Removal of Sulfur from CaF2 Containing Desulfurization Slag Exhausted from Secondary Steelmaking Process by Oxidation

The oxidation behavior of sulfur in desulfurization slag generated from the secondary steelmaking process with air has been investigated in the temperature range of 973 K to 1373 K (700 °C to 1100 °C). Although a high removal rate of sulfur is not achieved at temperatures lower than 1273 K (1000 °C)...

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Published in	Metallurgical and materials transactions. B, Process metallurgy and materials processing science Vol. 43; no. 4; pp. 703 - 709
Main Authors	Hiraki, Takehito, Kobayashi, Junichi, Urushibata, Satomi, Matsubae, Kazuyo, Nagasaka, Tetsuya
Format	Journal Article
Language	English
Published	Boston Springer US 01.08.2012 Springer
Subjects	Applied sciences Calcium fluoride Characterization and Evaluation of Materials Chemistry and Materials Science Desulfurizing Exact sciences and technology Iron and steel making Materials Science Metallic Materials Metals. Metallurgy Nanotechnology Oxidation Process metallurgy Production of metals Slags Structural Materials Sulfur Surfaces and Interfaces Thin Films Transaction processing Desulfurization Sulfur Removal Fluorine Content Sulfide Capacity Sulfur Removability Exhaust Removal Steelmaking Slag Oxidation Calcium fluoride
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Abstract	The oxidation behavior of sulfur in desulfurization slag generated from the secondary steelmaking process with air has been investigated in the temperature range of 973 K to 1373 K (700 °C to 1100 °C). Although a high removal rate of sulfur is not achieved at temperatures lower than 1273 K (1000 °C) because of the formation of CaSO 4 , most of the sulfur is rapidly removed from slag as SO 2 gas in the 1273 K to 1373 K (700 °C to 1100 °C) range. This finding indicates that the desulfurization slag generated from the secondary steelmaking process can be reused as a desulfurized flux through air oxidation, making it possible to reduce significantly the amount of desulfurization slag for disposal.
AbstractList	The oxidation behavior of sulfur in desulfurization slag generated from the secondary steelmaking process with air has been investigated in the temperature range of 973 K to 1373 K (700 °C to 1100 °C). Although a high removal rate of sulfur is not achieved at temperatures lower than 1273 K (1000 °C) because of the formation of CaSO 4 , most of the sulfur is rapidly removed from slag as SO 2 gas in the 1273 K to 1373 K (700 °C to 1100 °C) range. This finding indicates that the desulfurization slag generated from the secondary steelmaking process can be reused as a desulfurized flux through air oxidation, making it possible to reduce significantly the amount of desulfurization slag for disposal. The oxidation behavior of sulfur in desulfurization slag generated from the secondary steelmaking process with air has been investigated in the temperature range of 973 K to 1373 K (700 ?C to 1100 ?C). Although a high removal rate of sulfur is not achieved at temperatures lower than 1273 K (1000 ?C) because of the formation of CaSO4, most of the sulfur is rapidly removed from slag as SO2 gas in the 1273 K to 1373 K (700 ?C to 1100 ?C) range. This finding indicates that the desulfurization slag generated from the secondary steelmaking process can be reused as a desulfurized flux through air oxidation, making it possible to reduce significantly the amount of desulfurization slag for disposal.
Author	Kobayashi, Junichi Urushibata, Satomi Matsubae, Kazuyo Hiraki, Takehito Nagasaka, Tetsuya
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Keywords	Desulfurization Sulfur Removal Fluorine Content Sulfide Capacity Sulfur Removability Exhaust Removal Steelmaking Slag Oxidation Calcium fluoride
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Snippet	The oxidation behavior of sulfur in desulfurization slag generated from the secondary steelmaking process with air has been investigated in the temperature...
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SubjectTerms	Applied sciences Calcium fluoride Characterization and Evaluation of Materials Chemistry and Materials Science Desulfurizing Exact sciences and technology Iron and steel making Materials Science Metallic Materials Metals. Metallurgy Nanotechnology Oxidation Process metallurgy Production of metals Slags Structural Materials Sulfur Surfaces and Interfaces Thin Films Transaction processing
Title	Removal of Sulfur from CaF2 Containing Desulfurization Slag Exhausted from Secondary Steelmaking Process by Oxidation
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