Mechanical Properties of Shaped Metal–Organic Frameworks

Metal–organic frameworks (MOFs) have gathered tremendous interest among researchers for their potential applications such as in storage and separation. While some progress has been made towards shaping of MOFs to realize industrial applications, the mechanical properties of MOFs remain more or less...

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Published inTopics in current chemistry (2016) Vol. 377; no. 5; p. 25
Main Authors Shah, Bhuvan B., Kundu, Tanay, Zhao, Dan
Format Journal Article
LanguageEnglish
Published Cham Springer International Publishing 01.10.2019
Subjects
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Life Sciences
Materials Science
Metal-Organic Framework: From Design to Applications
Molecular Medicine
Physics
Review
Tablets
Gels
Shaping
Mechanical properties
Granules
Monoliths
Metal–organic frameworks
Pellets
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Abstract Metal–organic frameworks (MOFs) have gathered tremendous interest among researchers for their potential applications such as in storage and separation. While some progress has been made towards shaping of MOFs to realize industrial applications, the mechanical properties of MOFs remain more or less unexplored. Over the last decade, this area has witnessed a steady growth in terms of understanding the mechanical stability of MOFs and its consequence on their performance. In this review, the mechanical properties of the reported macroscopic shaped MOF structures (mainly granules, pellets, tablets, monoliths, and gels) are discussed. Conclusions are then drawn to determine which shapes and shaping techniques promise to meet industrial requirements on the basis of mechanical stability. Finally, future research directions are proposed to improve our understanding, and possibly enhance stability, by correlating the properties from microscopic single-crystalline level to the industrially relevant macroscopic polycrystalline scale.
AbstractList Metal–organic frameworks (MOFs) have gathered tremendous interest among researchers for their potential applications such as in storage and separation. While some progress has been made towards shaping of MOFs to realize industrial applications, the mechanical properties of MOFs remain more or less unexplored. Over the last decade, this area has witnessed a steady growth in terms of understanding the mechanical stability of MOFs and its consequence on their performance. In this review, the mechanical properties of the reported macroscopic shaped MOF structures (mainly granules, pellets, tablets, monoliths, and gels) are discussed. Conclusions are then drawn to determine which shapes and shaping techniques promise to meet industrial requirements on the basis of mechanical stability. Finally, future research directions are proposed to improve our understanding, and possibly enhance stability, by correlating the properties from microscopic single-crystalline level to the industrially relevant macroscopic polycrystalline scale.
Metal-organic frameworks (MOFs) have gathered tremendous interest among researchers for their potential applications such as in storage and separation. While some progress has been made towards shaping of MOFs to realize industrial applications, the mechanical properties of MOFs remain more or less unexplored. Over the last decade, this area has witnessed a steady growth in terms of understanding the mechanical stability of MOFs and its consequence on their performance. In this review, the mechanical properties of the reported macroscopic shaped MOF structures (mainly granules, pellets, tablets, monoliths, and gels) are discussed. Conclusions are then drawn to determine which shapes and shaping techniques promise to meet industrial requirements on the basis of mechanical stability. Finally, future research directions are proposed to improve our understanding, and possibly enhance stability, by correlating the properties from microscopic single-crystalline level to the industrially relevant macroscopic polycrystalline scale.Metal-organic frameworks (MOFs) have gathered tremendous interest among researchers for their potential applications such as in storage and separation. While some progress has been made towards shaping of MOFs to realize industrial applications, the mechanical properties of MOFs remain more or less unexplored. Over the last decade, this area has witnessed a steady growth in terms of understanding the mechanical stability of MOFs and its consequence on their performance. In this review, the mechanical properties of the reported macroscopic shaped MOF structures (mainly granules, pellets, tablets, monoliths, and gels) are discussed. Conclusions are then drawn to determine which shapes and shaping techniques promise to meet industrial requirements on the basis of mechanical stability. Finally, future research directions are proposed to improve our understanding, and possibly enhance stability, by correlating the properties from microscopic single-crystalline level to the industrially relevant macroscopic polycrystalline scale.
ArticleNumber 25
Author Shah, Bhuvan B.
Zhao, Dan
Kundu, Tanay
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  givenname: Dan
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  surname: Zhao
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  email: chezhao@nus.edu.sg
  organization: Department of Chemical and Biomolecular Engineering, National University of Singapore
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Pellets
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Snippet Metal–organic frameworks (MOFs) have gathered tremendous interest among researchers for their potential applications such as in storage and separation. While...
Metal-organic frameworks (MOFs) have gathered tremendous interest among researchers for their potential applications such as in storage and separation. While...
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SubjectTerms Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Life Sciences
Materials Science
Metal-Organic Framework: From Design to Applications
Molecular Medicine
Physics
Review
Title Mechanical Properties of Shaped Metal–Organic Frameworks
URI https://link.springer.com/article/10.1007/s41061-019-0250-7
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