Facile synthesis of iron-ruthenium bimetallic oxide nanoparticles on carbon nanotube composites by liquid phase plasma method for supercapacitor

Iron-ruthenium bimetallic oxide nanoparticles were precipitated on carbon nanotubes by liquid-phase plasma method. We also evaluated the physicochemical and electrochemical properties of prepared composite for supercapacitor electrode. Polycrystalline about 10 to 25 nm-sized bimetallic nanoparticles...

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Published inThe Korean journal of chemical engineering Vol. 34; no. 11; pp. 2993 - 2998
Main Authors Lee, Won-June, Jeong, Sangmin, Lee, Heon, Kim, Byung-Joo, An, Kay-Hyeok, Park, Young-Kwon, Jung, Sang-Chul
Format Journal Article
LanguageEnglish
Published New York Springer US 01.11.2017
Springer Nature B.V
한국화학공학회
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Abstract Iron-ruthenium bimetallic oxide nanoparticles were precipitated on carbon nanotubes by liquid-phase plasma method. We also evaluated the physicochemical and electrochemical properties of prepared composite for supercapacitor electrode. Polycrystalline about 10 to 25 nm-sized bimetallic nanoparticles were evenly precipitated on the carbon nanotube (CNT) and consisted of Fe 3+ and Ru 4+ . Bimetallic oxide nanoparticles’ composition depended on the ratio of the metal precursor concentration and standard reduction potential. The C-V area and specific capacitance of iron-ruthenium oxide nanoparticle/carbon nanotube (IRCNT) composite electrodes was higher than that of untreated CNT electrode, and increased with increasing ruthenium content. The cycling stability of IRCNT composite electrode was higher than untreated CNT electrode, especially iron element was more stable.
AbstractList Iron-ruthenium bimetallic oxide nanoparticles were precipitated on carbon nanotubes by liquid-phase plasma method. We also evaluated the physicochemical and electrochemical properties of prepared composite for supercapacitor electrode. Polycrystalline about 10 to 25 nm-sized bimetallic nanoparticles were evenly precipitated on the carbon nanotube (CNT) and consisted of Fe3+ and Ru4+. Bimetallic oxide nanoparticles’ composition depended on the ratio of the metal precursor concentration and standard reduction potential. The C-V area and specific capacitance of iron-ruthenium oxide nanoparticle/carbon nanotube (IRCNT) composite electrodes was higher than that of untreated CNT electrode, and increased with increasing ruthenium content. The cycling stability of IRCNT composite electrode was higher than untreated CNT electrode, especially iron element was more stable.
Iron-ruthenium bimetallic oxide nanoparticles were precipitated on carbon nanotubes by liquid-phase plasma method. We also evaluated the physicochemical and electrochemical properties of prepared composite for supercapacitor electrode. Polycrystalline about 10 to 25 nm-sized bimetallic nanoparticles were evenly precipitated on the carbon nanotube (CNT) and consisted of Fe 3+ and Ru 4+ . Bimetallic oxide nanoparticles’ composition depended on the ratio of the metal precursor concentration and standard reduction potential. The C-V area and specific capacitance of iron-ruthenium oxide nanoparticle/carbon nanotube (IRCNT) composite electrodes was higher than that of untreated CNT electrode, and increased with increasing ruthenium content. The cycling stability of IRCNT composite electrode was higher than untreated CNT electrode, especially iron element was more stable.
Iron-ruthenium bimetallic oxide nanoparticles were precipitated on carbon nanotubes by liquid-phase plasma method. We also evaluated the physicochemical and electrochemical properties of prepared composite for supercapacitor electrode. Polycrystalline about 10 to 25 nm-sized bimetallic nanoparticles were evenly precipitated on the carbon nanotube (CNT) and consisted of Fe3+ and Ru4+. Bimetallic oxide nanoparticles’ composition depended on the ratio of the metal precursor concentration and standard reduction potential. The C-V area and specific capacitance of iron-ruthenium oxide nanoparticle/carbon nanotube (IRCNT) composite electrodes was higher than that of untreated CNT electrode, and increased with increasing ruthenium content. The cycling stability of IRCNT composite electrode was higher than untreated CNT electrode, especially iron element was more stable. KCI Citation Count: 45
Author Jeong, Sangmin
Jung, Sang-Chul
An, Kay-Hyeok
Park, Young-Kwon
Lee, Won-June
Lee, Heon
Kim, Byung-Joo
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  fullname: Lee, Won-June
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  fullname: Jung, Sang-Chul
  email: jsc@sunchon.ac.kr
  organization: Department of Environmental Engineering, Sunchon National University
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Keywords Specific Capacitance
Liquid Phase Plasma
Iron
Ruthenium
Bimetallic Oxide Nanoparticle
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한국화학공학회
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Snippet Iron-ruthenium bimetallic oxide nanoparticles were precipitated on carbon nanotubes by liquid-phase plasma method. We also evaluated the physicochemical and...
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SubjectTerms Bimetals
Biotechnology
Carbon
Carbon nanotubes
Catalysis
Chemistry
Chemistry and Materials Science
Electrochemical analysis
Electrodes
Electronic
Industrial Chemistry/Chemical Engineering
Inorganic
Iron
Materials (Organic
Materials Science
Nanoparticles
Nanotubes
Ruthenium
Ruthenium oxide
Supercapacitors
Thin Films
화학공학
Title Facile synthesis of iron-ruthenium bimetallic oxide nanoparticles on carbon nanotube composites by liquid phase plasma method for supercapacitor
URI https://link.springer.com/article/10.1007/s11814-017-0205-z
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