Metallocene-Catalyzed Polymerization in Nonaqueous Fluorous Emulsion
A nonaqueous organic‐in‐fluorous emulsion applicable for polymerization using water‐sensitive catalysts is presented. With statistical biphasic copolymers based on poly(4‐hydroxystyrene) containing fluorinated and nonfluorinated alkyl side chains, emulsions of hydrocarbons dispersed in perfluorocarb...
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| Published in | Macromolecular chemistry and physics Vol. 208; no. 13; pp. 1362 - 1369 |
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| Main Authors | , , , |
| Format | Journal Article Conference Proceeding |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
03.07.2007
WILEY‐VCH Verlag Wiley |
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| Abstract | A nonaqueous organic‐in‐fluorous emulsion applicable for polymerization using water‐sensitive catalysts is presented. With statistical biphasic copolymers based on poly(4‐hydroxystyrene) containing fluorinated and nonfluorinated alkyl side chains, emulsions of hydrocarbons dispersed in perfluorocarbons were stabilized. The addition of metallocenes, activated by methylalumoxane (MAO), enabled the polymerization of olefins inside this highly hydrophobic system. High molecular weight polyolefin nanoparticles ($\overline M _{\rm n}$ up to 450 000) of polyethylene and poly(propylene) were synthesized without supporting the catalyst and without reactor fouling. In this diffusion‐controlled process, the sizes of the particles were controlled by the reaction time and the ratio of the emulsifier to solvents. |
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| AbstractList | A nonaqueous organic‐in‐fluorous emulsion applicable for polymerization using water‐sensitive catalysts is presented. With statistical biphasic copolymers based on poly(4‐hydroxystyrene) containing fluorinated and nonfluorinated alkyl side chains, emulsions of hydrocarbons dispersed in perfluorocarbons were stabilized. The addition of metallocenes, activated by methylalumoxane (MAO), enabled the polymerization of olefins inside this highly hydrophobic system. High molecular weight polyolefin nanoparticles ($\overline M _{\rm n}$ up to 450 000) of polyethylene and poly(propylene) were synthesized without supporting the catalyst and without reactor fouling. In this diffusion‐controlled process, the sizes of the particles were controlled by the reaction time and the ratio of the emulsifier to solvents. A nonaqueous organic-in-fluorous emulsion applicable for polymerization using water-sensitive catalysts is presented. With statistical biphasic copolymers based on poly(4-hydroxystyrene) containing fluorinated and nonfluorinated alkyl side chains, emulsions of hydrocarbons dispersed in perfluorocarbons were stabilized. The addition of metallocenes, activated by methylalumoxane (MAO), enabled the polymerization of olefins inside this highly hydrophobic system. High molecular weight polyolefin nanoparticles ( up to 450000) of polyethylene and poly(propylene) were synthesized without supporting the catalyst and without reactor fouling. In this diffusion-controlled process, the sizes of the particles were controlled by the reaction time and the ratio of the emulsifier to solvents. . Abstract A nonaqueous organic‐in‐fluorous emulsion applicable for polymerization using water‐sensitive catalysts is presented. With statistical biphasic copolymers based on poly(4‐hydroxystyrene) containing fluorinated and nonfluorinated alkyl side