The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts

A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas wh...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 40; no. 41; pp. 10812 - 10814
Main Authors Singh Bindra, Gurmeet, Schulz, Martin, Paul, Avishek, Soman, Suraj, Groarke, Robert, Inglis, Jane, Pryce, Mary T, Browne, Wesley R, Rau, Sven, Maclean, Brian J, Vos, Johannes G
Format Journal Article
LanguageEnglish
Published England 01.01.2011
Subjects
Bimetals
Catalysis
Hydrogen production
Ligands
Palladium
Photocatalysis
Pyrazines
Ruthenium
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Summary:A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c1dt11241d