Abstract Cross sections for the excitation and ionization of atomic oxygen by electron impact are presented as the result of a critical review of experimental and theoretical work on this subject. An effort has been made to compile the most accurate and complete set of cross sections available. More than 60 profiles of excitation cross section versus electron‐impact energy are presented. These include transitions to the forbidden metastable O(2p 4 1 D) and O(2p 4 1 S) states, the allowed autoionizing O(2p 5 3 P  o ) state, nine allowed Rydberg series, and twenty‐nine forbidden Rydberg series. Recommended ionization cross sections for transitions to the outer‐electron ionization states O+(4 S  o ), O+(2 D o ), O+(2 P o ), to the inner‐electron ionization state O+(4 P), and to the O2 + state are also given. Many of these excitation and ionization cross sections are based on recently published laboratory measurements, and differ from previously accepted values by factors of ∼2–3, and in a few cases by up to a factor of 10. The data presented in this report will be useful in calculations of aeronomical and artificially‐induced electron impact on atomic oxygen, an important component of the upper atmosphere.
AbstractList Cross sections for the excitation and ionization of atomic oxygen by electron impact are presented as the result of a critical review of experimental and theoretical work on this subject. An effort has been made to compile the most accurate and complete set of cross sections available. More than 60 profiles of excitation cross section versus electron-impact energy are presented. These include transitions to the forbidden metastable O(2{ital p}{sup 4} {ital D}) and O(2{ital p}{sup 4} {sup 1}{ital S}) states, the allowed autoionizing O(2{ital p}{sup 5 }{sup 3}{ital P} {sup {ital o}}) state, nine allowed Rydberg series, and twenty-nine forbidden Rydberg series. Recommended ionization cross sections for transitions to the outer-electron ionization states O{sup +}({sup 4}{ital S} {sup {ital o}}), O{sup +}({sup 2}{ital D}{sup {ital o}}), O{sup +}({sup 2}{ital P}{sup {ital o}}), to the inner-electron ionization state O{sup +}({sup 4}{ital P}), and to the O{sup 2+} state are also given. Many of these excitation and ionization cross sections are based on recently published laboratory measurements, and differ from previously accepted values by factors of {similar to}2--3, and in a few cases by up to a factor of 10. The data presented in this report will be useful in calculations of aeronomical and artificially-induced electron impact on atomic oxygen, an important component of the upper atmosphere.
Cross sections for the excitation and ionization of atomic oxygen by electron impact are presented as the result of a critical review of experimental and theoretical work on this subject. An effort has been made to compile the most accurate and complete set of cross sections available. More than 60 profiles of excitation cross section versus electron-impact energy are presented. These include transitions to the forbidden metastable O(2p4 1D) and O(2p4 1S) states, the allowed autoionizing O(2p5 3P o) state, nine allowed Rydberg series, and twenty-nine forbidden Rydberg series. Recommended ionization cross sections for transitions to the outer-electron ionization states O+(4S o), O+(2Do), O+(2Po), to the inner-electron ionization state O+(4P), and to the O2+ state are also given. Many of these excitation and ionization cross sections are based on recently published laboratory measurements, and differ from previously accepted values by factors of ∼2–3, and in a few cases by up to a factor of 10. The data presented in this report will be useful in calculations of aeronomical and artificially-induced electron impact on atomic oxygen, an important component of the upper atmosphere.
Cross sections for the excitation and ionization of atomic oxygen by electron impact are presented as the result of a critical review of experimental and theoretical work on this subject. An effort has been made to compile the most accurate and complete set of cross sections available. More than 60 profiles of excitation cross section versus electron‐impact energy are presented. These include transitions to the forbidden metastable O(2p 4 1 D) and O(2p 4 1 S) states, the allowed autoionizing O(2p 5 3 P  o ) state, nine allowed Rydberg series, and twenty‐nine forbidden Rydberg series. Recommended ionization cross sections for transitions to the outer‐electron ionization states O+(4 S  o ), O+(2 D o ), O+(2 P o ), to the inner‐electron ionization state O+(4 P), and to the O2 + state are also given. Many of these excitation and ionization cross sections are based on recently published laboratory measurements, and differ from previously accepted values by factors of ∼2–3, and in a few cases by up to a factor of 10. The data presented in this report will be useful in calculations of aeronomical and artificially‐induced electron impact on atomic oxygen, an important component of the upper atmosphere.
Author Gilmore, Forrest R.
Laher, Russ R.
Author_xml – sequence: 1
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  surname: Laher
  fullname: Laher, Russ R.
  organization: R&D Associates, Marina del Rey, California 90295
– sequence: 2
  givenname: Forrest R.
  surname: Gilmore
  fullname: Gilmore, Forrest R.
  organization: R&D Associates, Marina del Rey, California 90295
BackLink https://www.osti.gov/biblio/7103372$$D View this record in Osti.gov
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Issue 1
Keywords REVIEWS
EXCITATION
ELECTRON−ATOM COLLISIONS
COMPILED DATA
ELECTRONIC STRUCTURE
ENERGY−LEVEL TRANSITIONS
FORBIDDEN TRANSITIONS
TABLES
OXYGEN
CROSS SECTIONS
INNER−SHELL EXCITATION
IONIZATION
RYDBERG STATES
EXPERIMENTAL DATA
Language English
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1990-01-01
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PublicationTitle Journal of physical and chemical reference data
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Snippet Cross sections for the excitation and ionization of atomic oxygen by electron impact are presented as the result of a critical review of experimental and...
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scitation
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Publisher
StartPage 277
SubjectTerms 640304 - Atomic, Molecular & Chemical Physics- Collision Phenomena
ATOM COLLISIONS
ATOMIC AND MOLECULAR PHYSICS
COLLISIONS
COMPILED DATA
CROSS SECTIONS
DATA
DOCUMENT TYPES
ELECTRON COLLISIONS
ELECTRON-ATOM COLLISIONS
ELECTRONIC STRUCTURE
ELEMENTS
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITATION
EXCITED STATES
EXPERIMENTAL DATA
FORBIDDEN TRANSITIONS
INFORMATION
INNER-SHELL EXCITATION
IONIZATION
NONMETALS
NUMERICAL DATA
OXYGEN
REVIEWS
RYDBERG STATES
TABLES
Title Updated Excitation and Ionization Cross Sections for Electron Impact on Atomic Oxygen
URI http://dx.doi.org/10.1063/1.555872
https://www.osti.gov/biblio/7103372
Volume 19
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