chains, emulsions of hydrocarbons dispersed in perfluorocarbons were stabilized. The addition of metallocenes, activated by methylalumoxane (MAO), enabled the polymerization of olefins inside this highly hydrophobic system. High molecular weight polyolefin nanoparticles ( $\overline M _{\rm n}$ up to 450 000) of polyethylene and poly(propylene) were synthesized without supporting the catalyst and without reactor fouling. In this diffusion‐controlled process, the sizes of the particles were controlled by the reaction time and the ratio of the emulsifier to solvents. magnified image |
| Author | Nenov, Svetlin Klapper, Markus Müllen, Klaus Clark Jr, Christopher G. |
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| Cites_doi | 10.1021/ar00110a004 10.1002/marc.200300048 10.1016/S0040-4039(98)02537-4 10.1002/pola.21508 10.1002/masy.200450914 10.1081/CR-100101172 10.1016/S1359-0294(97)80026-X 10.1002/masy.200690044 10.1007/s00396-006-1468-9 10.1016/j.porgcoat.2005.06.017 10.1002/pola.21418 10.1016/S0079-6700(03)00015-7 10.1016/0033-0655(83)85007-9 10.1002/1521-3773(20020215)41:4<544::AID-ANIE544>3.0.CO;2-U 10.1002/macp.200290085 10.1002/marc.200600027 10.1088/0034-4885/62/6/203 10.1002/pola.10804 10.1016/S1359-0294(03)00045-1 10.1021/cr9804700 10.1002/pol.1970.110080210 10.1016/S1359-0286(98)80071-5 10.1002/anie.199511431 10.1002/1521-3900(200101)163:1<1::AID-MASY1>3.0.CO;2-2 10.1016/j.porgcoat.2004.03.002 10.1016/S0300-9440(96)00686-8 10.1021/om00015a033 10.1021/cr040670d 10.1021/ma991782n |
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| Keywords | Fluorine containing copolymer perfluorinated Nanoparticle Emulsifying power Surfactant polymer Complex catalyst polymerization Styrene derivative copolymer nonaqueous Etherification Metallocene metallocene catalysts Emulsion polymerization Olefin polymer Chloro complex Polyethylene Non ionic surfactant Propylene polymer Zirconium complex Experimental study Styrene(hydroxy) polymer Random copolymer Chemical modification polyolefins Preparation Nonaqueous media Catalyst activity |
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| References | R. Mülhaupt, Macromol. Chem. Phy. 2003, 204, 289. H. H. Brintzinger, D. Fischer, R. Muelhaupt, B. Rieger, R. M. Waymouth, Angew. Chem., Int. Ed. Engl. 1995, 34, 1143. M. Klapper, K. Müllen, Macromol. Symp. 2001, 163, 1. T. Schuman, A. Karlsson, J. Larsson, M. Wikstroem, M. Rigdahl, Prog. Org. Coat. 2005, 54, 360. J. Bibette, F. L. Calderon, P. Poulin, Rep. Prog. Phys. 1999, 62, 969. R. F. G. Brown, C. Carr, M. E. Taylor, Prog. Org. Coat. 1997, 30, 185. M. P. Krafft, J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 4251. G. Riess, C. Labbe, Macromol. Rapid Commun. 2004, 25, 401. V. Khrenov, F. Schwager, M. Klapper, M. Koch, K. Müllen, Colloid Polym. Sci. 2006, 284, 927. U. Stehling, J. Diebold, R. Kirsten, W. Roell, H. H. Brintzinger, S. Juengling, R. Muelhaupt, F. Langhauser, Organometallics 1994, 13, 964. M. A. Winnik, Curr. Opin. Colloid Interface Sci. 1997, 2, 192. M. P. Krafft, A. Chittofrati, J. G. Riess, Curr. Opin. Colloid Interface Sci. 2003, 8, 251. D. Y. Perera, Prog. Org. Coat. 2004, 50, 247. G. Riess, Prog. Polym. Sci. 2003, 28, 1107. J. C. Padget, J. Coat. Technol. 1994, 66, 89. P. L. Watson, G. W. Parshall, Acc. Chem. Res. 1985, 18, 51. T. J. Pullukat, R. E. Hoff, Catal. Rev. - Sci. Eng. 1999, 41, 389. J. Periard, A. Banderet, G. Riess, J. Polym. Sci., Polym. Lett. Ed. 1970, 8, 109. D. Sinou, G. Pozzi, E. G. Hope, A. M. Stuart, Tetrahedron Lett. 1999, 40, 849. S. Mecking, A. Held, F. M. Bauers, Angew. Chem., Int. Ed. 2002, 41, 544. K. Landfester, M. Willert, M. Antonietti, Macromolecules 2000, 33, 2370. K. Müller, M. Klapper, K. Müllen, Macromol. Rapid Commun. 