Scalable Photoelectrochemical Dehydrogenative Cross‐Coupling of Heteroarenes with Aliphatic C−H Bonds

• Published in: Angewandte Chemie International Edition Vol. 59; no. 34; pp. 14275 - 14280
• Main Authors: Xu, Pin, Chen, Peng‐Yu, Xu, Hai‐Chao
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 17.08.2020; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Aliphatic compounds; Alkylation; Bioactive compounds; Carbon; Catalysts; Chemical bonds; Chemistry; Chemistry, Multidisciplinary; Chlorine; Coupling (molecular); Cross coupling; C−H functionalization; Dehydrogenation; Electrochemistry; Functional materials; heterocycles; Hydrogen evolution; Irradiation; Light irradiation; Oxidants; Oxidizing agents; Photochemistry; photoelectrochemistry; Physical Sciences; Radiation; radical reactions; Radicals; Science & Technology; ELECTROSYNTHESIS; CATALYSIS; photoelectrochemistry; electrochemistry; LIGHT; ARYLATION; radical reactions; C-H functionalization; FUNCTIONALIZATION; heterocycles; GENERATION; ARYL CHLORIDES; ALKANES

Heteroarenes are structural motifs found in many bioactive compounds and functional materials. Dehydrogenative cross‐coupling of heteroarenes with aliphatic C−H bonds provides straightforward access to functionalized heteroarenes from readily available materials. Established methods employ stoichiom...