Application of biochar-based catalysts in biomass upgrading: a review

Biochar is a low-cost carbon-rich material derived from the thermochemical degradation of biomass. Due to its unique chemical structure, biochar with a large surface area and tailored surface functional groups can be easily prepared by activation and/or functionalization, and shows great potential t...

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Published inRSC advances Vol. 7; no. 77; pp. 48793 - 4885
Main Authors Cao, Xuefei, Sun, Shaoni, Sun, Runcang
Format Journal Article
LanguageEnglish
Published 01.01.2017
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Abstract Biochar is a low-cost carbon-rich material derived from the thermochemical degradation of biomass. Due to its unique chemical structure, biochar with a large surface area and tailored surface functional groups can be easily prepared by activation and/or functionalization, and shows great potential to be used as a versatile catalyst and/or catalyst support in many chemical processes. However, the application of biochars as versatile catalysts and/or catalyst supports for biomass upgrading has not been systematically overviewed so far. In this work, the formation of pyrochar and hydrochar is proposed, and the activation and/or functionalization of biochar are also included. Subsequently, the application of biochar-based catalysts in biomass upgrading, including biochar-based solid acids for biomass hydrolysis and dehydration, biochar-based catalysts for biodiesel production, and biochars as catalyst supports for biomass pyrolysis, gasification, and bio-oil upgrading, are discussed in detail. The application of biochars as versatile catalysts and/or catalyst supports for biomass upgrading is systematically overviewed.
AbstractList Biochar is a low-cost carbon-rich material derived from the thermochemical degradation of biomass. Due to its unique chemical structure, biochar with a large surface area and tailored surface functional groups can be easily prepared by activation and/or functionalization, and shows great potential to be used as a versatile catalyst and/or catalyst support in many chemical processes. However, the application of biochars as versatile catalysts and/or catalyst supports for biomass upgrading has not been systematically overviewed so far. In this work, the formation of pyrochar and hydrochar is proposed, and the activation and/or functionalization of biochar are also included. Subsequently, the application of biochar-based catalysts in biomass upgrading, including biochar-based solid acids for biomass hydrolysis and dehydration, biochar-based catalysts for biodiesel production, and biochars as catalyst supports for biomass pyrolysis, gasification, and bio-oil upgrading, are discussed in detail.
Biochar is a low-cost carbon-rich material derived from the thermochemical degradation of biomass. Due to its unique chemical structure, biochar with a large surface area and tailored surface functional groups can be easily prepared by activation and/or functionalization, and shows great potential to be used as a versatile catalyst and/or catalyst support in many chemical processes. However, the application of biochars as versatile catalysts and/or catalyst supports for biomass upgrading has not been systematically overviewed so far. In this work, the formation of pyrochar and hydrochar is proposed, and the activation and/or functionalization of biochar are also included. Subsequently, the application of biochar-based catalysts in biomass upgrading, including biochar-based solid acids for biomass hydrolysis and dehydration, biochar-based catalysts for biodiesel production, and biochars as catalyst supports for biomass pyrolysis, gasification, and bio-oil upgrading, are discussed in detail. The application of biochars as versatile catalysts and/or catalyst supports for biomass upgrading is systematically overviewed.
Author Sun, Shaoni
Sun, Runcang
Cao, Xuefei
AuthorAffiliation South China University of Technology
Beijing Key Laboratory of Lignocellulosic Chemistry
Beijing Forestry University
State Key Laboratory of Pulp and Paper Engineering
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  givenname: Shaoni
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  fullname: Sun, Shaoni
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  givenname: Runcang
  surname: Sun
  fullname: Sun, Runcang
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Snippet Biochar is a low-cost carbon-rich material derived from the thermochemical degradation of biomass. Due to its unique chemical structure, biochar with a large...
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SubjectTerms acids
biochar
biodiesel
biomass
catalysts
fuel production
gasification
hydrochars
hydrolysis
moieties
pyrolysis
surface area
Title Application of biochar-based catalysts in biomass upgrading: a review
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