2006, 27, 586. J. W. Taylor, M. A. Winnik, JCT Res. 2004, 1, 163. M. Klapper, Y.-J. Jang, K. Bieber, T. Nemnich, N. Nenov, K. Müllen, Macromol. Symp. 2004, 213, 131. S. Mecking, V. Monteil, J. Huber, L. Kolb, P. Wehrmann, Macromol. Symp. 2006, 236, 117. C. Jenny, P. Maddox, Curr. Opin. Solid State Mater. Sci. 1998, 3, 94. G. P. Bierwagen, D. C. Rich, Prog. Org. Coat. 1983, 11, 339. P. Galli, G. Vecellio, J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 396. J. R. Severn, J. C. Chadwick, R. Duchateau, N. Friederichs, Chem. Rev. 2005, 105, 4073. C. Naundorf, S. Matsui, J. Saito, T. Fujita, M. Klapper, K. Müllen, J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 3103. H. G. Alt, A. Koeppl, Chem. Rev. (Washington, DC) 2000, 100, 1205. 1970; 8 2004; 42 2001; 163 2004; 25 1995; 34 1994; 66 1999; 41 1997; 2 1999; 40 1999; 62 2004; 1 2006; 236 1983; 11 1985; 18 2004; 50 2004; 213 2003; 204 2001 2002; 41 2006; 44 1997; 30 2006; 27 2000; 33 2005; 105 2003; 8 2006; 284 1994; 13 2005; 54 1998; 3 2003; 28 2000; 100 e_1_2_6_30_2 e_1_2_6_18_2 e_1_2_6_19_2 Taylor J. W. (e_1_2_6_31_2) 2004; 1 Padget J. C. (e_1_2_6_32_2) 1994; 66 e_1_2_6_12_2 e_1_2_6_13_2 e_1_2_6_10_2 e_1_2_6_11_2 e_1_2_6_16_2 e_1_2_6_17_2 e_1_2_6_14_2 e_1_2_6_15_2 e_1_2_6_20_2 e_1_2_6_8_2 e_1_2_6_7_2 e_1_2_6_9_2 e_1_2_6_29_2 e_1_2_6_4_2 e_1_2_6_3_2 e_1_2_6_6_2 e_1_2_6_5_2 e_1_2_6_24_2 e_1_2_6_23_2 e_1_2_6_2_2 e_1_2_6_22_2 e_1_2_6_1_2 e_1_2_6_21_2 e_1_2_6_28_2 e_1_2_6_27_2 e_1_2_6_26_2 e_1_2_6_25_2 |
| References_xml | – volume: 18 start-page: 51 year: 1985 publication-title: Acc. Chem. Res. – volume: 3 start-page: 94 year: 1998 publication-title: Curr. Opin. Solid State Mater. Sci. – volume: 41 start-page: 544 year: 2002 publication-title: Angew. Chem., Int. Ed. – volume: 284 start-page: 927 year: 2006 publication-title: Colloid Polym. Sci. – volume: 34 start-page: 1143 year: 1995 publication-title: Angew. Chem., Int. Ed. Engl. – year: 2001 – volume: 11 start-page: 339 year: 1983 publication-title: Prog. Org. Coat. – volume: 105 start-page: 4073 year: 2005 publication-title: Chem. Rev. – volume: 8 start-page: 109 year: 1970 publication-title: J. Polym. Sci., Polym. Lett. Ed. – volume: 204 start-page: 289 year: 2003 publication-title: Macromol. Chem. Phy. – volume: 44 start-page: 3103 year: 2006 publication-title: J. Polym. Sci., Part A: Polym. Chem. – volume: 28 start-page: 1107 year: 2003 publication-title: Prog. Polym. Sci. – volume: 25 start-page: 401 year: 2004 publication-title: Macromol. Rapid Commun. – volume: 33 start-page: 2370 year: 2000 publication-title: Macromolecules – volume: 41 start-page: 389 year: 1999 publication-title: Catal. Rev. – Sci. Eng. – volume: 42 start-page: 396 year: 2004 publication-title: J. Polym. Sci., Part A: Polym. Chem. – volume: 44 start-page: 4251 year: 2006 publication-title: J. Polym. Sci., Part A: Polym. Chem. – volume: 66 start-page: 89 year: 1994 publication-title: J. Coat. Technol. – volume: 27 start-page: 586 year: 2006 publication-title: Macromol. Rapid Commun. – volume: 100 start-page: 1205 year: 2000 publication-title: Chem. Rev. (Washington, DC) – volume: 40 start-page: 849 year: 1999 publication-title: Tetrahedron Lett. – volume: 30 start-page: 185 year: 1997 publication-title: Prog. Org. Coat. – volume: 213 start-page: 131 year: 2004 publication-title: Macromol. Symp. – volume: 