The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts
A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas wh...
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Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 40; no. 41; pp. 10812 - 10814 |
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Main Authors | , , , , , , , , , , |
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01.01.2011
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Abstract | A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not. |
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AbstractList | A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4[prime or minute]-dicarboxyethyl-2,2[prime or minute]-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2[prime or minute]-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not. A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not. |
Author | Schulz, Martin Rau, Sven Pryce, Mary T Paul, Avishek Browne, Wesley R Maclean, Brian J Vos, Johannes G Soman, Suraj Singh Bindra, Gurmeet Inglis, Jane Groarke, Robert |
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Snippet | A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together... A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4[prime or minute]-dicarboxyethyl-2,2[prime or minute]-bipyridine ligands,... |
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SubjectTerms | Bimetals Catalysis Hydrogen production Ligands Palladium Photocatalysis Pyrazines Ruthenium |
Title | The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts |
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