Complexes of molybdenum(VI) oxide tetrafluoride and molybdenum(VI) dioxide difluoride with neutral N- and O-donor ligands

• Published in: Journal of fluorine chemistry Vol. 200; pp. 190 - 197
• Main Authors: Levason, William, Monzittu, Francesco M., Reid, Gillian, Zhang, Wenjian, Hope, Eric G.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 01.08.2017; Elsevier BV
• Subjects: Chemical compounds; Crystal structure; Fluorides; Ligands; Magnetic resonance spectroscopy; Molybdenum; Nitrogen donor ligand; NMR spectroscopy; Oxide-fluoride; Oxygen donor ligand; Spectrum analysis; X-ray structures; Nitrogen donor ligand; Oxide-fluoride; Molybdenum; X-ray structures; Oxygen donor ligand

[Display omitted] •First examples of MoOF4 complexes with neutral ligands.•X-ray structure of [MoOF4(Ph3PO)].•Comparisons of [MoOF4(L)] and [MoO2F2(L)2] complexes.•Comparisons of Mo(VI) and W(VI) oxide fluoride complexes. [MoOF4(MeCN)], prepared from reaction of MoF6 with (Me3Si)2O in anhydrous MeCN...