54 start-page: 360 year: 2005 publication-title: Prog. Org. Coat. – volume: 2 start-page: 192 year: 1997 publication-title: Curr. Opin. Colloid Interface Sci. – volume: 50 start-page: 247 year: 2004 publication-title: Prog. Org. Coat. – volume: 1 start-page: 163 year: 2004 publication-title: JCT Res. – volume: 13 start-page: 964 year: 1994 publication-title: Organometallics – volume: 62 start-page: 969 year: 1999 publication-title: Rep. Prog. Phys. – volume: 163 start-page: 1 year: 2001 publication-title: Macromol. Symp. – volume: 236 start-page: 117 year: 2006 publication-title: Macromol. Symp. – volume: 8 start-page: 251 year: 2003 publication-title: Curr. Opin. Colloid Interface Sci. – ident: e_1_2_6_1_2 doi: 10.1021/ar00110a004 – ident: e_1_2_6_15_2 doi: 10.1002/marc.200300048 – ident: e_1_2_6_19_2 doi: 10.1016/S0040-4039(98)02537-4 – ident: e_1_2_6_10_2 – ident: e_1_2_6_21_2 doi: 10.1002/pola.21508 – ident: e_1_2_6_7_2 doi: 10.1002/masy.200450914 – ident: e_1_2_6_2_2 doi: 10.1081/CR-100101172 – ident: e_1_2_6_30_2 doi: 10.1016/S1359-0294(97)80026-X – ident: e_1_2_6_12_2 doi: 10.1002/masy.200690044 – ident: e_1_2_6_18_2 doi: 10.1007/s00396-006-1468-9 – ident: e_1_2_6_26_2 doi: 10.1016/j.porgcoat.2005.06.017 – ident: e_1_2_6_25_2 doi: 10.1002/pola.21418 – ident: e_1_2_6_16_2 doi: 10.1016/S0079-6700(03)00015-7 – ident: e_1_2_6_29_2 doi: 10.1016/0033-0655(83)85007-9 – ident: e_1_2_6_11_2 doi: 10.1002/1521-3773(20020215)41:4<544::AID-ANIE544>3.0.CO;2-U – volume: 66 start-page: 89 year: 1994 ident: e_1_2_6_32_2 publication-title: J. Coat. Technol. contributor: fullname: Padget J. C. – ident: e_1_2_6_6_2 doi: 10.1002/macp.200290085 – volume: 1 start-page: 163 year: 2004 ident: e_1_2_6_31_2 publication-title: JCT Res. contributor: fullname: Taylor J. W. – ident: e_1_2_6_13_2 doi: 10.1002/marc.200600027 – ident: e_1_2_6_24_2 doi: 10.1088/0034-4885/62/6/203 – ident: e_1_2_6_4_2 doi: 10.1002/pola.10804 – ident: e_1_2_6_20_2 doi: 10.1016/S1359-0294(03)00045-1 – ident: e_1_2_6_5_2 doi: 10.1021/cr9804700 – ident: e_1_2_6_17_2 doi: 10.1002/pol.1970.110080210 – ident: e_1_2_6_3_2 doi: 10.1016/S1359-0286(98)80071-5 – ident: e_1_2_6_22_2 doi: 10.1002/anie.199511431 – ident: e_1_2_6_9_2 doi: 10.1002/1521-3900(200101)163:1<1::AID-MASY1>3.0.CO;2-2 – ident: e_1_2_6_27_2 doi: 10.1016/j.porgcoat.2004.03.002 – ident: e_1_2_6_28_2 doi: 10.1016/S0300-9440(96)00686-8 – ident: e_1_2_6_23_2 doi: 10.1021/om00015a033 – ident: e_1_2_6_8_2 doi: 10.1021/cr040670d – ident: e_1_2_6_14_2 doi: 10.1021/ma991782n |
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| Snippet | A nonaqueous organic‐in‐fluorous emulsion applicable for polymerization using water‐sensitive catalysts is presented. With statistical biphasic copolymers... Abstract A nonaqueous organic‐in‐fluorous emulsion applicable for polymerization using water‐sensitive catalysts is presented. With statistical biphasic... A nonaqueous organic-in-fluorous emulsion applicable for polymerization using water-sensitive catalysts is presented. With statistical biphasic copolymers... |
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| SubjectTerms | Applied sciences emulsion polymerization Exact sciences and technology metallocene catalysts non-aqueous Organic polymers perfluorinated Physicochemistry of polymers Polymerization polyolefins Preparation, kinetics, thermodynamics, mechanism and catalysts |
| Title | Metallocene-Catalyzed Polymerization in Nonaqueous Fluorous Emulsion |
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