In Situ Electrochemical Generation of Hydrogen Peroxide in Alkaline Aqueous Solution by using an Unmodified Gas Diffusion Electrode
Hydrogen peroxide (H2O2) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of concentrations. This work describes the H2O2 electrogeneration process in alkaline medium (KOH 1.0 mol L−1), using an unmodified gas diffusion electrode (GDE)...
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| Published in | ChemElectroChem Vol. 2; no. 5; pp. 714 - 719 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY‐VCH Verlag
13.05.2015
John Wiley & Sons, Inc |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Hydrogen peroxide (H2O2) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of concentrations. This work describes the H2O2 electrogeneration process in alkaline medium (KOH 1.0 mol L−1), using an unmodified gas diffusion electrode (GDE) manufactured with Printex 6L carbon. The experiments were performed in a single‐compartment electrochemical cell equipped with a GDE as the working electrode, which was fed with N2 or O2 at a pressure of 0.2 bar. Electrolysis experiments were performed at a constant potential (−0.5≤E≤−1.4 V) for 90 min. The H2O2 concentration reached a maximum value of 3370 mg L−1 at −1.1 V (vs. Ag/AgCl), and H2O2 electrogeneration followed pseudo‐zero‐order kinetics with an apparent rate constant kapp=59.7 mg L−1 min−1. A low energy consumption of 8.0 kWh kg−1 was calculated for these electrogeneration conditions.
Volt of confidence: Electrogeneration of H2O2 in alkaline medium, using a gas diffusion electrode with unmodified carbon Printex 6L carbon, exhibits low energy consumption and a high kinetic constant. |
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| AbstractList | Hydrogen peroxide (H2O2) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of concentrations. This work describes the H2O2 electrogeneration process in alkaline medium (KOH 1.0 mol L-1), using an unmodified gas diffusion electrode (GDE) manufactured with Printex 6L carbon. The experiments were performed in a single-compartment electrochemical cell equipped with a GDE as the working electrode, which was fed with N2 or O2 at a pressure of 0.2bar. Electrolysis experiments were performed at a constant potential (-0.5≤E≤-1.4V) for 90min. The H2O2 concentration reached a maximum value of 3370mgL-1 at -1.1V (vs. Ag/AgCl), and H2O2 electrogeneration followed pseudo-zero-order kinetics with an apparent rate constant kapp=59.7mgL-1min-1. A low energy consumption of 8.0 kWh kg-1 was calculated for these electrogeneration conditions. Hydrogen peroxide (H2O2) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of concentrations. This work describes the H2O2 electrogeneration process in alkaline medium (KOH 1.0 mol L−1), using an unmodified gas diffusion electrode (GDE) manufactured with Printex 6L carbon. The experiments were performed in a single‐compartment electrochemical cell equipped with a GDE as the working electrode, which was fed with N2 or O2 at a pressure of 0.2 bar. Electrolysis experiments were performed at a constant potential (−0.5≤E≤−1.4 V) for 90 min. The H2O2 concentration reached a maximum value of 3370 mg L−1 at −1.1 V (vs. Ag/AgCl), and H2O2 electrogeneration followed pseudo‐zero‐order kinetics with an apparent rate constant kapp=59.7 mg L−1 min−1. A low energy consumption of 8.0 kWh kg−1 was calculated for these electrogeneration conditions. Volt of confidence: Electrogeneration of H2O2 in alkaline medium, using a gas diffusion electrode with unmodified carbon Printex 6L carbon, exhibits low energy consumption and a high kinetic constant. Abstract Hydrogen peroxide (H 2 O 2 ) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of concentrations. This work describes the H 2 O 2 electrogeneration process in alkaline medium (KOH 1.0 mol L −1 ), using an unmodified gas diffusion electrode (GDE) manufactured with Printex 6L carbon. The experiments were performed in a single‐compartment electrochemical cell equipped with a GDE as the working electrode, which was fed with N 2 or O 2 at a pressure of 0.2 bar. Electrolysis experiments were performed at a constant potential (−0.5≤ E ≤−1.4 V) for 90 min. The H 2 O 2 concentration reached a maximum value of 3370 mg L −1 at −1.1 V (vs. Ag/AgCl), and H 2 O 2 electrogeneration followed pseudo‐zero‐order kinetics with an apparent rate constant k app =59.7 mg L −1 min −1 . A low energy consumption of 8.0 kWh kg −1 was calculated for these electrogeneration conditions. Hydrogen peroxide (H sub(2)O sub(2)) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of concentrations. This work describes the H sub(2)O sub(2) electrogeneration process in alkaline medium (KOH 1.0 mol L super(-1)), using an unmodified gas diffusion electrode (GDE) manufactured with Printex 6L carbon. The experiments were performed in a single-compartment electrochemical cell equipped with a GDE as the working electrode, which was fed with N sub(2) or O sub(2) at a pressure of 0.2bar. Electrolysis experiments were performed at a constant potential (-0.5 less than or equal to E less than or equal to -1.4V) for 90min. The H sub(2)O sub(2) concentration reached a maximum value of 3370mgL super(-1) at -1.1V (vs. Ag/AgCl), and H sub(2)O sub(2) electrogeneration followed pseudo-zero-order kinetics with an apparent rate constant k sub(app)=59.7mgL super(-1)min super(-1). A low energy consumption of 8.0 kWh kg super(-1) was calculated for these electrogeneration conditions. Volt of confidence: Electrogeneration of H sub(2)O sub(2) in alkaline medium, using a gas diffusion electrode with unmodified carbon Printex 6L carbon, exhibits low energy consumption and a high kinetic constant. |
| Author | Barros, Willyam R. P. Ereno, Thaís Lanza, Marcos R. V. Tavares, Ana C. |
| Author_xml | – sequence: 1 givenname: Willyam R. P. surname: Barros fullname: Barros, Willyam R. P. – sequence: 2 givenname: Thaís surname: Ereno fullname: Ereno, Thaís – sequence: 3 givenname: Ana C. surname: Tavares fullname: Tavares, Ana C. – sequence: 4 givenname: Marcos R. V. surname: Lanza fullname: Lanza, Marcos R. V. email: marcoslanza@iqsc.usp.br |
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| Snippet | Hydrogen peroxide (H2O2) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of concentrations.... Abstract Hydrogen peroxide (H 2 O 2 ) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of... Hydrogen peroxide (H sub(2)O sub(2)) is an oxidizing agent commonly used for various applications and is available in aqueous solution in a wide range of... |
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| SubjectTerms | alkaline medium Aqueous solutions Carbon carbon black Constants Diffusion Electrodes Energy consumption Gas diffusion gas diffusion electrode Hydrogen peroxide Low energy oxygen reduction reaction |
| Title | In Situ Electrochemical Generation of Hydrogen Peroxide in Alkaline Aqueous Solution by using an Unmodified Gas Diffusion Electrode |
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